Abstract:
A resin composition may include a (meth)acrylate (A) comprising a hydroxy group and having a molecular weight of about 500 or less, and a polymer (B) comprising polyisoprene or polybutadiene as a main skeleton, having at least one radical reactive group in one molecule, and having a molecular weight in a range of about 2,000 to about 35,000, wherein the resin composition has a glass transition temperature in a range of about −50° C. to about 0° C. after the resin composition is cured, and the resin composition has a viscosity in a range of about 5 mPa·s to about 50 mPa·s at a temperature in a range of about 30° C. to about 50° C.
Abstract:
Polyolefin elastomers are widely employed commodity polymers. There remains a desire to expand the structural diversity of polyolefin elastomers to facilitate their use in additional applications. Polyolefin elastomers may be graft copolymers that comprise: a first polymer chain comprising at least a first olefinic monomer comprising isobutylene and a second olefinic monomer bearing a benzylic carbon atom or an allylic carbon atom, and a second polymer chain bonded to the benzylic carbon atom or the allylic carbon atom of the first polymer chain. The second polymer chain comprises at least one monomer that is not present in the first polymer chain. The second polymer chain may be bonded to the first polymer chain by generating a carbanion upon the benzylic carbon atom or the allylic carbon atom and growing the second polymer chain by anionic polymerization.
Abstract:
A composition is described comprising a styrene-isobutylene block copolymer; and at least one ethylenically unsaturated monomer. After curing the composition comprises polymerized units of the ethylenically unsaturated monomer. In some embodiments the ethylenically unsaturated groups are selected from (meth)acryl or vinyl ether. The composition is suitable for use as a (e.g. pressure sensitive) adhesive. Articles, methods of making an article, and methods of bonding are also described.
Abstract:
UV-absorbing polymers are provided that have at least one anhydride repeating unit that is covalently attached to at least one UV-absorbing moiety selected from the group consisting of functionalized dibenzoylmethanes, benzophenone sulfonamides, triphenyl triazines, and combinations thereof. Also provided are formulations comprising the UV-absorbing polymers.
Abstract:
UV-absorbing polymers are provided that have at least one anhydride repeating unit that is covalently attached to at least one UV-absorbing moiety selected from the group consisting of functionalized dibenzoylmethanes, benzophenone sulfonamides, triphenyl triazines, and combinations thereof. Also provided are formulations comprising the UV-absorbing polymers.
Abstract:
An adhesive resin composition, including: a base resin which comprises (A) 30-90 parts by weight of a modified ethylene-olefin copolymer, and (B) 70-10 parts by weight of a styrene thermoplastic elastomer, provided that (A)+(B) equals 100 parts by weight; and (C) a tackifier in an amount of 30-60 parts by weight per 100 parts by weight of the base resin, the modified ethylene-olefin copolymer being one which has been graft-modified with (a) an unsaturated carboxylic acid or a derivative thereof and (b) an aromatic vinyl monomer, comprises 0.1%-5% by weight of (a) the unsaturated carboxylic acid or the derivative thereof, and has a melting point peak in a range of 100-150° C. with an enthalpy of crystal fusion of 0.5-10 J/g as determined by DSC.
Abstract:
A photocurable elastomer composition comprising: (A) a liquid polymer having a number average molecular weight of 5,000 or more, and mainly containing —[CH2C(CH3)2]— units; (B) a (meth)acrylate monomer; and (C) a photo polymerization initiator, the mass ratio ((A):(B)) between the component (A) and the component (B) being 10:90 to 39:61.
Abstract:
The present invention is directed to a new class of thermoplastic elastomers (TPEs) and processes for making them. In some embodiments of the present invention, the end groups of the multi-arm PIB copolymer is a conjugated diene, whereas the other component is a multi-functional dienophile. The components of the TPE of the present invention are chemically connected via the well-known Diels-Alder reaction which is thermally reversible (by the retro-Diels-Alder reaction) at moderately elevated temperatures. The reversibility of the Diels-Alder retro-Diels-Alder reactions allows the recovery of the original components of the TPE and thus its recyclability and also gives the TPE the ability to be reshaped or reformed.
Abstract:
The application provides a terpolymer obtainable by copolymerizing (A) 1% to 70% by weight of at least one electron-deficient olefin, an example being an anhydride of a monoethylenically unsaturated C4 to C6 dicarboxylic acid, (B) 1% to 85% by weight of at least one olefin which on its olefinic double bond carries only hydrogen atoms and/or carbon atoms without electron-withdrawing substituents, an example being an isobutene homopolymer or copolymer having a number-average molecular weight of 100 to 500 000, and (C) 1% to 70% by weight of at least one alkoxyvinylsilane, and also derivatives of this terpolymer that are obtainable by modification or crosslinking.
Abstract:
A composition of the reaction product of (a) an isobutylene-diene copolymer having thereon groups containing carboxylic acid functionality or reactive equivalent thereof, derived from an α,β-unsaturated carboxylic compound; and (b) an amine component comprising at least one aromatic amine containing at least one N—H group capable of condensing with said carboxylic acid functionality, is a useful dispersant viscosity modifier.