摘要:
A process for the modification of unsaturated polyolefin rubbers by reaction with other polymers amenable to the metathesis reaction, in the liquid phase, preferably in solution, in the presence of a metathesis catalyst system comprising (a) a soluble compound of a metal of the Subgroups V through VII of the periodic table, and (b) a soluble alkyl or hydride of a metal of Main groups I through III of the periodic table, as well as optionally activators, characterized by the metallic components of the catalyst system each being dispersed, preferably dissolved, separately in partial streams wherein the reaction components are contained, and these partial streams are intermixed intensively.
摘要:
Polyalkenamers are produced by a ring-opening polymerization of cyclic olefins employing a catalyst system comprising (1) a tungsten or molybdenum compound; (2) an organoaluminum compound; (3) a vinylic chloride, bromide or iodide; and, optionally, (4) a compound containing a hydroxyl or sulfhydryl group; and conducting the polymerization in the presence of an ethylenically unsaturated halogenated hydrocarbon wherein one of the double bonded carbon atoms is substituted by chlorine, bromine or iodine or halogenated alkyl or aryl and at least one hydrogen atom.
摘要:
For the production of polyalkenamers there are provided catalysts consisting essentially of a catalyst system for the ring-opening polymerization of cyclic olefins consisting essentially of (1) a tungsten or molybdenum compound; (2) an organoaluminum compound; and (3) an ether of vinyl alcohol, of allyl alcohol, or of 2-butene-1,4-diol, the molar ratio of component (1) to component (2) being less than 1 : 1 and the molar ratio of component (1) to component (3) being less than 100 : 1. The catalyst system may also contain a compound containing one or more hydroxyl or sulfhydryl groups in a molar ratio to component (1) of about 0 : 1 to 2 : 1, respectively.
摘要:
The invention discloses a portable tool having a housing with a gearhead, having a motor shaft which can be rotationally driven by a motor and which can be coupled via an eccentric coupling drive to a tool spindle for the drive thereof, wherein the tool spindle can be driven in a rotational oscillatory manner about the longitudinal axis thereof and is configured for accommodating a tool, wherein a motion-reversal drive is provided which is configured for converting an oscillating drive movement produced by the eccentric coupling drive into an oscillating output movement which has a direction of oscillation opposed to said drive movement. The motion-reversal drive is configured as an epicyclic gearing.
摘要:
Briquettes made from bituminous or sub-bituminous coal or peat are produced by grinding the coal, mixing it with a binder and compacting the mixture. They are then carbonized in a continuous process in a shaft oven. The coal may be predried and the finished briquettes may be preheated, with a subsequent drying and hardening. The carbonization is effected in two stages in an indirectly heated shaft oven, with the evolved gas being taken off about at the mid-height of the oven shaft, processed, and used for heating in the second, high-temperature stage. The flue gases from this high-temperature stage are used for heating in the first stage and for preheating. The second or high-temperature stage is followed by a cooling stage where the gases evolved in the second stage, and mainly comprising hydrogen are used and circulated. The evolved gas in excess is continuously removed from the cooling circuit.
摘要:
A coke cooler and method of operating the cooler is disclosed for dry cooling hot glowing coke through the recovery of the sensible heat of the hot glowing coke. The apparatus includes a vertically elongated vessel having walls partially formed with integral heat exchange tubes for the passage of a liquid coolant and a shroud having an internal prechamber mounted in the upper end of the vessel for receiving a charge of the hot glowing coke. The shroud cooperates with the vessel to provide a annular passage for fluid flow therebetween of a gas which directly contacts the hot glowing coke for direct cooling while liquid coolant is passed through the tubes for indirectly cooling the coke.
摘要:
The process for the production of molded metallurgical coke from dried coal or fine coal mixtures with a low swelling index particularly highly volatile fine coal comprises mixing normal washed fine coal or fine coal mixtures of a grain size of from 0 to 10 mm and a swelling index of not more than 5 with a binder, pressing the mixture into briquettes, oxidizing the briquettes in a continuous material flow stream, and coking the oxidized briquettes continuously in an oven chamber by supplying indirectly and exhausting the coke oven gases with a temperature of 300.degree. to 1200.degree. C. The device for carrying out the process includes a vertically extending reactor housing having an oxidation chamber adjacent the top thereof with an indirectly heated vertical coking chamber directly below the oxidation chamber and with a cooling chamber directly below the coking chamber and including means for circulating heating gases into the coking chamber and then upwardly through the coking chamber and out adjacent the top of the coking chamber and into the oxidation chamber.
摘要:
A method of cooling and dedusting degasification gases which escape from coal degasification chambers particularly gases which are obtained in high temperature or low temperature carbonization of bituminous and subbituminous coals and which pass from degasification chambers through risers and bends into collection mains and in the bends or in the collecting mains themselves which comprises directing crude tar having a temperature in excess of 50.degree. C. and lower than 170.degree. C. into the bends and collecting mains either alone or with water added which has a temperature and is of a quantity such that it completely evaporates in the collecting main. An apparatus for carrying out the method includes means for spraying either the tar or the tar plus water into the collecting main containing the degasification gases and passing the gases and the liquids from the main into a cooler to separate the gases and a liquid condensate and the tar oil from the condensate and which includes means for directing the crude tar through a separator for separating the heavy tar from a remaining portion of the tar and further directing the remaining portion through a supply tank and a centrifuge for removing solid matter therefrom.
摘要:
A method of producing form coke, particularly metallurigical coke for a blast furnace, comprises, mixing at least two fine ground coal components, of which one is a non-caking component containing only little of volatile matter and comprises an oil coke, and the other is a caking bituminous coal, and at temperatures corresponding approximately to the softening point of the caking coal component. The mixture is carbonized and pressed to form a briquetted form coke, and the form coke is subsequently hardened.
摘要:
A continuous process is provided for scrubbing hydrogen sulfide and ammonia from coke oven gases by selectively scrubbing the hydrogen sulfide using aqueous ammonia, then distilling the hydrogen sulfide again from the wash liquor combining the ammonia directly with acids or certain acid salts, e.g., sulfuric acid or ammonium bisulfate, liberating the combined ammonia therefrom by decomposition, and then recycling the released ammonia to the hydrogen sulfide scrubber, thereby increasing the ratio of ammonia to hydrogen sulfide therein. A preferred absorbent for ammonia is monoammonium phosphate.