公开(公告)号：US4150230A

公开(公告)日：1979-04-17

申请号：US889366

申请日：1978-03-23

申请人： Roland Mislin ,  Wolfgang Schoenauer ,  Karl U. Steiner

发明人： Roland Mislin ,  Wolfgang Schoenauer ,  Karl U. Steiner

IPC分类号： C09B1/34 ,  C09B62/024 ,  D06P1/38 ,  D06P1/382 ,  C07D241/40

CPC分类号： C09B1/34 ,  C09B62/024 ,  D06P1/38 ,  D06P1/382

摘要： 1,4-Diaminoanthraquinone derivatives containing a halopyrimidinyl or haloquinoxaline-6-carbonyl reactive group are useful as reactive dyestuffs for the dyeing or printing of leather and textile materials.

摘要翻译： 含有卤代嘧啶基或卤代喹喔啉-6-羰基反应性基团的1,4-二氨基蒽醌衍生物可用作皮革和纺织材料的染色或印花的活性染料。

公开(公告)号：US4080322A

公开(公告)日：1978-03-21

申请号：US697402

申请日：1976-06-18

申请人： Roland Mislin ,  Hanspeter Uehlinger

发明人： Roland Mislin ,  Hanspeter Uehlinger

IPC分类号： C09B29/30 ,  C09B43/12

CPC分类号： C09B29/30

摘要： Compounds of the formula ##STR1## in which R.sub.1 signifies an optionally substituted hydrocarbon radical,R.sub.2 signifies hydrogen, halogen, nitro, a linear or branched optionally substituted alkyl radical such as haloalkyl, an optionally substituted cycloalkyl radical, alkoxy, alkylthio, an optionally substituted aryl radical, an acyl radical of an aliphatic or aromatic sulphonic or carboxylic acid, an ester or amide group of a sulphonic acid, an ester or amide group of a carboxylic acid, an ester group of a carbamic acid, unsubstituted or mono- or disubstituted amino or an acylamino group,The ring A may be further substituted, and may as R.sub.2 bear a condensed cycloalkyl radical, but ring A and any substituent on it is free from carboxylic or sulphonic acid groups and from groups in the ortho-position to the azo group which are capable of the formation of metal complexes,Provided that the total number of carbon atoms in R.sub.1 and in the substituent(s) on ring A is from 12 to 30, preferably 12 to 18, in free acid or water-soluble salt form, are useful water-soluble dyes for acid-dyeable non-wovens and textile fibres, leather and paper.

摘要翻译： 式I的化合物其中R 1表示任选取代的烃基，R 2表示氢，卤素，硝基，直链或支链任选取代的烷基如卤代烷基，任选取代的环烷基，烷氧基，烷硫基，任选地 取代的芳基，脂族或芳族磺酸或羧酸的酰基，磺酸的酯或酰胺基，羧酸的酯或酰胺基，氨基甲酸的酯基，未取代的或单或 二取代的氨基或酰氨基，环A可以被进一步取代，并且可以作为R 2具有稠合的环烷基，但环A和其上的任何取代基不含羧酸或磺酸基团，并且与邻位 - 能够形成金属络合物的偶氮基团，提供R1中的碳原子数和环A上的取代基中的碳数为12〜30，优选为12 至18，以游离酸或水溶性盐形式，可用于酸可染无纺布和纺织纤维，皮革和纸张的水溶性染料。

公开(公告)号：US4058516A

公开(公告)日：1977-11-15

申请号：US481181

申请日：1974-06-20

申请人： Roland Mislin ,  Hanspeter Uehlinger

发明人： Roland Mislin ,  Hanspeter Uehlinger

IPC分类号： C09B35/00 ,  C09B35/34 ,  C09B35/376 ,  C09B35/40 ,  C09B45/24 ,  C09B62/006 ,  C09B62/08 ,  C09B43/00 ,  C09B43/12 ,  C09B43/18

CPC分类号： C09B45/28 ,  C09B35/34 ,  C09B35/376 ,  C09B35/40 ,  C09B62/09

摘要： Dyes of the formula ##STR1## AND SUBSTITUTED DERIVATIVES THEREOF, WHEREIN R is a coupling component radical,R.sub.1 is a coupling component radical, with the proviso that R and R.sub.1 are different, andN is 1 to 8,Are disclosed. They are useful for dyeing and printing natural and synthetic polyamides, cotton and other cellulosic fibers, polypropylene fibers modified by basic groups, synthetic polyamides and polyesters modified by acid groups, paper and leather. They exhibit good fastness to light, wet treatments and abrasion.

摘要翻译： 下式的染料及其取代的衍生物，其中R是偶合成分基团，R1是偶合成分基团，条件是R和R1不同，并且N IS 1至8被公开。 它们可用于染色和印刷天然和合成聚酰胺，棉花和其他纤维素纤维，由碱性基团改性的聚丙烯纤维，合成聚酰胺和由酸基改性的聚酯，纸和皮革。 它们具有良好的耐光牢度，湿润处理和耐磨性。

公开(公告)号：US4685934A

公开(公告)日：1987-08-11

申请号：US754533

申请日：1985-07-12

申请人： Francois Benguerel ,  Roland Mislin

发明人： Francois Benguerel ,  Roland Mislin

IPC分类号： C09B29/036 ,  C09B29/00 ,  D06P1/39 ,  C09B29/09 ,  C09B29/30 ,  C09B29/36

CPC分类号： D06P1/39 ,  C09B29/0037 ,  Y10S8/929

摘要： Monoazo compounds of formula ##STR1## wherein R.sub.1 is a coupling component radical,R.sub.1 is C.sub.1-6 alkyl; C.sub.1-6 alkyl substituted by 1 or 2 substituents selected from chloro, cyano, hydroxy, C.sub.1-4 alkoxy, phenyl and phenyl substituted by 1 or 2 substituents selected from chloro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, carboxy, sulfo, sulfamoyl and acetamido; C.sub.5-7 cycloalkyl; C.sub.5-7 cycloalkyl substituted by 1 to 3 C.sub.1-4 alkyl groups; phenyl; phenyl substituted by 1 to 3 substituents selected from chloro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, acetamido (maximum of 1), carboxy (maximum of 1), sulfo (maximum of 1) and --SO.sub.2 NR.sub.7 R.sub.8 (maximum of 1); 1- or 2-naphthyl or 1- or 2-naphthyl substituted by sulfo,whereineach of R.sub.7 and R.sub.8 is independently hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy or phenyl; cyclohexyl; phenyl or phenyl monosubstituted by chloro, methyl or methoxy, or--NR.sub.7 R.sub.8 is a 5- or 6-membered saturated or unsaturated ring containing 1 or 2 hetero atoms,R.sub.2 is hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy, chloro, cyano, C.sub.1-4 alkoxy, phenyl or phenyl substituted by 1 or 2 substituents selected from chloro, methyl, methoxy, sulfo and sulfamoyl; C.sub.1-4 alkoxy; cyano; phenyl; phenoxy; or phenyl or phenoxy monosubstituted by chloro, methyl, methoxy or sulfo, andR.sub.3 is cyano, carbamoyl, --COOR.sub.4, sulfo or --CO.sub.2 NR.sub.5 R.sub.6,whereinR.sub.4 is hydrogen, C.sub.1-4 alkyl, phenyl or phenyl(C.sub.1-4 alkyl), andeach of R.sub.5 and R.sub.6 is independently hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy or phenyl; cyclohexyl; phenyl or phenyl monosubstituted by chloro, methyl or methoxy, or--NR.sub.5 R.sub.6 is a 5- or 6-membered saturated or unsaturated ring containing 1 or 2 hetero atoms,with the provisos that (i) the total number of sulfo groups is 1 or 2 and (ii) R.sub.1, R.sub.2 or R.sub.3 must contain a sulfo group when K.sub.1 is a coupling component radical of the aminobenzene series the amino group of which is substituted by an alkylene radical having a terminal sulfo or sulfato group, by a bridge member-containing alkylene radical having a terminal sulfo or sulfato group or by a phenylalkyl group the phenyl group of which has a sulfo substituent, are useful for dyeing or printing anionically dyeable substrates such as natural or synthetic polyamides, especially nylon carpet.

公开(公告)号：US4377517A

公开(公告)日：1983-03-22

申请号：US159952

申请日：1980-06-16

申请人： Roland Mislin ,  Hanspeter Uehlinger ,  Max Oppliger

发明人： Roland Mislin ,  Hanspeter Uehlinger ,  Max Oppliger

IPC分类号： C09B62/085 ,  D06P1/382 ,  D06P3/10

CPC分类号： C09B62/085

摘要： Compounds of the formula ##STR1## in which R.sub.1 is C.sub.1-4 alkyl,Hal is halogen,R.sub.2 is ##STR2## --SO.sub.2 C.sub.1-4 alkyl, --SO.sub.2 NR.sub.8 R.sub.9 or --NHCOOR.sub.10,R.sub.3 is hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,R.sub.4 is hydrogen or C.sub.1-4 alkyl,R.sub.5 is hydrogen; C.sub.1-4 alkyl; cyclohexyl; cyclohexyl substituted by one to three C.sub.1-4 alkyl groups; phenyl or phenyl substituted by one or two substituents selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy,R.sub.6 is hydrogen or hydroxy, with the proviso that R.sub.6 is hydrogen when R.sub.2 is --NHCOOR.sub.10,R.sub.7 is hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,each of R.sub.8 and R.sub.9, independently, is hydrogen, C.sub.1-4 alkyl, C.sub.2-4 hydroxyalkyl, cyclohexyl; or phenyl or phenyl substituted by one or two substituents selected from halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, sulfo and carboxy, with the proviso that not more than one of R.sub.8 and R.sub.9 is cyclohexyl, phenyl or substituted phenyl,R.sub.10 is C.sub.1-6 alkyl, the triazinylamino group is in the 4-position when R.sub.2 is --NHCOOR.sub.10 and otherwise is in the 4- or 5-position,m is 1 or 2,n is 0 or 1, andp is 0 or 1,and the molecule contains at least two sulpho groups, and mixtures of such compounds, which compounds are in free acid or salt form and are useful as reactive dyes for dyeing and printing hydroxy group-containing and nitrogen-containing organic substrates such as leather and textile materials consisting of or comprising natural or regenerated cellulose (for example, cotton, viscose and spun rayon) or natural or synthetic polyamides (for example, wool, silk and nylon. The obtained dyeings and prints have notable fastness to light, washing, water, sweat and milling. The combination dyeings obtained when used in combination with other sulfo group-containing reactive dyes are tone-in-tone, resist catalytic fading and exhibit good fastness to light and wet treatments.

摘要翻译： 其中R 1是C 1-4烷基，Hal是卤素，R 2是-SO 2 C 1-4烷基，-SO 2 NR 8 R 9或-NHCOOR 10，R 3是氢，C 1-4烷基或C 1-4烷氧基，R 4是氢 或C 1-4烷基，R 5是氢; C 1-4烷基; 环己基 被一至三个C 1-4烷基取代的环己基; 苯基或被一个或两个选自卤素，C 1-4烷基和C 1-4烷氧基的取代基取代的苯基，R 6是氢或羟基，条件是当R 2是-NHCOOR 10时，R 6是氢，R 7是氢，C 1-4烷基或C1- 4个烷氧基，R8和R9各自独立地是氢，C 1-4烷基，C 2-4羟烷基，环己基; 或被一个或两个选自卤素，C 1-4烷基，C 1-4烷氧基，磺基和羧基的取代基取代的苯基或苯基，条件是R 8和R 9中不多于一个是环己基，苯基或取代的苯基，R 10是C1- 6烷基，当R2为-NHCOOR10时，三嗪基氨基为4-位，否则为4-或5-位，m为1或2，n为0或1，p为0或1，分子 含有至少两个磺基，以及这些化合物的混合物，该化合物为游离酸或盐形式，可用作活性染料，用于染色和印刷含羟基和含氮有机基底如皮革和纺织材料，由 或者包括天然或再生纤维素（例如棉，粘胶和纺丝人造丝）或天然或合成聚酰胺（例如羊毛，丝绸和尼龙），得到的染色和印花具有显着的耐光牢度，洗涤，水，汗和研磨 当我们获得的组合染色 与其他含有磺基的活性染料组合使用的是色调调节，抵抗催化褪色，对光和湿处理表现出良好的牢度。

公开(公告)号：US4237284A

公开(公告)日：1980-12-02

申请号：US942446

申请日：1978-09-14

申请人： Roland Mislin

发明人： Roland Mislin

IPC分类号： C09B1/28 ,  C09B62/024 ,  D06P1/38 ,  C07D251/42 ,  C07D251/50 ,  C07D295/10

CPC分类号： C09B1/28 ,  C09B62/024 ,  D06P1/38

摘要： The present invention relates to reactive dye-compounds of formula I, ##STR1## in which Y is hydrogen or sulpho,X is a straight chain or branched (C.sub.2-6) alkylene group or ##STR2## in which each of A.sub.1 and A.sub.2, independently, is a direct bond or a (C.sub.1-4) alkylene group, n is 1 or 2 and the ring D is optionally substituted by up to three (C.sub.1-4) alkyl groups,with the proviso that when n is 2, the group ##STR3## is the radical of an unsymmetrical diamine, R.sub.1 is hydrogen; (C.sub.1-4) alkyl; (C.sub.2-4) alkyl substituted in the .beta.,.gamma.-or .delta.-position by hydroxy and/or carboxy; or (C.sub.5-6) cycloalkyl or (C.sub.1-4) alkyl-substituted (C.sub.5-6) cycloalkylZ is the radical of a fibre reactive group which contains a single fibre reactive componentor mixtures thereof, which compounds are in free acid or water-soluble salt form and are useful as dyestuffs for dyeing or printing hydroxy group-containing or nitrogen containing organic textile substrates.

摘要翻译： 本发明涉及式I的活性染料化合物，其中Y为氢或磺基，X为直链或支链（C2-6）亚烷基或“IMAGE”，其中A1和A2各自为 独立地是直接键或（C 1-4）亚烷基，n是1或2，并且环D任选被至多三个（C 1-4）烷基取代，条件是当n是2时， 该组是不对称二胺的基团，R1是氢; （C 1-4）烷基; 被羟基和/或羧基取代的β-，γ-或δ-位的（C2-4）烷基; 或（C 5-6）环烷基或（C 1-4）烷基取代的（C 5-6）环烷基Z是含有单纤维反应性组分或其混合物的纤维反应性基团的基团，该化合物在游离酸或水 可溶性盐形式，可用作染色或印刷含羟基或含氮有机织物基材的染料。

公开(公告)号：US4728464A

公开(公告)日：1988-03-01

申请号：US486033

申请日：1983-04-18

申请人： Roland Mislin

发明人： Roland Mislin

IPC分类号： C09B1/34 ,  D06P3/06 ,  C09B1/26 ,  D06P1/20

CPC分类号： D06P3/06 ,  C09B1/343

摘要： Compounds of formula I ##STR1## in which R is hydrogen, methyl or ethyl, R.sub.1 is methyl, ethyl, C.sub.1-4 alkoxy or halogenR.sub.2 is hydrogen, methyl or ethylR.sub.3 is hydrogen, methyl or ethylM is hydrogen or one equivalent of a cation andring A may be unsubstituted or substituted by up to three substituents selected from C.sub.1-4 alkyl, C.sub.1-4 alkoxy, halogen and C.sub.2-4 acylaminoare useful anionic dyestuffs having superior alkali resistance for the dyeing and printing of natural and synthetic polyamides, especially nylon.

摘要翻译： 式Ⅰ化合物其中R为氢，甲基或乙基，R1为甲基，乙基，C1-4烷氧基或卤素R2为氢，甲基或乙基，R3为氢，甲基或乙基，M为氢或一个 等同的阳离子和环A可以是未被取代的或被多至三个选自C 1-4烷基，C 1-4烷氧基，卤素和C 2-4酰基氨基的取代基取代，是对于天然和合成聚酰胺的染色和印刷具有优异的耐碱性的阴离子染料 ，特别是尼龙。

公开(公告)号：US4188187A

公开(公告)日：1980-02-12

申请号：US893730

申请日：1978-04-05

申请人： Roland Mislin ,  Karl-Ulrich Steiner

发明人： Roland Mislin ,  Karl-Ulrich Steiner

IPC分类号： C09B1/34 ,  D06P1/20 ,  D06P1/40 ,  D06P1/42 ,  D06P3/24 ,  C09B1/00

CPC分类号： C09B1/343 ,  D06P1/40 ,  Y10S8/924

摘要： A process for dyeing or printing natural or synthetic polyamide textile substrates comprising employing, as dyestuff, a compound of formula I, ##STR1## in which R is hydrogen, methyl or ethyl,R.sub.1 is hydrogen, methyl or ethyl, andthe ring A is unsubstituted or monosubstituted by halogen, (C.sub.1-2)alkyl, (C.sub.1-2)alkoxy or alkyl(C.sub.1-2)carbonylamino or disubstituted by methyl groups,in free acid or salt form.

摘要翻译： 一种用于染色或印刷天然或合成聚酰胺纺织品基材的方法，其包括使用式I化合物作为染料，其中R是氢，甲基或乙基，R 1是氢，甲基或乙基，环A 被卤素，（C1-2）烷基，（C1-2）烷氧基或烷基（C1-2）羰基氨基单取代或被甲基二取代的游离酸或盐形式单取代。

公开(公告)号：US4101547A

公开(公告)日：1978-07-18

申请号：US700064

申请日：1976-06-25

申请人： Roland Mislin ,  Wolfgang Schoenauer ,  Karl Ulrich Steiner

发明人： Roland Mislin ,  Wolfgang Schoenauer ,  Karl Ulrich Steiner

IPC分类号： C07D239/42 ,  C09B1/34 ,  C09B62/024 ,  C09B62/22 ,  D06P1/38 ,  D06P1/382 ,  C09B62/20 ,  C09B1/22 ,  C09B62/28

CPC分类号： C09B62/024 ,  C09B1/34 ,  D06P1/38 ,  D06P1/382

摘要： 1,4-Diaminoanthraquinone derivatives containing a halopyrimidinyl or haloquinoxaline-6-carbonyl reactive group are useful as reactive dyestuffs for the dyeing or printing of leather and textile materials.

摘要翻译： 含有卤代嘧啶基或卤代喹喔啉-6-羰基反应性基团的1,4-二氨基蒽醌衍生物可用作皮革和纺织材料的染色或印花的活性染料。

公开(公告)号：US3981858A

公开(公告)日：1976-09-21

申请号：US323621

申请日：1973-01-15

申请人： Roland Mislin ,  Hanspeter Uehlinger

发明人： Roland Mislin ,  Hanspeter Uehlinger

IPC分类号： C09B29/16 ,  C09B43/128 ,  C07C107/04

CPC分类号： C09B29/16

摘要： Azo dyes bearing at least one sulphonic acid group and of formula I, ##SPC1##in whichR signifies an alkyl radical of 6 to 18 carbon atoms or a cyclohexyl radical,R.sub.1 signifies hydrogen, halogen, alkyl, or --SO.sub.3 H,R.sub.2 signifies hydrogen, halogen or alkyl, andn signifies 0, 1 or 2,Which compounds, in free acid or salt form, dye textiles, paper and leather. The dyeings have good light fastness, especially on polyamides and basic dyeable polypropylene, and good fastness to wet treatments, rubbing, gas fumes and dry cleaning. The dyes have good build-up power, are well-soluble in hot and cold water and reserve polyesters and polyacrylonitrile.

摘要翻译： 具有至少一个磺酸基团和式I的偶氮染料，其中R表示6至18个碳原子的烷基或环己基，R1表示氢，卤素，烷基或-SO3H，R2表示氢，卤素或 烷基，以及N，I或2，化合物，无机酸或盐形式，染色纺织品，造纸和皮革。 染色剂具有良好的耐光性，特别是在聚酰胺和碱性可染色聚丙烯上，具有良好的湿处理，摩擦，气体烟雾和干洗的牢度。 染料具有良好的积聚能力，易溶于冷热水和储存聚酯和聚丙烯腈。