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    Liquid Maleated Butyl Rubber
    4.
    发明申请
    Liquid Maleated Butyl Rubber 审中-公开
    液体马来酸丁酯橡胶

    公开(公告)号：US20090189118A1

    公开(公告)日：2009-07-30

    申请号：US11922546

    申请日：2006-07-06

    申请人： Rui Resendes ,  John Scott Parent ,  Ralph Allen Whitney

    发明人： Rui Resendes ,  John Scott Parent ,  Ralph Allen Whitney

    IPC分类号： C09K3/00

    CPC分类号： C08F255/08 ,  C08F8/50 ,  C08F255/00 ,  C08F255/10 ,  C08F279/02 ,  C08K5/17 ,  C08L51/04 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/04 ,  C08F210/12 ,  C08L23/22

    摘要： The present invention relates to a grafted liquid polymer comprising a polymer of a C4 to C7 monoolefin monomer and a C4 to C14 multiolefin monomer, a grafting material and a free radical initiator and to a process for the preparation of the grafted liquid polymer. More specifically, a liquid maleated butyl rubber composition is disclosed. The present invention also relates to grafted liquid polymer compositions which are curable in the presence of multifunctional amines. The compositions of the invention are used in a variety of applications, including injection molded fuel cells gaskets, adhesives, sealants or as polyurethane substrates.

    摘要翻译： 本发明涉及包含C4〜C7单烯烃单体和C4〜C14多烯烃单体的聚合物，接枝材料和自由基引发剂的接枝液体聚合物以及制备接枝液体聚合物的方法。 更具体地，公开了液体马来化丁基橡胶组合物。 本发明还涉及在多官能胺存在下可固化的接枝液体聚合物组合物。 本发明的组合物用于各种应用中，包括注射成型的燃料电池垫圈，粘合剂，密封剂或聚氨酯基材。

    Process to produce silica-filled elastomeric compounds
    5.
    发明授权
    Process to produce silica-filled elastomeric compounds 有权
    生产二氧化硅填充的弹性体化合物的方法

    公开(公告)号：US07238736B2

    公开(公告)日：2007-07-03

    申请号：US10834437

    申请日：2004-04-29

    申请人： John Scott Parent ,  Ralph Allen Whitney ,  Andrea Liskova ,  Rui Resendes

    发明人： John Scott Parent ,  Ralph Allen Whitney ,  Andrea Liskova ,  Rui Resendes

    IPC分类号： C08K5/50 ,  C08K3/32

    CPC分类号： C08K3/36 ,  C08K3/346 ,  C08K5/50 ,  C08L23/28 ,  C08L23/283

    摘要： The present invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer with at least one mineral filler and at least one phosphine modifier and optionally curing the filled elastomer with sulfur or other curative systems. Filled halobutyl elastomers prepared according to the present invention possess improved levels of filler dispersion which results in a reduction in the hardness of the compound and an increased tensile strength.

    摘要翻译： 本发明提供一种制备填充的卤代丁基弹性体的方法，其包括将卤代丁基弹性体与至少一种矿物填料和至少一种膦改性剂混合，并任选地用硫或其它固化体系固化填充的弹性体。 根据本发明制备的填充的卤代丁基弹性体具有提高的填料分散体水平，导致化合物的硬度降低和拉伸强度的增加。

    Functionalised polyolefins, moisture curable polyolefin resins and processes of manufacturer thereof
    6.
    发明授权
    Functionalised polyolefins, moisture curable polyolefin resins and processes of manufacturer thereof 失效
    官能化聚烯烃，湿固化聚烯烃树脂及其制造方法

    公开(公告)号：US07858705B2

    公开(公告)日：2010-12-28

    申请号：US11266487

    申请日：2005-11-04

    申请人： John Scott Parent ,  Saurav Sankar Sengupta

    发明人： John Scott Parent ,  Saurav Sankar Sengupta

    IPC分类号： C08F297/02 ,  C08F297/00

    CPC分类号： C08F8/42 ,  C07F7/1804 ,  C08F8/34 ,  C08F255/02

    摘要： A process for preparing a functionalised polyolefin is described. The process comprises the step of reacting: (i) a polyolefin, (ii) a compound containing a functional group, and (iii) a coagent compound having Formula I: Xn—Y—Zm  (I) wherein: Y is a core moiety; Z is a moiety containing a carbon-carbon double bond or a carbon-carbon triple bond; X is a moiety different than Z and the bond between X and Y may be a single bond or a double bond; n is a whole number greater than or equal to 0; m is a whole number greater than or equal to 2; and m+n equals a number up to the valence of Y; wherein: (a) when m is 2 and n is 0, the process comprises initially reacting the polyolefin and the coagent to form a product that is then reacted with the compound containing the functional group, and (b) the compound containing a functional group is substantially inert in free radical-mediated polymerization reactions and in free radical-mediated grafting reactions. The invention also relates to a functionalized polyolefin produced by such a process. The polyolefins, particularly high molecular weight polyolefins (Mn>10,000), can be extensively modified with functional groups (e.g., thiols, epoxides, anhydrides, carboxylic acids, amines, amides, boron-containing compounds, silicon-containing compounds, cyano-containing compounds, sulfates, sulfonates, sulfites, esters, thioesters, dithioesters, ether, halides, phosphates, phosphonates, phosphines, phosphites and other compounds containing polar moieties) without altering molecular weight thereby rendering the functionalised polyolefins useful in a wide range of applications.

    摘要翻译： 描述了制备官能化聚烯烃的方法。 该方法包括以下步骤：（i）聚烯烃，（ii）含有官能团的化合物，和（iii）具有式I的固体化合物：Xn-Y-Zm（I）其中：Y是核心部分 ; Z是含有碳 - 碳双键或碳 - 碳三键的部分; X是不同于Z的部分，X和Y之间的键可以是单键或双键; n是大于或等于0的整数; m是大于或等于2的整数; 并且m + n等于直到Y的价数; 其中：（a）当m为2且n为0时，该方法首先使聚烯烃和助剂反应形成一种产物，然后与含有该官能团的化合物反应，和（b）含有官能团的化合物 在自由基介导的聚合反应和自由基介导的接枝反应中基本上是惰性的。 本发明还涉及通过这种方法制备的官能化聚烯烃。 聚烯烃，特别是高分子量聚烯烃（Mn> 10,000）可以用官能团（例如硫醇，环氧化物，酸酐，羧酸，胺，酰胺，含硼化合物，含硅化合物，含氰基的化合物， 化合物，硫酸盐，磺酸盐，亚硫酸盐，酯，硫酯，二硫代酯，醚，卤化物，磷酸盐，膦酸盐，膦，亚磷酸盐和其它含有极性部分的化合物），而不改变分子量，从而使功能化的聚烯烃在广泛的应用范围内有用。

    Tap-mediated, rheology-modified polymers and preparation methods
    8.
    发明申请
    Tap-mediated, rheology-modified polymers and preparation methods 审中-公开
    水分子介导的流变改性聚合物及其制备方法

    公开(公告)号：US20080188623A1

    公开(公告)日：2008-08-07

    申请号：US11592524

    申请日：2006-11-03

    申请人： Bharat I. Chaudhary ,  Malcolm F. Finlayson ,  Stephen F. Hahn ,  Stephane Costeux ,  John Scott Parent ,  Saurav S. Sengupta

    发明人： Bharat I. Chaudhary ,  Malcolm F. Finlayson ,  Stephen F. Hahn ,  Stephane Costeux ,  John Scott Parent ,  Saurav S. Sengupta

    IPC分类号： C08F8/40

    CPC分类号： C08F8/40

    摘要： The present invention yields a triallyl phosphate (TAP)-mediated, rheology-modified polymer being prepared in a reaction from a reaction mixture made from or containing (a) a free-radical, chain-scissionable organic polymer and (b) TAP, wherein the TAP-mediated, rheology-modified polymer has extensional viscosity at Hencky strains above one greater than that of the free-radical, chain-scissionable organic polymer and/or a Relaxation Spectra Index (RSI) greater than that of the free-radical, chain-scissionable organic polymer.

    摘要翻译： 本发明产生了一种由烯丙基（TAP）介导的流变学改性的聚合物，它是在由（a）自由基，可断开的有机聚合物和（b）TAP制成的反应混合物的反应中制备的，其中 TAP介导的流变改性聚合物在Hencky菌株具有比自由基，可断开链段的有机聚合物和/或大于自由基的松弛光谱指数（RSI）大一倍以上的拉伸粘度， 可断链的有机聚合物。

    Imide-Coupled Propylene-Based Polymer and Process
    9.
    发明申请
    Imide-Coupled Propylene-Based Polymer and Process 审中-公开
    酰亚胺基聚合物和工艺

    公开(公告)号：US20110009513A1

    公开(公告)日：2011-01-13

    申请号：US12831394

    申请日：2010-07-07

    申请人： Bharat I. Chaudhary ,  Rongjuan Cong ,  John Scott Parent

    发明人： Bharat I. Chaudhary ,  Rongjuan Cong ,  John Scott Parent

    IPC分类号： C08F255/00

    CPC分类号： C08F8/32 ,  C08F10/06

    摘要： Disclosed are propylene-based polymers with improved melt strength, improved strain hardening characteristics and processes for producing the same. The processes include reacting a polyamine with a maleic anhydride-grafted-propylene-based polymer. The processes produce a rheology-modified propylene-based polymer with long chain branching by forming a polyimide linkage which couples polymer chains of the propylene-based polymer. The polyimide-coupled propylene-based polymer exhibits improved melt strength and improved strain hardening characteristics.

    摘要翻译： 公开了具有改进的熔体强度，改进的应变硬化特性的丙烯基聚合物及其制备方法。 该方法包括使多胺与马来酸酐接枝丙烯基聚合物反应。 该方法通过形成聚合物连接而产生具有长链支化的流变改性的丙烯基聚合物，其聚合丙烯类聚合物的聚合物链。 聚酰亚胺结合的丙烯基聚合物表现出改进的熔体强度和改进的应变硬化特性。