Process for the preparation of mixed trimers from organic isocyanates,
the mixed trimers obtained according to the process and the use thereof
for the production of polyurethanes
    1.
    发明授权
    Process for the preparation of mixed trimers from organic isocyanates, the mixed trimers obtained according to the process and the use thereof for the production of polyurethanes 失效
    从有机异氰酸酯制备混合三聚物的方法,根据该方法获得的混合三聚物及其在生产聚氨酯中的用途

    公开(公告)号:US4518761A

    公开(公告)日:1985-05-21

    申请号:US439086

    申请日:1982-11-04

    摘要: The present invention is directed to a new process for the preparation of mixed trimers by at least partly trimerizing the isocyanate groups of at least two organic isocyanates of a reactivity which differs in the sense of the trimerization reaction, in the presence of trimerization catalysts and optionally interrupting the trimerization reaction at the respectively desired degree of trimerization, in which process the less reactive isocyanate component is introduced, polymerization is then commenced in the presence of the catalyst with the trimerization of at least 0.1% of the isocyanate groups and the more reactive isocyanate component is finally metered into the reaction mixture thus obtained; the mixed trimers obtained according to this process; and the use of the mixed trimers having free isocyanate groups obtained by this process, optionally in a form blocked by blocking agents for organic polyisocyanates, as a starting material for the production of polyurethane plastics materials.

    摘要翻译: 本发明涉及一种新的制备混合三聚体的方法,该方法是在三聚催化剂存在下,至少部分地将三聚反应意义上的至少两种有机异氰酸酯的反应性的异氰酸酯基团三聚,其反应性不同, 在分别期望的三聚程度下中断三聚反应,其中引入反应活性较低的异氰酸酯组分较少,然后在催化剂存在下开始聚合,三聚化至少为0.1%的异氰酸酯基团,反应活性较高的异氰酸酯 将组分最终计量加入由此获得的反应混合物中; 根据该方法得到的混合三聚物; 以及使用通过该方法获得的具有游离异氰酸酯基团的混合三聚体,任选地以用于有机聚异氰酸酯的封闭剂封闭的形式作为用于制备聚氨酯塑料材料的起始材料。