-
公开(公告)号：US08466214B2
公开(公告)日：2013-06-18
申请号：US13057555
申请日：2009-08-04
申请人： Rosangela Pirri , Philippe Hajji
发明人： Rosangela Pirri , Philippe Hajji
CPC分类号： C08F2/38 , C08F2/22 , C08L51/04 , C08L63/00 , C08L67/00 , C08L69/00 , Y10T428/2998 , C08L2666/24 , C08L2666/02
摘要： Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.
摘要翻译： 本文提供了制备核心和核 - 壳共聚物的方法。 用于制备交联的弹性体芯颗粒的方法包括在自由基聚合引发剂存在下，将含有至少一种烯属弹性体单体，至少一种交联剂和至少一种下式I的含硫添加剂的聚合混合物乳液聚合 其中R和Z在本文中定义。 形成的核 - 壳共聚物可用作例如聚合物基质中的添加剂，例如用于改善冲击强度和改善光学性能。
-
公开(公告)号：US20090018248A1
公开(公告)日：2009-01-15
申请号：US12279225
申请日：2007-02-09
申请人： Rosangela Pirri , Philippe Hajji
发明人： Rosangela Pirri , Philippe Hajji
CPC分类号： C08K9/10 , C08K2003/265 , C08L27/06 , C08L69/00
摘要： The present invention relates to hybrid impact modifiers prepared by: either spray drying, coagulation, freeze coagulation or other known recovery methods of a mixture of a latex or slurry of standard impact modifiers and a slurry of a mineral filler, either simultaneous drying (by spray-drying, coagulation other known recovery possible methods) of (i) a latex or slurry of standard impact modifiers and of (ii) a slurry of a mineral filler, further to the coagulation or freeze coagulation, if any, there is a filtration and drying step to recover these hybrid impact modifiers as a powder. The host polymers to be impact modified, can be any thermoplastic. Advantageously it can be polyvinyl chloride (PVC), polyamide (PA), polymethyl methacrylate (PMMA), polystyrene (PS), polycarbonate (PC), thermoplastic polyesters such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polycyclohexanedimethanol terephthalate, and polyolefins such as polyethylene (PE), polypropylene (PP), and any other matrix polymer which can be improved by an impact modifier.The present invention also relates to the use of said hybrid impact modifiers in thermoplastic polymers.The present invention also relates to a thermoplastic polymer containing said hybrid impact modifiers.The present invention also relates to hybrid impact modifiers having improved powder properties (flowability, lumping/caking resistance, segregation between the organic and the mineral parts).The present invention also relates to a thermoplastic polymer containing said hybrid impact modifiers with better dispersion homogeneities.
摘要翻译： 本发明涉及混合冲击改性剂，其通过以下方法制备：通过喷雾干燥，凝固，冷冻凝固或其它已知的标准冲击改性剂的胶乳或浆料的混合物的回收方法和矿物填料的浆料，同时干燥（通过喷雾 （i）标准冲击改性剂的胶乳或浆料，以及（ii）矿物填料的浆料，进一步凝固或冷冻凝结（如果有的话）有过滤和 干燥步骤以回收这些混合冲击改性剂作为粉末。 要进行冲击改性的主体聚合物可以是任何热塑性塑料。 有利地，它可以是聚氯乙烯（PVC），聚酰胺（PA），聚甲基丙烯酸甲酯（PMMA），聚苯乙烯（PS），聚碳酸酯（PC），热塑性聚酯如聚对苯二甲酸乙二醇酯（PET），聚对苯二甲酸丁二醇酯（PBT） 和聚烯烃如聚乙烯（PE），聚丙烯（PP）以及任何可通过抗冲改性剂改进的基体聚合物。 本发明还涉及所述混合冲击改性剂在热塑性聚合物中的用途。 本发明还涉及含有所述混合冲击改性剂的热塑性聚合物。 本发明还涉及具有改进的粉末性质（流动性，结块/耐结块性，有机和矿物部件之间的偏析）的混合冲击改性剂。 本发明还涉及含有具有更好的分散均匀性的所述混合冲击改性剂的热塑性聚合物。
-
公开(公告)号：US08378013B2
公开(公告)日：2013-02-19
申请号：US12279225
申请日：2007-02-09
申请人： Rosangela Pirri , Philippe Hajji
发明人： Rosangela Pirri , Philippe Hajji
CPC分类号： C08K9/10 , C08K2003/265 , C08L27/06 , C08L69/00
摘要： The present invention relates to hybrid impact modifiers prepared by: either spray drying, coagulation, freeze coagulation or other known recovery methods of a mixture of a latex or slurry of standard impact modifiers and a slurry of a mineral filler, or simultaneous drying (by spray-drying, coagulation other known recovery possible methods) of (i) a latex or slurry of standard impact modifiers and of (ii) a slurry of a mineral filler, further to the coagulation or freeze coagulation, if any, there is a filtration and drying step to recover these hybrid impact modifiers as a powder. The present invention also relates to the use of said hybrid impact modifiers in thermoplastic polymers, and a thermoplastic polymer containing said hybrid impact modifiers. The hybrid impact modifiers may exhibit improved powder properties (flowability, lumping/caking resistance, segregation between the organic and the mineral parts) and better dispersion homogeneities.
摘要翻译： 本发明涉及通过以下方法制备的混合抗冲改性剂：喷雾干燥，凝固，冷冻凝固或其它已知的标准冲击改性剂的胶乳或浆料的混合物的回收方法和矿物填料的浆料，或同时干燥（通过喷雾 （i）标准冲击改性剂的胶乳或浆料，以及（ii）矿物填料的浆料，进一步凝固或冷冻凝结（如果有的话）有过滤和 干燥步骤以回收这些混合冲击改性剂作为粉末。 本发明还涉及所述混合抗冲改性剂在热塑性聚合物中的用途，以及含有所述混合抗冲改性剂的热塑性聚合物。 混合冲击改性剂可以表现出改善的粉末性质（流动性，结块/结块性，有机和矿物部分之间的偏析）和更好的分散均匀性。
-
公开(公告)号：US20110136980A1
公开(公告)日：2011-06-09
申请号：US13057555
申请日：2009-08-04
申请人： Rosangela Pirra , Philippe Hajji
发明人： Rosangela Pirra , Philippe Hajji
CPC分类号： C08F2/38 , C08F2/22 , C08L51/04 , C08L63/00 , C08L67/00 , C08L69/00 , Y10T428/2998 , C08L2666/24 , C08L2666/02
摘要： Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.
摘要翻译： 本文提供了制备核心和核 - 壳共聚物的方法。 用于制备交联的弹性体芯颗粒的方法包括在自由基聚合引发剂存在下，将含有至少一种烯属弹性体单体，至少一种交联剂和至少一种下式I的含硫添加剂的聚合混合物乳液聚合 其中R和Z在本文中定义。 形成的核 - 壳共聚物例如可用作聚合物基质中的添加剂，例如用于改善冲击强度和改善光学性能。
-
5.发明申请THERMOPLASTIC COMPOSITIONS HAVING IMPROVED PROPERTIES DURING AND AFTER PROCESSING STEPS, PROCESS FOR MANUFACTURING AN ARTICLE AND ARTICLE THUS OBTAINED 审中-公开在加工步骤和加工步骤之后具有改进性能的热塑性组合物，用于制造所获得的物品和物品的方法公开(公告)号：US20100048797A1
公开(公告)日：2010-02-25
申请号：US12374561
申请日：2007-07-12
申请人： Stephane Girois , Claude C. Granel , Philippe Hajji , Jeffrey Brake , Alexis Chenet , Francoise Fenouillot-Rimlinger , Henry Sautereau
发明人： Stephane Girois , Claude C. Granel , Philippe Hajji , Jeffrey Brake , Alexis Chenet , Francoise Fenouillot-Rimlinger , Henry Sautereau
CPC分类号： C08L67/02 , C08L33/08 , C08L69/00 , C08L2666/04
摘要： The present invention relates to a thermoplastic composition, said composition comprising at least one non-PVC thermoplastic matrix and at least one copolymer chosen from the group consisting of acrylic-based copolymer having an average molecular weight Mw below 400.000 g/mol and acrylic-styrene-based copolymer. The present invention also relates to a process for manufacturing an article from such a thermoplastic composition and to an article obtained from such a thermoplastic composition.
摘要翻译： 本发明涉及热塑性组合物，所述组合物包含至少一种非PVC热塑性基质和至少一种选自平均分子量Mw低于400.000g / mol的丙烯酸类共聚物和丙烯酸 - 苯乙烯的共聚物 基共聚物。 本发明还涉及一种从这种热塑性组合物制造制品的方法和由这种热塑性组合物获得的制品。
-
-
-
-
搜索结果
5 条记录 (耗时 0.017 秒)
