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公开(公告)号：US4354959A
公开(公告)日：1982-10-19
申请号：US289446
申请日：1981-08-03
申请人： Ronald A. Epstein , Robert I. Mink
发明人： Ronald A. Epstein , Robert I. Mink
CPC分类号： C08F10/00 , Y10S526/904
摘要： A catalytic system for polymerizing olefins comprises:(a) a component containing an organoaluminum compound, and(b) a component containing a titanium halide obtained by:(i) copulverizing a magnesium compound containing halogen or a manganese compound containing halogen with at least one electron-donor compound to produce a copulverized product,(ii) treating the copulverized product with an ether to produce a treated product, and(iii) reacting the treated product with a titanium chloride.The novel catalytic system is useful for polymerizing olefins such as ethylene and propylene.A process for producing the component containing a titanium halide is also provided.
摘要翻译： 用于聚合烯烃的催化体系包括：（a）含有机铝化合物的组分，和（b）含有卤化钛的组分，其通过以下步骤获得：（i）将含卤素的镁化合物或含有卤素的锰化合物与至少一种 电子给体化合物，以产生共混产物，（ii）用醚处理共成型产物以产生处理产物，和（iii）使处理过的产物与氯化钛反应。 新型催化体系可用于聚合烯烃如乙烯和丙烯。 还提供了制备含有卤化钛的组分的方法。
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公开(公告)号：US4364853A
公开(公告)日：1982-12-21
申请号：US303329
申请日：1981-09-18
申请人： Robert I. Mink , Ronald A. Epstein
发明人： Robert I. Mink , Ronald A. Epstein
CPC分类号： C08F10/00
摘要： A catalytic system for polymerizing olefins comprises:(a) a component containing an organoaluminum compound, and(b) a component containiong a titanium halide prepared by a process comprising:(i) intimately contacting a magnesium compound containing halogen or a manganese compound containing halogen with a carboxylic acid to produce an activated product,(ii) optionally treating the activated product with a phenol, and(iii) reacting the activated product, optionally treated with phenol, with a titanium halide compound.The invention also includes a process for preparing component (b) containing a titanium halide, the composition of component (b), and the use of the catalytic system for polymerizing olefins such as ethylene or propylene.
摘要翻译： 用于聚合烯烃的催化体系包括：（a）含有有机铝化合物的组分，和（b）含有卤化钛的组分，其通过以下方法制备，所述方法包括：（i）使含有卤素的镁化合物或含有卤素的锰化合物 与羧酸反应以产生活化产物，（ii）任选地用苯酚处理活化产物，和（iii）将任选用苯酚处理的活化产物与卤化钛化合物反应。 本发明还包括制备含有卤化钛的组分（b），组分（b）的组合物以及用于聚合烯烃如乙烯或丙烯的催化体系的方法。
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公开(公告)号：US4347160A
公开(公告)日：1982-08-31
申请号：US163615
申请日：1980-06-27
申请人： Ronald A. Epstein , Robert I. Mink
发明人： Ronald A. Epstein , Robert I. Mink
CPC分类号： C08F10/00 , Y10S526/904
摘要： A novel catalyst system for the polymerization of alpha-olefins is provided. The catalyst system comprises: (a) an organoaluminum containing component, e.g. triethyl aluminum, and (b) a titanium halide containing component. The titanium halide containing component is obtained by co-pulverizing a halogen containing magnesium compound, e.g. MgCl.sub.2, with an electron-donor compound, e.g. ethyl benzoate, to produce a co-pulverized product. The co-pulverized product is then reacted with an organic phosphite, e.g. triphenyl phosphite, to produce a reaction product. The reaction product is then reacted with a titanium halide compound, e.g. TiCl.sub.4.A novel titanium halide containing component is provided as well as a process for producing said component. A process for the polymerization of alpha-olefins is also provided.
摘要翻译： 提供了一种用于α-烯烃聚合的新型催化剂体系。 催化剂体系包括：（a）含有机铝的组分，例如 三乙基铝，和（b）含卤化钛的组分。 含卤化钛的组分是通过将含卤素的镁化合物，例如， MgCl 2与电子给体化合物，例如 苯甲酸乙酯，以产生共粉碎产物。 然后将共粉碎产物与有机亚磷酸酯反应，例如 亚磷酸三苯酯，产生反应产物。 然后使反应产物与卤化钛化合物反应。 TiCl4。 提供了新颖的含卤化钛的组分以及制备所述组分的方法。 还提供了α-烯烃聚合方法。
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公开(公告)号：US4325836A
公开(公告)日：1982-04-20
申请号：US170262
申请日：1980-07-18
申请人： Ronald A. Epstein , Robert I. Mink
发明人： Ronald A. Epstein , Robert I. Mink
摘要： A novel catalyst system for the polymerization of alpha-olefins is provided. The catalyst system comprises:(a) an organoaluminum containing component, e.g. triethyl aluminum, and(b) a titanium halide containing component.The titanium halide containing component is obtained by reacting a halogen containing magnesium compound, e.g. MgCl.sub.2, with an organic phosphite, e.g. triphenyl phosphite, to produce a reaction product. The reaction product is then co-pulverized with a complex of a titanium halide compound and an electron donor compound, e.g. TiCl.sub.4.ethyl benzoate, to produce a co-pulverized product. The co-pulverized product is then reacted with a titanium halide compound, e.g. TiCl.sub.4.A novel titanium halide containing component is provided as well as a process for producing said component. A process for the polymerization of alpha-olefins is also provided.
摘要翻译： 提供了一种用于α-烯烃聚合的新型催化剂体系。 催化剂体系包括：（a）含有机铝的组分，例如 三乙基铝，和（b）含卤化钛的组分。 含卤化钛的组分是通过使含卤素的镁化合物，例如， MgCl 2与有机亚磷酸酯，例如 亚磷酸三苯酯，产生反应产物。 然后将反应产物与卤化钛化合物和电子给体化合物的络合物共粉碎，例如。 苯甲酸TiCl 4乙酯，以产生共粉碎产物。 然后将共粉碎产物与卤化钛化合物反应，例如 TiCl4。 提供了新颖的含卤化钛的组分以及制备所述组分的方法。 还提供了α-烯烃聚合方法。
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公开(公告)号：US4384984A
公开(公告)日：1983-05-24
申请号：US307036
申请日：1981-09-30
申请人： Robert I. Mink , Ronald A. Epstein
发明人： Robert I. Mink , Ronald A. Epstein
CPC分类号： C08F10/00
摘要： A catalytic system for polymerizing olefins contains an organoaluminum compound and a component containing titanium halide on a support of a magnesium or manganese compound containing halogen, which is obtained by (i) pretreating the support with an ether, (ii) intimately contacting the support with an electron donor, to activate it, and (iii) reacting the activated support with a titanium halide, such as titanium tetrachloride.The invention also includes the process for preparing the titanium component, the composition of the titanium component, and the use of the novel catalytic system to polymerize olefins.
摘要翻译： 用于聚合烯烃的催化体系包含有机铝化合物和在含有卤素的镁或锰化合物的载体上的含有卤化钛的组分，其通过以下步骤获得：（i）用醚预处理载体，（ii）使载体与 电子给体，以使其活化，和（iii）使活化的载体与卤化钛如四氯化钛反应。 本发明还包括制备钛组分的方法，钛组分的组成以及新型催化体系聚合烯烃的用途。
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公开(公告)号：US4713484A
公开(公告)日：1987-12-15
申请号：US945257
申请日：1986-12-22
申请人： Ronald A. Epstein
发明人： Ronald A. Epstein
IPC分类号： B01J31/24 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/10 , C07C57/32 , C07C67/00 , C07C67/36 , C07C69/614 , C07C51/14
CPC分类号： C07C51/10
摘要： A process for preparing carboxylic acid salts by the reaction of carbon monoxide with substituted or unsubstituted aromatic halides or an aliphatic organic halide. The process comprises the catalytic single phase carbonylation of the halide utilizing in addition to carbon monoxide, a palladium catalyst, an excess of tertiary phosphine, optionally an amine compound, with an alkali metal or alkaline earth metal base added during the reaction to form the salt.
摘要翻译： 通过一氧化碳与取代或未取代的芳族卤化物或脂族有机卤化物的反应制备羧酸盐的方法。 该方法包括使用除了一氧化碳，钯催化剂，过量的叔膦，任选的胺化合物，在反应期间加入碱金属或碱土金属碱以形成盐的催化单相羰基化 。
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7.发明授权公开(公告)号：US06288005B1
公开(公告)日：2001-09-11
申请号：US08314568
申请日：1994-09-28
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F4/6565
摘要： A catalyst component, adapted for use in the polymerization and copolymerization of ethylene, is formed by reaction of an organomagnesium compound with a metal oxide support to form a supported organomagnesium composition, reaction of the supported organomagnesium composition and a tetraalkyl silicate, contact of the resulting product with a chlorinating reagent, and treatment of the product from the previous step with liquid titanium halide.
摘要翻译： 适用于乙烯聚合和共聚的催化剂组分是通过有机镁化合物与金属氧化物载体的反应形成负载的有机镁组合物，负载的有机镁组合物与硅烷四烷基酯的反应形成的， 产品与氯化试剂，并用前面的步骤用液体卤化钛处理产物。
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公开(公告)号：US4761499A
公开(公告)日：1988-08-02
申请号：US56636
申请日：1987-06-02
申请人： Ronald A. Epstein
发明人： Ronald A. Epstein
IPC分类号： C07C51/10 , C07C51/14 , C07C67/36 , C07C102/00
CPC分类号： C07C51/10
摘要： High yields of olefinic esters and amides, and the like are derived from a process wherein vinyl dihalides are carbonylated in the presence of a palladium catalyst and a primary or secondary amine base or tertiary amine, depending on the desired product, and a solvent.
摘要翻译： 高产率的烯烃酯和酰胺等衍生自其中乙烯基二卤化物在钯催化剂和伯胺或仲胺碱或叔胺存在下羰基化的方法，这取决于所需产物和溶剂。
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公开(公告)号：US4668816A
公开(公告)日：1987-05-26
申请号：US796687
申请日：1985-11-12
申请人： Ronald A. Epstein
发明人： Ronald A. Epstein
CPC分类号： C07C51/10
摘要： High yields of aromatic, aromatic acetic and olefinic acids, esters, amides and the like are derived from a process wherein a halo-hydrocarbon is carbonylated in the presence of a palladium catalyst, a hindered amine base and phosphine in excess. The hindered amine base can comprise C.sub.3 -C.sub.10 branched alkyls, cyclic compounds, or mixtures of the above. The preferred amine is N,N-diisopropylethyl amine. The preferred catalyst is PdCl.sub.2 (PPH.sub.3).sub.2 with the excess phosphine generally supplied by a compound of the formula PR.sup.1 R.sup.2 R.sup.3 where R.sup.1, R.sup.2 and R.sup.3 are preferably phenyl.
摘要翻译： 芳烃，芳族乙酸和烯酸，酯，酰胺等的高收率源自其中卤代烃在钯催化剂，受阻胺碱和过量的膦的存在下羰基化的方法。 受阻胺碱可以包含C 3 -C 10支链烷基，环状化合物或其混合物。 优选的胺是N，N-二异丙基乙胺。 优选的催化剂是PdCl 2（PPH 3）2，其中过量的膦通常由式PR1R2R3的化合物提供，其中R1，R2和R3优选为苯基。
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10.发明授权Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations 失效氟化烷氧基和/或芳氧基铝酸盐作为茂金属催化烯烃聚合的助催化剂
公开(公告)号：US5895771A
公开(公告)日：1999-04-20
申请号：US870354
申请日：1997-06-05
IPC分类号： B01J31/14 , B01J31/22 , C08F4/642 , C08F4/6592 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： B01J31/143 , B01J31/2295 , C08F10/00 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65925 , Y10S526/943
摘要： Catalyst compositions for the polymerization of an olefin are disclosed which comprise a neutral metallocene and, as the ionizing agent an anionic aluminum-containing complex which is a fluorinated alkoxy and/or aryloxy aluminate. The fluorinated alkoxy aluminate can be of the formula A.sup.+ (Al(OR).sub.4).sup.-, where A.sup.+ is a cation capable of reacting with the neutral metallocene to produce a cationic metallocene and a non-reacting neutral species and R is a fluorinated alkyl and/or aryl group, with a representative group for A.sup.+ being (C.sub.6 H.sub.5).sub.3 C.sup.+ and with the representative fluorinated alkoxy aluminates including �Al(OC(Ph)(CF.sub.3).sub.2).sub.4 !.sup.-, where Ph is phenyl, and �Al(OC(CH.sub.3)(CF.sub.3).sub.2).sub.4 !.sup.-.
摘要翻译： 公开了用于烯烃聚合的催化剂组合物，其包含中性茂金属，并且作为电离剂是作为氟化烷氧基和/或芳氧基铝酸盐的阴离子含铝络合物。 氟化烷氧基铝酸盐可以是式A +（Al（OR）4） - ，其中A +是能够与中性茂金属反应以产生阳离子茂金属和非反应中性物质的阳离子，R是氟化烷基， 具有代表性的基团为A +为（C 6 H 5）3 C +，代表性的氟化烷氧基铝酸盐包括[Al（OC（Ph）（CF 3）2）4] - ，其中Ph为苯基，[Al （CH 3）（CF 3）2）4] - 。
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