摘要:
The present invention relates to olefinic compositions comprising a functionalized branched olefin copolymer containing functionalized sidechains derived from olefin and at least one chain end nucleophilic heteroatom containing functional group with at least one protic hydrogen, optionally with one or more copolymerizable monomers, the copolymer characterized by having A) a Tg 100° C.; C) an elongation at break of greater than or equal to 500 percent; D) a Tensile Strength of greater than or equal to 1,500 psi (10,300 kPa) at 25° C.; E) a TMA temperature>80° C., and F) an elastic recovery of greater than or equal to 50 percent.
摘要:
A novel olefin-based polymer has excellent thermal resistance, as well as excellent balance among various properties. The olefin-based polymer is an olefin-based polymer comprising 50 to 100% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties: i) the diad isotacticity is 70% or greater, ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5, and iii) the intrinsic viscosity [η] is 0.5 (dl/g) or greater.
摘要:
A novel olefin-based polymer has excellent thermal resistance, as well as excellent balance among various properties. The olefin-based polymer is an olefin-based polymer comprising 50 to 100% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties: i) the diad isotacticity is 70% or greater, ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5, and iii) the intrinsic viscosity [η] is 0.5 (dl/g) or greater.
摘要:
A polypropylene composition containing a propylene/1-butene random copolymer which contains 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point of from 40 to 75° C. and a crystallization rate at 45° C. of 10 minutes or less, and satisfying the following relation, 146 exp (−0.022M)≧Tm≧125 exp (−0.032M), and an olefin catalyst for preparation thereof.
摘要:
The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120° C., and satisfies the following relation 146 exp(−0.022M)≧Tm≧125 exp(−0.032M) wherein Tm represents a melting point and M (mol %) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R1 and R3 is hydrogen, R2 and R4 are selected from a hydrocarbon group and silicon-containing group, R5 to R13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R5 to R12 may be linked to form a ring. R14 is an aryl group, and R13 and R14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.
摘要:
It is an object to provide a new polyolefin hybrid polymer composed of a polyolefin segment and a polar polymer segment (Z) and a method for manufacturing the hybrid polymer by an industrially advantageous procedure.A polyolefin hybrid polymer composed of a polyolefin segment and a polar polymer segment (Z), wherein the polyolefin hybrid polymer is a modified compound of maleic polyolefin (A), is characterized by comprising a constitutional unit represented by the general formula (I): wherein Z represents a polar polymer segment obtained by polymerizing monomers of at least one kind selected from organic compounds having at least one carbon-carbon unsaturated bond, and F represents a group including an unsaturated bond.
摘要:
A propylene/1-butene random copolymer containing 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point of from 40 to 75° C. and a crystallization rate at 45° C. of 10 minutes or less, and satisfying the following relation, 146 exp (−0.022M)≧Tm≧125 exp (−0.032M), and an olefin catalyst for preparation thereof.
摘要:
A polypropylene composite film having a propylene/1-butene random copolymer which has 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point of from 40 to 75° C. and a crystallization rate at 45° C. of 10 minutes or less, and satisfying the following relation, 146 exp (−0.022M)≧Tm ≧125 exp (−0.032M), and an olefin catalyst for preparation thereof.
摘要:
A hybrid polymer has a structure in which a polyolefin segment and a polar polymer segment are connected not via a bonding group containing a heteroatom. A method of the invention produces the hybrid polymer with industrial advantages. The hybrid polymer includes a polyolefin segment (A) and a polar polymer segment (B), the polar polymer segment being obtained by radical polymerization of a radically polymerizable monomer.