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    NANOSCALE HELICAL MICROSTRUCTURES AND CHANNELS FROM CHIRAL POLY(L-LACTIDE) BLOCK CONTAINING BLOCK COPOLYMERS
    1.
    发明申请
    NANOSCALE HELICAL MICROSTRUCTURES AND CHANNELS FROM CHIRAL POLY(L-LACTIDE) BLOCK CONTAINING BLOCK COPOLYMERS 失效
    包含嵌段共聚物的聚合物（L-LACTIDE）嵌段的纳米尺寸螺旋微结构和通道

    公开(公告)号：US20060211816A1

    公开(公告)日：2006-09-21

    申请号：US10799845

    申请日：2004-03-12

    申请人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy Wang

    发明人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy Wang

    IPC分类号： C08F8/00

    CPC分类号： C08L53/00 ,  C08F293/005 ,  G03F7/0002

    摘要： A method for making a series of nanoscale microstructures, including helical microstructures and cylindrical microstructures. This method includes the steps of: (1) forming a chiral block copolymer containing a plurality of chiral first polymer blocks and a second polymer blocks wherein the chiral first polymer blocks have a volume fraction ranging from 20 to 49%; (2) causing a phase separation in the chiral block copolymer. In a preferred embodiment, the chiral block copolymer is poly(styrene)-poly(L-lactide) (PS-PLLA) chiral block copolymer, and the copolymerization process is a living copolymerization process which includes the following steps: (a) mixing styrene with BPO and 4-OH-TEMPO to form 4-hydroxy-TEMPO-terminated polystyrene; and (2) mixing the 4-hydroxy-TEMPO-terminated polystyrene with [(η3-EDBP)Li2]2[(η3-nBu)Li(0.5Et2O)]2 and L-lactide in an organic solvent preferably CH2Cl2 to form the poly(styrene)-poly(L-lactide) chiral block copolymer. Transmission electron microscopy (TEM) and small X-ray scattering (SAXS) studies show that when the volume fraction of poly(L-lactide) is about 35-37%, nanoscale helices with a pitch of 43.8 nanometers and a diameter of 34.4 nanometers were observed.

    摘要翻译： 制备一系列纳米级微观结构的方法，包括螺旋微结构和圆柱微结构。 该方法包括以下步骤：（1）形成含有多个手性第一聚合物嵌段的手性嵌段共聚物和第二聚合物嵌段，其中手性第一聚合物嵌段具有20至49％的体积分数; （2）引起手性嵌段共聚物中的相分离。 在优选的实施方案中，手性嵌段共聚物是聚（苯乙烯） - 聚（L-丙交酯）（PS-PLLA）手性嵌段共聚物，共聚方法是一种活性共聚方法，其包括以下步骤：（a） 用BPO和4-OH-TEMPO形成4-羟基-TEMPO封端的聚苯乙烯; 和（2）将4-羟基-TEMPO封端的聚苯乙烯与[（η3 -EBP）Li 2 N 2 [（η 在有机溶剂中，Li（0.5Et 2 O）] 2 N和L - 丙交酯 优选CH 2 2 Cl 2以形成聚（苯乙烯） - 聚（L-丙交酯）手性嵌段共聚物。 透射电子显微镜（TEM）和小X射线散射（SAXS）研究表明，当聚（L-丙交酯）的体积分数为约35-37％时，具有43.8纳米的间距和34.4纳米的直径的纳米级螺旋 被观察到。

    Nanoscale helical microstructures and channels from chiral poly(L-lactide) block containing block copolymers
    2.
    发明授权
    Nanoscale helical microstructures and channels from chiral poly(L-lactide) block containing block copolymers 失效
    来自手性聚（L-丙交酯）嵌段的嵌段共聚物的纳米级螺旋微结构和通道

    公开(公告)号：US07135523B2

    公开(公告)日：2006-11-14

    申请号：US10799845

    申请日：2004-03-12

    申请人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy S. J. Wang

    发明人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy S. J. Wang

    IPC分类号： C08G63/08

    CPC分类号： C08L53/00 ,  C08F293/005 ,  G03F7/0002

    摘要： A method for making a series of nanoscale microstructures, including helical microstructures and cylindrical microstrustures. This method includes the steps of: (1) forming a chiral block copolymer containing a plurality of chiral first polymer blocks and a second polymer blocks wherein the chiral first polymer blocks have a volume fraction ranging from 20 to 49%; (2) causing a phase separation in the chiral block copolymer. In a preferred embodiment, the chiral block copolymer is poly(styrene)-poly(L-lactide) (PS-PLLA) chiral block copolymer, and the copolymerization process is a living copolymerization process which includes the following steps: (a) mixing styrene with BPO and 4-OH-TEMPO to form 4-hydroxy-TEMPO-terminated polystyrene; and (2) mixing the 4-hydroxy-TEMPO-terminated polystyrene with [η3-EDBP)Li2]2[(η3-nBu)Li(0.5Et2O)]2 and L-lactide in an organic solvent preferably CH2Cl2 to form the poly(styrene)-poly(L-lactide) chiral block copolymer. Transmission electron microscopy (TEM) and small X-ray scattering (SAXS) studies show that when the volume fraction of poly(L-lactide) is about 35–37%, nanoscale helices with a pitch of 43.8 nanometers and a diameter of 34.4 nanometers were observed.

    摘要翻译： 一种制备一系列纳米级微观结构的方法，包括螺旋微结构和圆柱形微结构。 该方法包括以下步骤：（1）形成含有多个手性第一聚合物嵌段的手性嵌段共聚物和第二聚合物嵌段，其中手性第一聚合物嵌段具有20至49％的体积分数; （2）引起手性嵌段共聚物中的相分离。 在优选的实施方案中，手性嵌段共聚物是聚（苯乙烯） - 聚（L-丙交酯）（PS-PLLA）手性嵌段共聚物，共聚方法是一种活性共聚方法，其包括以下步骤：（a） 用BPO和4-OH-TEMPO形成4-羟基-TEMPO封端的聚苯乙烯; 和（2）将4-羟基-TEMPO封端的聚苯乙烯与[η3 -EDBP] Li 2 N 2 [2] 优选的有机溶剂中的L 3→N 2→Bu）Li（0.5E 2 O 2）2 N 2和L-丙交酯 CH 2 2 Cl 2以形成聚（苯乙烯） - 聚（L-丙交酯）手性嵌段共聚物。 透射电子显微镜（TEM）和小X射线散射（SAXS）研究表明，当聚（L-丙交酯）的体积分数为约35-37％时，具有43.8纳米的间距和34.4纳米的直径的纳米级螺旋 被观察到。

    Nanopatterned templates from oriented degradable diblock copolymer thin films
    3.
    发明授权
    Nanopatterned templates from oriented degradable diblock copolymer thin films 有权
    来自定向可降解二嵌段共聚物薄膜的纳米图案模板

    公开(公告)号：US07632544B2

    公开(公告)日：2009-12-15

    申请号：US10850169

    申请日：2004-05-18

    申请人： Rong-Ming Ho ,  Hui-Wen Fan ,  Wen-Hsien Tseng ,  Yeo-Wan Chiang ,  Chu-Chien Lin ,  Bao-Tsan Ko ,  Bor-Hunn Huang ,  Hsi-Hsin Shih ,  Joung-Yei Chen

    发明人： Rong-Ming Ho ,  Hui-Wen Fan ,  Wen-Hsien Tseng ,  Yeo-Wan Chiang ,  Chu-Chien Lin ,  Bao-Tsan Ko ,  Bor-Hunn Huang ,  Hsi-Hsin Shih ,  Joung-Yei Chen

    IPC分类号： B05D3/00 ,  B05D5/00

    CPC分类号： C08F8/50 ,  B82Y30/00 ,  C08J5/005 ,  Y10T428/24802 ,  Y10T428/31786 ,  C08F297/00

    摘要： A nanopatterned template for use in manufacturing nanoscale objects. The nanopatterned template contains a nanoporous thin film with a periodically ordered porous geomorphology which is made from a process comprising the steps of: (a) using a block copolymerization process to prepare a block copolymer comprising first and second polymer blocks, the first and second polymer blocks being incompatible with each other; (b) forming a thin film under conditions such that the first polymer blocks form into a periodically ordered topology; and (c) selectively degrading the first polymer blocks to cause the thin film to become a nanoporous material with a periodically ordered porous geomorphology. In a preferred embodiment, the block copolymer is poly(styrene)-poly(L-lactide) (PS-PLLA) chiral block copolymer, the first polymer is poly(L-lactide), and the second polymer is polystyrene. Experimental results show that the first polymer blocks can be formed into a hexagonal cylindrical geomorphology with its axis perpendicular to a surface of the thin film. After hydrolysis to selectively degrade the first polymer blocks, a thin film having a series of repeated nanoscale hexagonal-cylindrical channels is obtained.

    摘要翻译： 用于制造纳米尺度物体的纳米图案模板。 纳米图案模板包含具有周期性排序的多孔地貌的纳米多孔薄膜，其由包括以下步骤的方法制备：（a）使用嵌段共聚方法制备包含第一和第二聚合物嵌段的嵌段共聚物，第一和第二聚合物 块相互不兼容; （b）在使第一聚合物嵌段形成周期排序的拓扑的条件下形成薄膜; 和（c）选择性降解第一聚合物嵌段以使薄膜成为具有定期多孔的地貌的纳米多孔材料。 在优选的实施方案中，嵌段共聚物是聚（苯乙烯） - 聚（L-丙交酯）（PS-PLLA）手性嵌段共聚物，第一聚合物是聚（L-丙交酯），第二聚合物是聚苯乙烯。 实验结果表明，第一聚合物嵌段可以形成六边形圆柱形地貌，其轴线垂直于薄膜表面。 在水解以选择性降解第一聚合物嵌段之后，获得具有一系列重复的纳米级六边形柱形通道的薄膜。

    Metal nanodot arrays and fabrication methods thereof
    4.
    发明申请
    Metal nanodot arrays and fabrication methods thereof 审中-公开
    金属纳米点阵列及其制造方法

    公开(公告)号：US20060124467A1

    公开(公告)日：2006-06-15

    申请号：US11300327

    申请日：2005-12-15

    申请人： Rong-Ming Ho ,  In-Mau Chen ,  Yu-Tsan Tseng ,  Bao-Tsan Ko ,  Wen-Hsien Tseng

    发明人： Rong-Ming Ho ,  In-Mau Chen ,  Yu-Tsan Tseng ,  Bao-Tsan Ko ,  Wen-Hsien Tseng

    IPC分类号： C25D5/02 ,  C25D11/02

    CPC分类号： C08J5/005 ,  B82Y30/00 ,  C08F8/50 ,  C08F297/00

    摘要： Metal nanodot arrays and fabrication methods thereof. A film of a block copolymer is deposited on a conductive substrate. The block copolymer comprises first polymer and second polymer blocks, wherein the first polymer blocks have a periodically ordered morphology. The first polymer blocks are selectively degraded to form a nanopatterned template comprising periodically ordered nanochannels. By electroplating, metal is deposited into the nanochannels that expose the conductive substrate, thus forming a metal nanodot array.

    摘要翻译： 金属纳米点阵列及其制造方法。 将嵌段共聚物膜沉积在导电基材上。 嵌段共聚物包含第一聚合物和第二聚合物嵌段，其中第一聚合物嵌段具有周期性排序的形态。 第一聚合物嵌段被选择性地降解以形成包含周期性有序的纳米通道的纳米图案化模板。 通过电镀，将金属沉积到暴露导电基底的纳米通道中，从而形成金属纳米点阵列。

    Fabrication method of nanomaterials by using polymeric nanoporous templates
    5.
    发明申请
    Fabrication method of nanomaterials by using polymeric nanoporous templates 审中-公开
    使用聚合纳米多孔模板制备纳米材料的方法

    公开(公告)号：US20110003069A1

    公开(公告)日：2011-01-06

    申请号：US12655342

    申请日：2009-12-29

    申请人： Rong-Ming Ho ,  Han-Yu Hsueh ,  Ming-Shiuan She ,  Wen-Hsien Tseng ,  Chun-Ku Chen ,  Yeo-Wan Chiang

    发明人： Rong-Ming Ho ,  Han-Yu Hsueh ,  Ming-Shiuan She ,  Wen-Hsien Tseng ,  Chun-Ku Chen ,  Yeo-Wan Chiang

    IPC分类号： B05D5/12 ,  B05D3/02 ,  B05D3/06

    CPC分类号： C01G23/006 ,  C01B33/18 ,  C01G23/053 ,  C01P2004/04 ,  C08J9/26 ,  C08J2201/0462

    摘要： A fabrication method of a nanomaterial by using a polymeric nanoporous template is disclosed. First, a block copolymer bulk is made from a block copolymer polymerized from decomposable and undecomposable monomers. By removing the decomposable portion of the block copolymer bulk, the polymeric nanoporous template with a plurality of holes is obtained, and these holes have nanostructures with regular arrangement. By exploiting a nanoreactor concept, a sol-gel process or an electrochemical synthesis, for example, is then carried out within the template such that the holes are filled with various filler materials, such as ceramics, metals and polymers, so as to prepare a nanocomposite material having the nanostructure. After removing the polymeric nanoporous template, the nanomaterial with the nanostructure is manufactured.

    摘要翻译： 公开了通过使用聚合物纳米多孔模板制备纳米材料的方法。 首先，由可分解和不可分解的单体聚合的嵌段共聚物制成嵌段共聚物体。 通过除去嵌段共聚物本体的可分解部分，获得具有多个孔的聚合纳米多孔模板，并且这些孔具有规则排列的纳米结构。 通过利用纳米反应器的概念，例如在模板内进行溶胶 - 凝胶法或电化学合成，使得孔用诸如陶瓷，金属和聚合物的各种填充材料填充，从而制备 具有纳米结构的纳米复合材料。 在去除聚合物纳米多孔模板之后，制造具有纳米结构的纳米材料。