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1.发明申请PROCESS FOR PREPARING A RUBBER COMPOSITION, RUBBER COMPOSITION OBTAINED THEREFROM, AND USE THEREOF 审中-公开制备橡胶组合物的方法，其获得的橡胶组合物及其用途公开(公告)号：US20090101205A1
公开(公告)日：2009-04-23
申请号：US12293393
申请日：2007-03-14
摘要： The present invention pertains to a process for preparing a rubber precursor or a rubber composition comprising a modified inorganic oxygen-containing particulate material comprising the steps of: a) preparing a mixture of the modified inorganic oxygen-containing particulate material and a first solvent; and b1) adding the mixture to a rubber precursor comprising at least one polymer and optionally a second solvent; or b2) adding the mixture to a rubber composition comprising at least one monomer of a rubber precursor and optionally a second solvent, and polymerising the monomer(s) to form the rubber precursor; c) optionally cross-linking the rubber precursor in the presence of a cross-linking agent to form a rubber composition; and d) optionally removing the first and/or second solvents before, during or after any of the steps b1), b2), and c). The invention further pertains to rubber compositions comprising rubber and inorganic oxygen-containing particulate material modified with a coupling agent.
摘要翻译： 本发明涉及一种制备橡胶前体或包含改性无机含氧颗粒材料的橡胶组合物的方法，包括以下步骤：a）制备改性无机含氧颗粒材料和第一溶剂的混合物; 和b1）将混合物加入到包含至少一种聚合物和任选的第二溶剂的橡胶前体中; 或b2）将混合物加入到包含橡胶前体和任选的第二溶剂的至少一种单体的橡胶组合物中，并聚合单体以形成橡胶前体; c）任选地在交联剂存在下交联橡胶前体以形成橡胶组合物; 和d）在任何步骤b1），b2）和c）之前，期间或之后任选地除去第一和/或第二溶剂。 本发明还涉及包含用偶联剂改性的橡胶和无机含氧颗粒材料的橡胶组合物。
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2.发明申请PROCESS FOR MODIFYING INORGANIC OXYGEN-CONTAINING PARTICULATE MATERIAL, PRODUCT OBTAINED THEREFROM, AND USE THEREOF 有权无机含氧含颗粒材料的制备方法及其获得的产品及其用途公开(公告)号：US20100179249A1
公开(公告)日：2010-07-15
申请号：US11993785
申请日：2006-06-16
IPC分类号： C08K9/00
CPC分类号： C09D5/033 , C08L71/02 , C09D143/04 , Y02P20/582
摘要： The present invention pertains to a process for preparing a modified inorganic oxygen-containing particulate material comprising the steps of: a) preparing a mixture of an aqueous suspension of inorganic oxygen-containing particulate material and an alkoxylated alcohol according to the formula (I) wherein R1 is a C1-C8 alkyl, C4-C8 cycloalkyl or phenyl, R2 is hydrogen or methyl, and n is an integer from 1 to 5; b) optionally adding a first resin and/or a first resin precursor; c) adding one or more coupling agents to the mixture; d) optionally adding a second resin and/or a second resin precursor to the resulting mixture; and wherein optionally water is removed at least partially from the mixture before or during step b), c) or d), or after step d); and optionally converting the first resin precursor into the first resin before, during or after step c) and/or the second resin precursor into the second resin after step d).
摘要翻译： 本发明涉及一种制备改性无机含氧颗粒材料的方法，包括以下步骤：a）制备根据式（I）的无机含氧颗粒材料的水悬浮液和烷氧基化醇的混合物，其中 R 1是C 1 -C 8烷基，C 4 -C 8环烷基或苯基，R 2是氢或甲基，n是1至5的整数; b）任选地加入第一树脂和/或第一树脂前体; c）向混合物中加入一种或多种偶联剂; d）任选地向所得混合物中加入第二树脂和/或第二树脂前体; 并且其中任选地在步骤b），c）或d）之前或之后或在步骤d）之后或之后至少部分地从混合物中除去水。 并且在步骤d）之后，在步骤c）和/或第二树脂前体之前，期间或之后，任选地将第一树脂前体转化为第二树脂。
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3.发明授权Process for modifying inorganic oxygen-containing particulate material, product obtained therefrom, and use thereof 有权无机含氧颗粒材料的改性方法，由其获得的产物及其用途公开(公告)号：US09296902B2
公开(公告)日：2016-03-29
申请号：US11993785
申请日：2006-06-16
IPC分类号： C08K9/00 , C09D5/03 , C08L71/02 , C09D143/04
CPC分类号： C09D5/033 , C08L71/02 , C09D143/04 , Y02P20/582
摘要： The present invention pertains to a process for preparing a modified inorganic oxygen-containing particulate material comprising the steps of: a) preparing a mixture of an aqueous suspension of inorganic oxygen-containing particulate material and an alkoxylated alcohol according to the formula (I) wherein R1 is a C1-C8 alkyl, C4-C8 cycloalkyl or phenyl, R2 is hydrogen or methyl, and n is an integer from 1 to 5; b) optionally adding a first resin and/or a first resin precursor; c) adding one or more coupling agents to the mixture; d) optionally adding a second resin and/or a second resin precursor to the resulting mixture; and wherein optionally water is removed at least partially from the mixture before or during step b), c) or d), or after step d); and optionally converting the first resin precursor into the first resin before, during or after step c) and/or the second resin precursor into the second resin after step d).
摘要翻译： 本发明涉及一种制备改性无机含氧颗粒材料的方法，包括以下步骤：a）制备根据式（I）的无机含氧颗粒材料的水悬浮液和烷氧基化醇的混合物，其中 R 1是C 1 -C 8烷基，C 4 -C 8环烷基或苯基，R 2是氢或甲基，n是1至5的整数; b）任选地加入第一树脂和/或第一树脂前体; c）向混合物中加入一种或多种偶联剂; d）任选地向所得混合物中加入第二树脂和/或第二树脂前体; 并且其中任选地在步骤b），c）或d）之前或之后或在步骤d）之后或之后至少部分地从混合物中除去水。 并且在步骤d）之后，在步骤c）和/或第二树脂前体之前，期间或之后，任选地将第一树脂前体转化为第二树脂。
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4.发明授权Use of a granulate for the removal of liquid, gaseous and/or dissolved constituents from a process stream 有权使用颗粒从工艺流中除去液体，气体和/或溶解成分公开(公告)号：US07258796B2
公开(公告)日：2007-08-21
申请号：US10344544
申请日：2001-08-15
CPC分类号： B01J20/28097 , B01J20/26 , B01J20/321 , B01J20/3248 , B01J20/3253 , B01J20/3293
摘要： The invention pertains to the use of a granulate for the removal of liquid, gaseous and/or dissolved organic constituents from a process stream, said granulate consisting of dimensionally stable, porous synthetic particles with an extracting agent having a boiling point higher than 350° C. at 1 bar immobilized therein, characterized in that the granulate is obtainable by suspension polymerization of a monovinyl compound in the presence of a polyvinyl compound, with at least 50% wt. % of the monomer units having an aromatic structure and with the solvent for the monomers acting both as a non-solvent for the copolymer and as an extracting agent.
摘要翻译： 本发明涉及使用颗粒从工艺流中除去液体，气体和/或溶解的有机成分，所述颗粒由具有沸点高于350℃的萃取剂的尺寸稳定的多孔合成颗粒组成 固定在其中的1巴，其特征在于，所述颗粒可通过聚乙烯基化合物存在下的单乙烯基化合物的悬浮聚合获得，至少50重量％。 ％的具有芳族结构的单体单元和用作单体的溶剂用作共聚物的非溶剂和作为萃取剂。
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公开(公告)号：US06764603B2
公开(公告)日：2004-07-20
申请号：US09820546
申请日：2001-03-29
IPC分类号： B01D1500
CPC分类号： B01D17/0202 , B01D15/00 , C02F1/288
摘要： A method for the extraction of hydrophobic constituents, such as benzene, toluene, xylene and/or chlorinated hydrocarbons, from an aqueous solution, involving the steps of contacting said solution with a porous, preferably dimensionally stable granular or powdery material, of which the pores have a size of from 0.1 to 50 &mgr;m and contain a hydrophobic substance with affinity for the hydrophobic constituents to be extracted, which granular or powdery material has a particle size of from 0.1 to 10 mm, and is wetted more readily by the hydrophobic substance immobilized in the pores than by the aqueous solution to be treated, and regenerating the product of step a), essentially without the granular or powdery material being freed from the hydrophobic substance, by removal of the hydrophobic constituents.
摘要翻译： 从水溶液中提取疏水成分如苯，甲苯，二甲苯和/或氯代烃的方法，包括使所述溶液与多孔的，优选尺寸稳定的颗粒状或粉末状材料接触的步骤，其中孔， 具有0.1至50μm的尺寸，并且含有疏水性物质，对疏水性组分具有亲和性，该颗粒或粉末材料的粒径为0.1至10mm，并且被固定的疏水性物质更容易润湿 在孔中比待处理的水溶液，并且通过除去疏水性组分，基本上不使粒状或粉末状物质脱离疏水性物质，再生步骤a）的产物。
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公开(公告)号：US07968740B2
公开(公告)日：2011-06-28
申请号：US12096433
申请日：2006-12-01
申请人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriëtte Zijtveld-Van Der Wiel
发明人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriëtte Zijtveld-Van Der Wiel
IPC分类号： C07F5/06
CPC分类号： C01F7/005 , C01B13/363 , C01F7/002 , C01P2002/22 , C01P2002/78
摘要： A process is disclosed for preparing an organically modified layered double hydroxide having a distance between the individual layers of the layered double hydroxide of about 1.5 nm and comprising an organic anion as charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension comprising a divalent metal ion source and a trivalent metal ion source; (b) solvothermally treating the precursor suspension to obtain a double layered hydroxide, wherein an organic anion is added before or during the formation of the layered double hydroxide of step (b), or following the formation of the layered double hydroxide, so as to obtain the organically modified layered double hydroxide, with the proviso that deoxycholic acid is not the sole organic anion.
摘要翻译： 公开了一种制备有机改性的层状双氢氧化物的方法，其具有约1.5nm的层状双氢氧化物的各层之间的距离，并且包含作为电荷平衡阴离子的有机阴离子，该方法包括以下步骤：（a）制备 包含二价金属离子源和三价金属离子源的前体悬浮液; （b）溶剂化处理前体悬浮液以获得双层氢氧化物，其中在步骤（b）的层状双氢氧化物的形成之前或期间，或在形成层状双氢氧化物之后加入有机阴离子，以便 获得有机改性的层状双氢氧化物，条件是脱氧胆酸不是唯一的有机阴离子。
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公开(公告)号：US20080300352A1
公开(公告)日：2008-12-04
申请号：US12096485
申请日：2006-12-04
申请人： Elwin Schomaker , Robin Winters
发明人： Elwin Schomaker , Robin Winters
CPC分类号： C01F7/005 , C01B13/363 , C01P2002/22
摘要： The invention relates to a process for preparing a layered double hydroxide comprising a charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension or solution comprising a divalent metal ion source, a trivalent metal ion source, water, and a solvent which is miscible with water and in which at least 5 g/l of a charge-balancing anion precursor can be dissolved; (b) treating the precursor suspension or solution to obtain the layered double hydroxide, wherein the charge-balancing anion precursor is added to the suspension or solution before, during or after step (b), and wherein, if the charge-balancing anion is an organic anion, less than 50 wt % of the charge-balancing anion precursors, based on the total weight of charge-balancing anion precursors, is a salt, with the proviso that the charge-balancing anion is not carbonate. The invention further pertains to a layered double hydroxide obtainable by this process.
摘要翻译： 本发明涉及一种制备包含电荷平衡阴离子的层状双氢氧化物的方法，该方法包括以下步骤：（a）制备包含二价金属离子源，三价金属离子源，水， 和与水混溶并且其中可以溶解至少5g / l的电荷平衡阴离子前体的溶剂; （b）处理前体悬浮液或溶液以获得层状双氢氧化物，其中在步骤（b）之前，期间或之后将电荷平衡阴离子前体加入到悬浮液或溶液中，并且其中如果电荷平衡阴离子是 基于电荷平衡阴离子前体的总重量，少于50重量％的电荷平衡阴离子前体的有机阴离子是盐，条件是电荷平衡阴离子不是碳酸盐。 本发明还涉及通过该方法可获得的层状双氢氧化物。
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公开(公告)号：US20080293957A1
公开(公告)日：2008-11-27
申请号：US12096433
申请日：2006-12-01
申请人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriette Zijtveld-Van Der Wiel
发明人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriette Zijtveld-Van Der Wiel
IPC分类号： C07F5/06
CPC分类号： C01F7/005 , C01B13/363 , C01F7/002 , C01P2002/22 , C01P2002/78
摘要： The invention relates to a process for preparing an organically modified layered double hydroxide having a distance between the individual layers of the layered double hydroxide of above 1.5 nm and comprising an organic anion as charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension comprising a divalent metal ion source and a trivalent metal ion source; (b) solvothermally treating the precursor suspension to obtain the layered double hydroxide, wherein an organic anion is added before or during the formation of the layered double hydroxide of step (b), or following the formation of the layered double hydroxide, so as to obtain the organically modified layered double hydroxide, with the proviso that deoxycholic acid is not the sole organic anion. The invention further pertains to a process for preparing an organically modified layered double hydroxide having a distance between the individual layers of the layered double hydroxide of above 1.5 nm and comprising an organic anion as charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension comprising a divalent metal ion source and a trivalent metal ion source; (b) thermally treating the precursor suspension to obtain the layered double hydroxide, wherein an organic anion is added before or during the formation of the layered double hydroxide of step (b), or following the formation of the layered double hydroxide, so as to obtain the organically modified layered double hydroxide, with the proviso that in step a) the trivalent metal ion source is not reacted with the organic anion at a temperature of between 60 and 85° C. for 4 to 8 hours prior to the addition of the divalent metal ion source and step b) is subsequently carried out at a temperature of 90 to 95° C. for 4 to 8 hours.
摘要翻译： 本发明涉及一种制备有机改性层状双氢氧化物的方法，其具有1.5nm以上层状双氢氧化物的各层之间的距离，并且包含作为电荷平衡阴离子的有机阴离子，该方法包括以下步骤：（a ）制备包含二价金属离子源和三价金属离子源的前体悬浮液; （b）溶剂化处理前体悬浮液以获得层状双氢氧化物，其中在形成步骤（b）的层状双氢氧化物之前或阶段期间加入有机阴离子，或在形成层状双氢氧化物之后加入有机阴离子，以便 获得有机改性的层状双氢氧化物，条件是脱氧胆酸不是唯一的有机阴离子。 本发明还涉及一种制备有机改性的层状双氢氧化物的方法，其具有1.5nm以上层状双氢氧化物的各层之间的距离，并且包含有机阴离子作为电荷平衡阴离子，该方法包括以下步骤：（ a）制备包含二价金属离子源和三价金属离子源的前体悬浮液; （b）热处理前体悬浮液以获得层状双氢氧化物，其中在步骤（b）的层状双氢氧化物形成之前或期间，或在形成层状双氢氧化物之后加入有机阴离子，以便 获得有机改性的层状双氢氧化物，条件是在步骤a）中，三价金属离子源在有机阴离子之间在60至85℃的温度下不与有机阴离子反应4至8小时，然后加入 二价金属离子源和步骤b）随后在90至95℃的温度下进行4至8小时。
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9.发明申请Nanocomposite Material Comprising Rubber and Modified Layered Double Hydroxide, Process for Its Preparation and Use Thereof 审中-公开包含橡胶和改性层状双氢氧化物的纳米复合材料，其制备和使用方法公开(公告)号：US20080293849A1
公开(公告)日：2008-11-27
申请号：US12096455
申请日：2006-12-01
申请人： Robin Winters , Haimo Tonnaer , Elwin Schomaker
发明人： Robin Winters , Haimo Tonnaer , Elwin Schomaker
CPC分类号： C08J3/226 , C08J2421/00 , C08K5/548 , C08K9/04 , C08L21/00
摘要： The present invention pertains to a nanocomposite material comprising rubber and a modified layered double hydroxide comprising: a charge-balancing organic ion having a first functional group and a second functional group, wherein at least part of the organic anions is chemically linked to the rubber through the second functional group; and/or a silane coupling agent having at least one alkoxysilane group and at least one reactive group, at least one alkoxysilane group being chemically linked to the layered double hydroxide, at least one reactive group being chemically linked to the rubber. The invention further pertains to a process for preparing the nanocomposite material or a precursor thereof.
摘要翻译： 本发明涉及包含橡胶和改性层状双氢氧化物的纳米复合材料，其包含：具有第一官能团和第二官能团的电荷平衡有机离子，其中至少部分有机阴离子通过化学连接到橡胶 第二功能组; 和/或具有至少一个烷氧基硅烷基团和至少一个反应性基团的硅烷偶联剂，至少一个烷氧基硅烷基团与层状双氢氧化物化学连接，至少一个与橡胶化学连接的反应性基团。 本发明还涉及制备纳米复合材料或其前体的方法。
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公开(公告)号：US06355094B1
公开(公告)日：2002-03-12
申请号：US09721017
申请日：2000-11-22
申请人： Elwin Schomaker , Johannes Bos
发明人： Elwin Schomaker , Johannes Bos
IPC分类号： B01D5302
CPC分类号： B01D53/02 , B01D53/1493 , B01D53/48 , B01J20/28004 , B01J20/28014 , B01J20/28085 , B01J20/28097 , B01J20/321 , B01J20/3217 , B01J20/3248 , B01J20/3251 , B01J20/3253 , B01J20/3425 , B01J20/3458 , B01J20/3483 , B01J2220/56 , B01J2220/58
摘要： Porous, preferably dimensionally stable material and a method for using for the removal of gaseous impurities from a gas mixture, such as H2S, COS, CH2, and SO2, into the pores of which there is incorporated a secondary amine which chemically bonds with the constituents to be removed, with the material including a hydrophobic polymer with pores having an average diameter in the range of from 0.1 to 50 &mgr;m and a secondary amine having hydrophobic properties which optionally is incorporated into a hydrophobic liquid is disclosed. Favorable results have been attained using polypropylene as the hydrophobic polymer and ditridecyl amine as the secondary amine, with a tertiary amine, such as C12 to C14-alkyl diethanol amine, being part of the hydrophobic liquid.
摘要翻译： 多孔的，优选尺寸稳定的材料和用于从气体混合物（例如H 2 S，COS，CH 2和SO 2）中除去气态杂质的方法，其中加入了与组分化学键合的仲胺 被除去，其中该材料包括具有平均直径在0.1-50μm范围内的孔的疏水性聚合物，并且公开了任选地掺入疏水性液体中的具有疏水性的仲胺。 使用聚丙烯作为疏水性聚合物和二季铵盐作为仲胺，使用叔胺如C12至C14-烷基二乙醇胺作为疏水液体的一部分已经获得了有利的结果。
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