摘要:
A device and process for injecting a diverted fluid into a simulated moving bed comprises a vessel containing beds of adsorbant Ai separated by plates Pi for distributing and extracting fluids, each plate comprising at least one pannel, each pannel comprising a single chamber Ci for distributing, mixing and/or extracting fluid, and a bypass circuit placing a plate in communication with a bypass line (Li, j). The device also comprises means (14, Voi,j, 20) for bringing at least one chamber (Ci) into communication with at least one bypass line (Li, j); one end of the bypass line is connected with said chamber Ci of a pannel of plate Pi and the other end communicates with a region (Ri+1) of a pannel of the distributor plate Pi+1, said region being distinct from the distribution chamber Ci+1. Application to separating n-paraffins containing 10 to 13 carbon atoms from sweetened kerosene type feeds.
摘要:
A process for separation and environmentally benign disposal of amine borane complexes includes adsorbing amine borane complex onto a solid support, treating the adsorbed amine borane complex with an oxidizing agent in situ on the adsorbent thereby forming decomposition products without the formation of hydrogen gas, and collecting the decomposition products for disposal thereof.
摘要:
A method for the extraction of hydrophobic constituents, such as benzene, toluene, xylene and/or chlorinated hydrocarbons, from an aqueous solution, involving the steps of contacting said solution with a porous, preferably dimensionally stable granular or powdery material, of which the pores have a size of from 0.1 to 50 &mgr;m and contain a hydrophobic substance with affinity for the hydrophobic constituents to be extracted, which granular or powdery material has a particle size of from 0.1 to 10 mm, and is wetted more readily by the hydrophobic substance immobilized in the pores than by the aqueous solution to be treated, and regenerating the product of step a), essentially without the granular or powdery material being freed from the hydrophobic substance, by removal of the hydrophobic constituents.
摘要:
This invention is directed a method for purifying an impure gas to produce an ultra-high purity gas comprising the steps of a) passing the impure liquefied gas through a first adsorption means to remove impurities from the liquid phase therein to produce a first purified fluid; b) passing the first purified fluid through an evaporation means to remove impurities therein to produce a second purified gas; and c) passing the second purified gas through a second adsorption means to remove impurities from the vapor phase therein to produce the ultra-high purity gas.
摘要:
A method for efficiently resolving optical isomers, in which a discriminating liquid consisting of a discriminating agent capable of discriminating optical isomers and a diluent are brought into contact with a mixture containing said optical isomers in countercurrent flow, to resolve the optical isomers by adsorption separation, distillation separation, absorption separation or membrane separation, and recovered at an optical isomer content of 5 wt % or less for recycled use, under one or more of the following conditions: (a) the dielectric constant of the diluent is 30 or less and the viscosity of the discriminating liquid is 0.2 Pa·s or less at the temperature of the resolving operation; (b) the discriminating agent contained has the effect of splitting the 1H or 13C-NMR spectrum peak of the optical isomers when added and the diluent contained has a dielectric constant equal to or lower than the dielectric constant of the measuring solvent at the time of measuring the 1H or 13C-NMR spectrum; (c) the boiling point of at least one compound of the discriminating agent at the pressure of the resolving operation is higher than the boiling point of at least one compound of the diluent at the pressure of the resolving operation; (d) the boiling point of at least one compound of the diluent at the pressure of the resolving operation is higher than the boiling point of the optical isomers to be resolved, at the pressure of the resolving operation, by 10° C. or more; and (e) the concentration of the discriminating agent in the discriminating liquid is 10 wt % or more.
摘要:
The present invention relates to a process to remove quaternary ammonium salt (QS), from brine solution. The process uses an adsorbent selected from the group consisting of activated carbon and pyrolyzed sulfonated polystyrene divinylbenzene resin, or mixtures thereof which aids in removing the quaternary ammonium salt (QS). The process can be generally carried out at a temperature ranging from about −10° C. to about 90° C., at a pH ranging from about 1 to about 13.
摘要:
For the removal of trace quantities of iodine-containing contaminants from corrosive liquid feed streams, an alternative with distinct advantages over the prior art is provided. The treatment method involves the use of a crystalline manganese phosphate which has been cation-exchanged with an iodine-reactive metal. This inorganic adsorbent may be used in unbound form, or it can bound with a substantially insoluble porous inorganic refractory metal oxide binder. A reactivation technique for this material is also presented.
摘要:
Carbon nanotube structures are disclosed in which nanotubes are disposed over a porous support such as a foam, felt, mesh, or membrane. Techniques of making these structures are also disclosed. In some of these techniques, a support is pretreated with a templated surfactant composition to assist with the formation of a nanotube layer.
摘要:
The invention provides the continuous, integrated methods and devices for substantially removing ionized and ionizable carbon compounds from an aqueous stream by first deionization step to produce a first product stream, ionizing nonionized and nonionizable carbon compounds in such stream to form further ionized and ionizable compounds, and removing the latter by a second deionization step. The method can be performed for example in an apparatus including an EDI unit (10), an ionizing unit (60), and EDI unit (100).
摘要:
The invention is directed to fluorinated particles having adsorbent properties for superior performance as the stationary phase for use in chromatographic separations. In particular, the fluorinated surface of such particles of the invention presents unusual and unexpected polarity that is beneficial in performing chromatographic separations such as that used for DNA.