公开(公告)号：US4594097A

公开(公告)日：1986-06-10

申请号：US745749

申请日：1985-06-17

申请人： Rolf Schurter ,  Werner Fory ,  Willy Meyer

发明人： Rolf Schurter ,  Werner Fory ,  Willy Meyer

IPC分类号： C07D251/16 ,  A01N47/36 ,  C07C67/00 ,  C07C301/00 ,  C07D239/42 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D251/42 ,  C07D401/12 ,  C07D409/12 ,  C07D521/00 ,  C07D251/50 ,  A01N43/70 ,  C07D251/52

CPC分类号： C07D521/00 ,  A01N47/36

摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein A is a radical of the formula --C.tbd.C--R,m is 1 or 2,Z is oxygen or sulfur,R is hydrogen; unsubstituted or substituted, branched or unbranched C.sub.1 -C.sub.9 alkyl; unsubstituted or substituted C.sub.3 -C.sub.9 cycloalkyl; unsubstituted or substituted phenyl; or an unsubstituted or substituted 5- or 6-membered aromatic heterocyclic ring,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, --NR.sub.9 R.sub.10 or --O--CH.sub.2 --CH.sub.2 --NR.sub.9 R.sub.10,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.9 is hydrogen, methyl or ethyl,R.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, methoxymethyl, cyanomethyl, cyanoethyl, C.sub.3 -C.sub.5 alkenyl or C.sub.3 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridgeand the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.

摘要翻译： N-苯基磺酰基-N'-嘧啶基脲和通式I的N-苯基磺酰基-N'-三嗪基脲其中A是式-CB 3 CR的基团，m是1或2，Z是氧 或硫，R是氢; 未取代或取代的支链或非支链C 1 -C 9烷基; 未取代或取代的C 3 -C 9环烷基; 未取代或取代的苯基; 或未取代或取代的5元或6元芳族杂环，R 1为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基或自由基-Y-R 5，R 2为氢，卤素，C 1 -C 5烷基，C 2 -C 5链烯基， C1-C4卤代烷基或自由基-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4各自独立地为氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基， C1-C4卤代烷基，C1-C4卤代烷氧基，C1-C4卤代烷硫基，卤素，C2-C5烷氧基烷基，-NR9R10或-O-CH2-CH2-NR9R10，R5和R6各自独立地为C1-C5烷基，C2-C5链烯基或C2 C 1-6炔基，C 1 -C 5卤代烷基，C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基，R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，R 9为氢，甲基或乙基，R 10为 氢，C1-C4烷基，C1-C4烷氧基，甲氧基甲基，氰基甲基，氰乙基，C3-C5链烯基或C3-C6炔基，Y是氧，硫，亚磺酰基或磺酰基桥，这些化合物与胺，碱金属碱或碱 地球 金属碱基或季铵碱基，具有良好的出芽前和出芽后选择性除草和生长调节性质。

公开(公告)号：US4443243A

公开(公告)日：1984-04-17

申请号：US396959

申请日：1982-07-09

申请人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

发明人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

IPC分类号： A01N47/24 ,  A01N47/08 ,  A01N47/22 ,  A01N47/36 ,  C07C303/36 ,  C07C311/16 ,  C07C311/53 ,  C07C323/67 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D251/16 ,  C07D251/22 ,  C07D251/40 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00 ,  C07D251/44 ,  A01N43/66 ,  C07D251/42

CPC分类号： C07C311/65 ,  A01N47/36 ,  C07D239/47 ,  C07D239/48 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.

摘要翻译： 具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性，除草和生长调节性质。 该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个 或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8 各自独立地为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

公开(公告)号：US4523944A

公开(公告)日：1985-06-18

申请号：US571985

申请日：1984-01-19

申请人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

发明人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

IPC分类号： A01N43/54 ,  A01N47/36 ,  C07D239/42 ,  C07D239/48 ,  C07D251/22 ,  C07D521/00

CPC分类号： C07D239/48 ,  A01N47/36 ,  C07C317/00 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.

摘要翻译： 具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性，除草和生长调节性质。 该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个 或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8 各自独立地为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

公开(公告)号：US4565887A

公开(公告)日：1986-01-21

申请号：US571986

申请日：1984-01-19

申请人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

发明人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

IPC分类号： A01N47/24 ,  A01N47/08 ,  A01N47/22 ,  A01N47/36 ,  C07C303/36 ,  C07C311/16 ,  C07C311/53 ,  C07C323/67 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D251/16 ,  C07D251/22 ,  C07D251/40 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00 ,  C07C143/78 ,  C07C149/447

CPC分类号： C07C311/65 ,  A01N47/36 ,  C07D239/47 ,  C07D239/48 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.

摘要翻译： 具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性，除草和生长调节性质。 该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个 或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8 各自独立地为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

公开(公告)号：US4936903A

公开(公告)日：1990-06-26

申请号：US374322

申请日：1989-06-29

申请人： Rolf Schurter ,  Willy Meyer ,  Werner Fory

发明人： Rolf Schurter ,  Willy Meyer ,  Werner Fory

IPC分类号： A01N47/36 ,  C07D307/64 ,  C07D307/82 ,  C07D333/00 ,  C07D333/34 ,  C07D333/38 ,  C07D333/62 ,  C07D409/12 ,  C07D521/00

CPC分类号： C07D333/62 ,  A01N47/36 ,  C07D333/34 ,  C07D333/38 ,  C07D521/00

摘要： N-Pyridinylsulfonyl-N'-pyrimidinylureas and N-pyridinylsulfonyl-N'-triazinylureas of the formula ##STR1## wherein E is nitrogen or the methine bridge,Z is oxygen or sulfur,R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.5 and R.sup.6 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.3 -C.sub.6 dialkoxyalkyl, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.12 R.sup.13,G is a ##STR2## R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl, trifluoromethoxy, difluoromethoxy, C.sub.1 -C.sub.4 alkyl carbonyl or --COOR.sup.14,R.sup.3 is a ##STR3## group, n is 0, 1 or 2,R.sup.8 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 haloalkyl, nitro, --COOR.sup.14, C.sub.1 -C.sub.4 haloalkoxy, --O--CR.sup.15 R.sup.16 --COOR.sup.14 or --O--CR.sup.15 R.sup.16 --CN,R.sup.9 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkoxyalkyl oder C.sub.2 -C.sub.4 alkoxyalkoxy,R.sup.10 and R.sup.11 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.12 and R.sup.13 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.14 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl, or is C.sub.1 -C.sub.4 alkyl which is substituted by C.sub.1 -C.sub.4 alkoxy, halogen or phenyl, andR.sup.15 and R.sup.16 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl, and the salts thereof have useful selective herbicidal properties for controlling weeds in crops of useful plants.

公开(公告)号：US4932997A

公开(公告)日：1990-06-12

申请号：US719614

申请日：1985-04-03

申请人： Rolf Schurter ,  Willy Meyer ,  Werner Fory

发明人： Rolf Schurter ,  Willy Meyer ,  Werner Fory

IPC分类号： A01N47/36 ,  C07D307/64 ,  C07D307/82 ,  C07D333/00 ,  C07D333/34 ,  C07D333/38 ,  C07D333/62 ,  C07D409/12 ,  C07D521/00

CPC分类号： C07D333/62 ,  A01N47/36 ,  C07D333/34 ,  C07D333/38 ,  C07D521/00

摘要： N-Heterocyclosulfonyl-N'-pyrimidinylureas and N-heterocyclosulfonyl-N'-triazinylureas of the formula ##STR1## wherein E is nitrogen or the methine bridge,Z is oxygen or sulfur,R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.5 and R.sup.6 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.3 -C.sub.6 dialkoxyalkyl, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.12 R.sup.13,G is a ##STR2## group R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl, trifluoromethoxy, difluoromethoxy, C.sub.1 -C.sub.4 alkyl carbonyl or --COOR.sup.14,R.sup.2 is a ##STR3## group, R.sup.3 is a ##STR4## Q is oxygen, sulfur or --NR.sup.7 --,A is oxygen, sulfur, --SO--, --SO.sub.2 -- or --(CR.sup.10 R.sup.11).sub.m --,m and n are 0, 1 or 2,R.sup.7 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, benzyl oder phenyl,R.sup.8 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 haloalkyl, nitro, --COOR.sup.14, C.sub.1 -C.sub.4 haloalkoxy, --O--CR.sup.15 R.sup.16 --COOR.sup.14 or --O--CR.sup.15 R.sup.16 --CN,R.sup.9 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkoxyalkyl oder C.sub.2 -C.sub.4 alkoxyalkoxy,R.sup.10 and R.sup.11 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.12 and R.sup.13 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.14 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl, or is C.sub.1 -C.sub.4 alkyl which is substituted by C.sub.1 -C.sub.4 alkoxy, halogen or phenyl, andR.sup.15 and R.sup.16 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,and the salts thereof have useful selective herbicidal properties for controlling weeds in crops of useful plants.

公开(公告)号：US4875923A

公开(公告)日：1989-10-24

申请号：US114993

申请日：1987-10-26

申请人： Rolf Schurter ,  Willy Meyer ,  Werner Fory

发明人： Rolf Schurter ,  Willy Meyer ,  Werner Fory

IPC分类号： A01N47/36 ,  C07D307/64 ,  C07D307/82 ,  C07D333/00 ,  C07D333/34 ,  C07D333/38 ,  C07D333/62 ,  C07D409/12 ,  C07D521/00

CPC分类号： C07D333/62 ,  A01N47/36 ,  C07D333/34 ,  C07D333/38 ,  C07D521/00

摘要： N-Pyridinylsulfonyl-N'-pyrimidinylureas and N-pyridinylsulfonyl-N'-triazinylureas of the formula ##STR1## wherein E is nitrogen or the methine bridge,Z is oxygen or sulfur,R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.5 and R.sup.6 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.2 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.12 R.sup.13,G is a ##STR2## R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl, trifluoromethoxy, difluoromethoxy, C.sub.1 -C.sub.4 alkyl carbonyl or --COOR.sup.14,R.sup.3 is a ##STR3## group, n is 0, 1 or 2,R.sup.8 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 haloalkyl, nitro, --COOR.sup.14, C.sub.1 -C.sub.4 haloalkoxy, --O--CR.sup.15 R.sup.16 --CN,R.sup.9 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkoxyalkyl oder C.sub.2 -C.sub.4 alkoxylkoxy,R.sup.10 and R.sup.11 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.12 and R.sup.13 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.14 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl, or is C.sub.1 -C.sub.4 alkyl which is substituted by C.sub.1 -C.sub.4 alkoxy, halogen or phenyl, andR.sup.15 and R.sup.16 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl, and the salts thereof have useful selective herbicidal properties for controlling weeds in crops of useful plants.

摘要翻译： N-吡啶基磺酰基-N'-嘧啶基脲和式（I）的N-吡啶基磺酰基-N'-三嗪基脲其中E是氮或次甲基桥，Z是氧或硫，R4是氢或C1-C4烷基，R5 和R 6各自独立地为氢，卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 2 -C 4 - 烷硫基，C 3 -C 6环烷基或-NR 12 R 13，G为R 1为氢，卤素， 硝基，C 1 -C 4烷基，C 1 -C 4烷氧基，三氟甲基，三氟甲氧基，二氟甲氧基，C 1 -C 4烷基羰基或-COOR 14，R 3是一个基团，n是0,1或2，R 8是氢，C 1 -C 4烷基， C4烷氧基，卤素，C1-C4卤代烷基，硝基，-COOR14，C1-C4卤代烷氧基，-O-CR15R16-CN，R9是氢，卤素，C1-C4烷基，C1-C4烷氧基，C2-C4烷氧基烷基，C2-C4烷氧基烷氧基，R10和R11是 各自独立地为氢或C 1 -C 4烷基，R 12和R 13各自独立地为氢或C 1 -C 4烷基，R 14为氢，C 1 -C 4烷基，C 2 -C 4链烯基，C 3 -C 4炔基，或为被C 1 -C 4烷氧基，卤素 o R苯基，R15和R16各自独立地为氢或C1-C4烷基，其盐具有有用的选择性除草性质，用于控制有用植物作物中的杂草。

公开(公告)号：US4537618A

公开(公告)日：1985-08-27

申请号：US496326

申请日：1983-05-19

申请人： Rolf Schurter ,  Werner Fory ,  Willy Meyer

发明人： Rolf Schurter ,  Werner Fory ,  Willy Meyer

IPC分类号： C07D251/16 ,  A01N47/36 ,  C07C67/00 ,  C07C301/00 ,  C07D239/42 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D251/42 ,  C07D401/12 ,  C07D409/12 ,  C07D521/00

CPC分类号： C07D521/00 ,  A01N47/36

摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein A is a radical of the formula --C.tbd.C--R,m is 1 or 2,E is the methine group or nitrogen,Z is oxygen or sulfur,R is hydrogen; unsubstituted or substituted, branched or unbranched C.sub.1 -C.sub.9 alkyl; unsubstituted or substituted C.sub.3 -C.sub.9 cycloalkyl; unsubstituted or substituted phenyl; or an unsubstituted or substituted 5- or 6-membered aromatic heterocyclic ring,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, --NR.sub.9 R.sub.10 or --O--CH.sub.2 --CH.sub.2 --NR.sub.9 R.sub.10,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.9 is hydrogen, methyl or ethyl,R.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, methoxymethyl, cyanomethyl, cyanoethyl, C.sub.3 -C.sub.5 alkenyl or C.sub.3 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridgeand the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.

摘要翻译： N-苯基磺酰基-N'-嘧啶基脲和通式I（I）的N-苯基磺酰基-N'-三嗪基脲其中A是式-CB 3 CR的基团，m是1或2，E是 次甲基或氮，Z为氧或硫，R为氢; 未取代或取代的支链或非支链C 1 -C 9烷基; 未取代或取代的C 3 -C 9环烷基; 未取代或取代的苯基; 或未取代或取代的5元或6元芳族杂环，R 1为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基或自由基-Y-R 5，R 2为氢，卤素，C 1 -C 5烷基，C 2 -C 5链烯基， C1-C4卤代烷基或自由基-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4各自独立地为氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基， C1-C4卤代烷基，C1-C4卤代烷氧基，C1-C4卤代烷硫基，卤素，C2-C5烷氧基烷基，-NR9R10或-O-CH2-CH2-NR9R10，R5和R6各自独立地为C1-C5烷基，C2-C5链烯基或C2 C 1-6炔基，C 1 -C 5卤代烷基，C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基，R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，R 9为氢，甲基或乙基，R 10为 氢，C1-C4烷基，C1-C4烷氧基，甲氧基甲基，氰基甲基，氰乙基，C3-C5链烯基或C3-C6炔基，Y是氧，硫，亚磺酰基或磺酰基桥，这些化合物与胺，碱金属碱或碱 地球 金属碱基或季铵碱基，具有良好的出芽前和出芽后选择性除草和生长调节性质。

公开(公告)号：US5221315A

公开(公告)日：1993-06-22

申请号：US705459

申请日：1991-05-24

申请人： Werner Fory ,  Rolf Schurter

发明人： Werner Fory ,  Rolf Schurter

IPC分类号： A01N47/36 ,  C07D213/71 ,  C07D213/73 ,  C07D213/74 ,  C07D401/12 ,  C07D521/00

CPC分类号： C07D213/73 ,  A01N47/36 ,  C07D213/74 ,  C07D521/00

摘要： N-Pyridinesulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl; C.sub.2 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl substituted by halogen; C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl substituted by --NR.sub.5 R.sub.6, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkyl-S(O).sub.n --; C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl substituted by C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl, C.sub.2 -C.sub.6 alkynyl or C.sub.4 -C.sub.8 alkadienyl; or C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl and C.sub.4 -C.sub.8 alkadienyl substituted by halogen; or R.sub.1 and R.sub.2 together are a 4-5-membered C.sub.4 -C.sub.10 alkylene chain which can be interrupted by oxygen, sulfur or N--R.sub.7 ; R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 - C.sub.4 alkylthio; C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio substituted by halogen; R.sub.4, R.sub.5, R.sub.6 and R.sub.7 independently of one another are hydrogen or C.sub.1 -C.sub.4 alkyl; n is 0, 1 or 2; X is C.sub.1 -C.sub.3 alkyl, or C.sub.1 -C.sub.3 alkyl which is substituted by 1 to 3 halogens; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is substituted by 1 to 3 halogens; Y is halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkyl which is substituted by 1 to 3 halogens; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is substituted by 1 to 3 halogens; cyclopropyl, methylamino or dimethylamino; and E is nitrogen or the methine group, and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good selective herbicidal and growth-regulating properties when used pre- and post-emergence.

摘要翻译： 其中R 1和R 2彼此独立地是氢，C 1 -C 8烷基或C 3 -C 8环烷基的式I（I）的N-吡啶磺酰基-N'-嘧啶基 - 和 - 三嗪基脲; C 2 -C 8烷基或被卤素取代的C 3 -C 8环烷基; 被-NR 5 R 6，C 1 -C 4烷氧基或C 1 -C 4烷基-S（O）n取代的C 1 -C 8烷基或C 3 -C 8环烷基; 被C 2 -C 4烯基，C 5 -C 6环烯基，C 2 -C 6炔基或C 4 -C 8链烯基取代的C 1 -C 4烷基或C 3 -C 6环烷基; 或C 2 -C 4烯基，C 5 -C 6环烯基和被卤素取代的C 4 -C 8链二烯基; 或R 1和R 2一起是可被氧，硫或N-R 7中断的4-5元C 4 -C 10亚烷基链; R 3是氢，卤素，C 1 -C 4烷基，C 1 -C 4烷氧基或C 1 -C 4烷硫基; C 1 -C 4烷基，C 1 -C 4烷氧基或被卤素取代的C 1 -C 4烷硫基; R 4，R 5，R 6和R 7彼此独立地是氢或C 1 -C 4烷基; n为0,1或2; X是C 1 -C 3烷基或被1至3个卤素取代的C 1 -C 3烷基; C1-C3烷氧基或被1〜3个卤素取代的C1-C3烷氧基; Y为卤素，C1-C3烷基或被1〜3个卤素取代的C1-C3烷基; C1-C3烷氧基或被1〜3个卤素取代的C1-C3烷氧基; 环丙基，甲基氨基或二甲基氨基; E是氮或次甲基，这些化合物与胺，碱金属碱或碱土金属碱或季铵碱的盐在出苗前和出苗后使用时具有很好的选择性除草和生长调节特性。

公开(公告)号：US5407900A

公开(公告)日：1995-04-18

申请号：US096137

申请日：1993-07-22

申请人： Werner Fory ,  Rolf Schurter

发明人： Werner Fory ,  Rolf Schurter

IPC分类号： A01N47/36 ,  C07D401/12 ,  C07D521/00 ,  A01N43/66

CPC分类号： C07D521/00 ,  A01N47/36

摘要： (Cyclopropyl-triazinyl- and cyclopropyl-pyrimidinyl-)pyridylsulfonylureas of formula I ##STR1## wherein R and R.sub.1 are each independently of the other hydrogen or methyl;R.sub.2 is methyl, methoxy or ethoxy; andE is nitrogen or the methine group;and the salts of those compounds, have good selective herbicidal properties. The preparation of those compounds and the use thereof as herbicidal active ingredients are described.

摘要翻译： （I）的（环丙基 - 三嗪基 - 和环丙基 - 嘧啶基）吡啶磺酰脲其中R和R 1各自独立地为氢或甲基; R2是甲基，甲氧基或乙氧基; E为氮或次甲基; 和这些化合物的盐具有良好的选择性除草性质。 描述了这些化合物的制备及其作为除草活性成分的用途。