公开(公告)号：US08003167B2

公开(公告)日：2011-08-23

申请号：US11806674

申请日：2007-06-01

申请人： Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： C23C16/00

CPC分类号： C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. The method may include heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) or other type of carbon, with a protective film thereon. In certain example embodiments, the protective film may be of or include a layer of or including SnOx prior to HT. Optionally, a release layer of a material such as zinc oxide may be provided between the SnOx and the DLC. Following and/or during heat treatment the SnOx transforms into SnOy (y>x) so that stress is created due to the SnOx to SnOy transition. Then, during quenching, stress relief may occur which causes the layer to buckle, creating cracks which may act as liquid channels that permit the sacrificial film to be easily removed via washing or the like.

摘要翻译： 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 该方法可以包括用至少一层或类金刚石碳（DLC）或其他类型的碳涂覆的玻璃基板与其上的保护膜进行热处理。 在某些示例性实施方案中，保护膜可以是HT之前的或包括SnOx层或包括SnOx层。 任选地，可以在SnO x和DLC之间提供诸如氧化锌的材料的剥离层。 跟随和/或在热处理期间，SnOx转变成SnOy（y> x），从而由于SnOx至SnOy转变而产生应力。 然后，在淬火期间，可能发生应力消除，这导致该层弯曲，产生可能作为允许通过洗涤等容易地除去牺牲膜的液体通道的裂纹。

公开(公告)号：US07914857B2

公开(公告)日：2011-03-29

申请号：US11806678

申请日：2007-06-01

申请人： Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Maximo Frati ,  Nestor P. Murphy ,  Jose Nunez-Regueiro

发明人： Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Maximo Frati ,  Nestor P. Murphy ,  Jose Nunez-Regueiro

IPC分类号： C23C14/00 ,  B05D1/36 ,  B05D3/02

CPC分类号： C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. The method may include heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) or other type of carbon, with an oxygen barrier layer provided thereon directly or indirectly. Optionally, a release layer of a material such as zinc oxide or the like may be provided between the oxygen barrier layer and the DLC. In certain example embodiments, the oxygen content of at least part of the protective film when deposited may be determined based on whether the coated surface is to be bent in a convex manner, to be bent in a concave manner, or to remain flat. Following heat treatment, which may include bending the coated surface into a convex or concave shape, and quenching, the protective film may be removed by washing or the like.

摘要翻译： 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 该方法可以包括用至少一层或类金刚石碳（DLC）或其他类型的碳涂覆的玻璃基板，其上直接或间接地提供氧阻挡层。 任选地，可以在氧阻隔层和DLC之间设置诸如氧化锌等的材料的剥离层。 在某些示例性实施例中，当沉积时保护膜的至少一部分的氧含量可以基于涂覆的表面是以凸形的方式弯曲，以凹形的方式弯曲还是保持平坦来确定。 在热处理之后，其可以包括将涂覆表面弯曲成凸形或凹形，并且淬火，可以通过洗涤等除去保护膜。

公开(公告)号：US20080178632A1

公开(公告)日：2008-07-31

申请号：US11798920

申请日：2007-05-17

申请人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： C03C17/00

CPC分类号： C03C17/3435 ,  C03C17/3423 ,  C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

摘要翻译： 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US20120137734A1

公开(公告)日：2012-06-07

申请号：US13369337

申请日：2012-02-09

申请人： Rudolph Hugo PETRMICHL ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Rudolph Hugo PETRMICHL ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： C03C17/22 ,  C03B27/012

CPC分类号： C03C17/3435 ,  C03C17/3423 ,  C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

摘要翻译： 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US08071166B2

公开(公告)日：2011-12-06

申请号：US12230551

申请日：2008-08-29

申请人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： C23C16/26 ,  B05D5/00 ,  B05D3/02 ,  B32B33/00

CPC分类号： C03C17/3441 ,  C03C17/22 ,  C03C2217/282 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/328 ,  C03C2218/33 ,  C03C2218/355 ,  Y10T428/30

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

摘要翻译： 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US20080182032A1

公开(公告)日：2008-07-31

申请号：US11806674

申请日：2007-06-01

申请人： Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： C23C14/00 ,  B05D3/02

CPC分类号： C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. The method may include heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) or other type of carbon, with a protective film thereon. In certain example embodiments, the protective film may be of or include a layer of or including SnOx prior to HT. Optionally, a release layer of a material such as zinc oxide may be provided between the SnOx and the DLC. Following and/or during heat treatment the SnOx transforms into SnOy (y>x) so that stress is created due to the SnOx to SnOy transition. Then, during quenching, stress relief may occur which causes the layer to buckle, creating cracks which may act as liquid channels that permit the sacrificial film to be easily removed via washing or the like.

摘要翻译： 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 该方法可以包括用至少一层或类金刚石碳（DLC）或其他类型的碳涂覆的玻璃基板与其上的保护膜进行热处理。 在某些示例性实施方案中，保护膜可以是或包含HT之前的或包括SnO x的层。 任选地，可以在SnO x和DLC之间提供诸如氧化锌的材料的剥离层。 在热处理之后和/或在热处理期间，SnO x x x转换成SnO y（y> x），使得由于SnO x x（x） 到SnO y y转换。 然后，在淬火期间，可能发生应力消除，这导致该层弯曲，产生可能作为允许通过洗涤等容易地除去牺牲膜的液体通道的裂纹。

公开(公告)号：US08443627B2

公开(公告)日：2013-05-21

申请号：US13369337

申请日：2012-02-09

申请人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： C03C17/34

CPC分类号： C03C17/3435 ,  C03C17/3423 ,  C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

公开(公告)号：US08440255B2

公开(公告)日：2013-05-14

申请号：US13373046

申请日：2011-11-03

申请人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： B05D5/08 ,  C23C16/27 ,  C23C16/34

CPC分类号： C03C17/3441 ,  C03C17/22 ,  C03C2217/282 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/328 ,  C03C2218/33 ,  C03C2218/355 ,  Y10T428/30

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

公开(公告)号：US08132426B2

公开(公告)日：2012-03-13

申请号：US11798920

申请日：2007-05-17

申请人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： C03C17/34

CPC分类号： C03C17/3435 ,  C03C17/3423 ,  C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

摘要翻译： 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括在其上涂覆至少一层或类金刚石碳（DLC）和其上的保护膜的玻璃基材的热处理步骤。 在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US20120052212A1

公开(公告)日：2012-03-01

申请号：US13373046

申请日：2011-11-03

申请人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

发明人： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC分类号： B05D3/02

CPC分类号： C03C17/3441 ,  C03C17/22 ,  C03C2217/282 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/328 ,  C03C2218/33 ,  C03C2218/355 ,  Y10T428/30

摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.