公开(公告)号：US20110009513A1

公开(公告)日：2011-01-13

申请号：US12831394

申请日：2010-07-07

申请人： Bharat I. Chaudhary ,  Rongjuan Cong ,  John Scott Parent

发明人： Bharat I. Chaudhary ,  Rongjuan Cong ,  John Scott Parent

IPC分类号： C08F255/00

CPC分类号： C08F8/32 ,  C08F10/06

摘要： Disclosed are propylene-based polymers with improved melt strength, improved strain hardening characteristics and processes for producing the same. The processes include reacting a polyamine with a maleic anhydride-grafted-propylene-based polymer. The processes produce a rheology-modified propylene-based polymer with long chain branching by forming a polyimide linkage which couples polymer chains of the propylene-based polymer. The polyimide-coupled propylene-based polymer exhibits improved melt strength and improved strain hardening characteristics.

摘要翻译： 公开了具有改进的熔体强度，改进的应变硬化特性的丙烯基聚合物及其制备方法。 该方法包括使多胺与马来酸酐接枝丙烯基聚合物反应。 该方法通过形成聚合物连接而产生具有长链支化的流变改性的丙烯基聚合物，其聚合丙烯类聚合物的聚合物链。 聚酰亚胺结合的丙烯基聚合物表现出改进的熔体强度和改进的应变硬化特性。

公开(公告)号：US20110009514A1

公开(公告)日：2011-01-13

申请号：US12831348

申请日：2010-07-07

申请人： Bharat I. Chaudhary ,  John Scott Parent ,  Malcolm F. Finlayson ,  John D. Weaver ,  Rongjuan Cong ,  Jian Wang

发明人： Bharat I. Chaudhary ,  John Scott Parent ,  Malcolm F. Finlayson ,  John D. Weaver ,  Rongjuan Cong ,  Jian Wang

IPC分类号： C08G77/00 ,  C08F110/06

CPC分类号： C08F255/02 ,  C08F8/00 ,  C08F2810/20 ,  C08F230/08

摘要： The present disclosure provides propylene-based polymers which exhibit a strain hardening distribution factor that is less than zero and/or a strain hardening factor greater than 1.5. The propylene-based polymers are rheology-modified by way of silane coupling to improve melt strength.

摘要翻译： 本公开提供了表现出小于零的应变硬化分布因子和/或应变硬化因子大于1.5的基于丙烯的聚合物。 基于丙烯的聚合物通过硅烷偶联进行流变改性以改善熔体强度。

公开(公告)号：US08629214B2

公开(公告)日：2014-01-14

申请号：US13453541

申请日：2012-04-23

申请人： Teresa P. Karjala ,  Rongjuan Cong ,  Colleen M. Tice ,  Sarah M. Hayne ,  Mehmet Demirors ,  Lori L. Kardos

发明人： Teresa P. Karjala ,  Rongjuan Cong ,  Colleen M. Tice ,  Sarah M. Hayne ,  Mehmet Demirors ,  Lori L. Kardos

IPC分类号： C08F8/00 ,  C08L23/04

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08L2666/06 ,  C08F4/64193 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/26

摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions and blends thereof with one or more polymers, such as LDPE, are useful for making many articles, especially including films.

摘要翻译： 已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物及其与一种或多种聚合物如LDPE的共混物可用于制备许多制品，特别是 包括电影。

公开(公告)号：US20120227469A1

公开(公告)日：2012-09-13

申请号：US13512387

申请日：2010-12-21

申请人： William L. Winniford ,  Rongjuan Cong ,  Theodore M. Stokich, JR. ,  Randy J. Pell ,  Matthew D. Miller ,  Abhishek Roy ,  Freddy Van Damme ,  Alexander W. Degroot ,  John W. Lyons ,  David M. Meunier

发明人： William L. Winniford ,  Rongjuan Cong ,  Theodore M. Stokich, JR. ,  Randy J. Pell ,  Matthew D. Miller ,  Abhishek Roy ,  Freddy Van Damme ,  Alexander W. Degroot ,  John W. Lyons ,  David M. Meunier

IPC分类号： G01N30/06

CPC分类号： B01D15/161 ,  B01D15/166 ,  B01D15/1878 ,  B01J20/24 ,  B01J2220/4825 ,  G01N30/34 ,  G01N2030/3076 ,  G01N2030/885

摘要： The invention provides a method for one-dimensional chromatography of a polyolefin polymer, comprising introducing a solution of the polyolefin polymer into a liquid flowing through a liquid chromatography stationary phase, the liquid chromatography stationary phase comprising graphitic carbon, and wherein the polyolefin polymer emerging from the liquid chromatography stationary phase has a retention factor greater than zero, and wherein the solution introduced into the liquid chromatography stationary phase is subjected to a temperature gradient, and/or the solution is subjected to a solvent gradient. The invention also provides a method for multi-dimensional chromatography of a polyolefin polymer, comprising introducing a solution of the polyolefin polymer into a liquid flowing through a first liquid chromatography stationary phase or a field flow fractionation device, and subsequently flowing the solution through a second liquid chromatography stationary phase, the second liquid chromatography stationary phase comprising graphitic carbon, and wherein the polyolefin polymer emerging from the liquid chromatography stationary phase has a retention factor greater than zero. The invention also provides an apparatus for polyolefin polymer chromatography, comprising a liquid chromatography stationary phase, the liquid chromatography stationary phase comprising graphitic carbon and at least one inert filler.

摘要翻译： 本发明提供了聚烯烃聚合物的一维色谱法的方法，包括将聚烯烃聚合物的溶液引入流过液相色谱固定相的液体中，液相色谱固定相包含石墨碳，其中聚烯烃聚合物从 液相色谱固定相具有大于零的保留因子，其中引入液相色谱固定相的溶液经受温度梯度，和/或溶液经受溶剂梯度。 本发明还提供了聚烯烃聚合物的多维色谱法的方法，包括将聚烯烃聚合物的溶液引入流过第一液相色谱固定相或场流分离装置的液体中，随后使溶液流过第二 液相色谱固定相，第二液相色谱固定相包含石墨碳，其中从液相色谱固定相中出现的聚烯烃聚合物具有大于零的保留因子。 本发明还提供了一种用于聚烯烃聚合物色谱的装置，包括液相色谱固定相，液相色谱固定相包含石墨碳和至少一种惰性填料。

公开(公告)号：US08829115B2

公开(公告)日：2014-09-09

申请号：US13581726

申请日：2011-03-02

申请人： Theresa J. Hermel-Davidock ,  Mehmet Demirors ,  Sarah M. Hayne ,  Rongjuan Cong ,  Lori L. Kardos ,  Teresa P. Karjala

发明人： Theresa J. Hermel-Davidock ,  Mehmet Demirors ,  Sarah M. Hayne ,  Rongjuan Cong ,  Lori L. Kardos ,  Teresa P. Karjala

IPC分类号： C08L23/04 ,  C08F2/00 ,  C08F4/642 ,  C08F4/659 ,  C08F10/02 ,  C08L23/08 ,  C08F10/00 ,  C08F210/16 ,  B32B27/32 ,  C08L23/02

CPC分类号： C08L23/04 ,  C08F10/00 ,  C08F210/16 ,  C08L23/02 ,  C08L23/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08F2/001 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/09 ,  C08F2500/20 ,  C08F4/64193

摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions are useful for making many articles, especially including films. The polymers are made using a metal complex of a polyvalent aryloxyether.

摘要翻译： 已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物可用于制备许多制品，特别是包括膜。 聚合物使用多价芳氧基醚的金属络合物制成。

公开(公告)号：US20130046061A1

公开(公告)日：2013-02-21

申请号：US13581726

申请日：2011-03-02

申请人： Theresa J. Hermel-Davidock ,  Mehmet Demirors ,  Sarah M. Hayne ,  Rongjuan Cong ,  Lori L. Kardos ,  Teresa P. Karjala

发明人： Theresa J. Hermel-Davidock ,  Mehmet Demirors ,  Sarah M. Hayne ,  Rongjuan Cong ,  Lori L. Kardos ,  Teresa P. Karjala

IPC分类号： C08F210/02 ,  C08F2/01 ,  C08L23/08

CPC分类号： C08L23/04 ,  C08F10/00 ,  C08F210/16 ,  C08L23/02 ,  C08L23/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08F2/001 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/09 ,  C08F2500/20 ,  C08F4/64193

摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions are useful for making many articles, especially including films. The polymers are made using a metal complex of a polyvalent aryloxyether.

摘要翻译： 已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物可用于制备许多制品，特别是包括膜。 聚合物使用多价芳氧基醚的金属络合物制成。

公开(公告)号：US20100197880A1

公开(公告)日：2010-08-05

申请号：US12668794

申请日：2008-07-14

申请人： Colin Li Pi Shan ,  Roger L. Kuhlman ,  Gary L. Rath ,  Pamela J. Kenny ,  Morgan M. Hughes ,  Rongjuan Cong

发明人： Colin Li Pi Shan ,  Roger L. Kuhlman ,  Gary L. Rath ,  Pamela J. Kenny ,  Morgan M. Hughes ,  Rongjuan Cong

IPC分类号： C08F210/02

CPC分类号： C08F210/16 ,  C08L23/02 ,  C08L23/08 ,  C08L23/0807 ,  C08L2205/02 ,  C08L2666/06 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/12

摘要： The invention is related to an ethylene/α-olefin interpolymer having at least a hard segment and at least a soft segment. The soft segment contains a higher amount of comonomers than the hard segment. The hard segment has low crystallinity. The copolymer has a number of unique characteristics disclosed herein.ethylene/α-olefin interpolymers containing low crystallinity hard blocks

摘要翻译： 本发明涉及至少具有硬链段和至少一个软链段的乙烯/α-烯烃互聚物。 软链段含有比硬链段更高量的共聚单体。 硬链段结晶度低。 共聚物具有本文公开的许多独特特征。含有低结晶度硬嵌段的乙烯/α-烯烃互聚物

公开(公告)号：US10363700B2

公开(公告)日：2019-07-30

申请号：US14240776

申请日：2011-08-26

申请人： Xiao B. Yun ,  Rongjuan Cong ,  Jephrey Pan ,  Teresa P. Karjala

发明人： Xiao B. Yun ,  Rongjuan Cong ,  Jephrey Pan ,  Teresa P. Karjala

IPC分类号： B29C55/14 ,  B29C55/00 ,  B29C48/00 ,  C08J5/18 ,  C08L23/08 ,  B32B15/08 ,  B32B15/20 ,  B32B27/08 ,  B32B27/10 ,  B32B27/16 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B7/02 ,  B29C47/00 ,  C08L23/10 ,  B29K23/00

摘要： The present invention discloses a process for forming a biaxially oriented film. The process includes first selecting a polyolefin resin wherein said polyolefin resin comprises a linear low density polyethylene resin characterized by having from 9 to 35 weight percent of the total weight of linear low density polyethylene resin eluting from a CEF at a temperature greater than 97.0° C.; and further characterized by having a CDR of from 33 to 80 and a Mw Ratio of from 0.15 to 0.45. Next a film is formed from the polyolefin resin selected in the first step. Finally the film formed in the second step is oriented in a sequential manner. The films produced by this process are characterized by having an ultimate elongation at least 1.5 times greater in the MD as compared to the CD and the 2% secant modulus is a least 1.25 times greater in the CD as compared to the MD. The films are further characterized by having free residual shrinkage of less than 10% in the MD and less than 10% in the CD when exposed to a temperature of 90° C. for 10 minutes.

公开(公告)号：US08476393B2

公开(公告)日：2013-07-02

申请号：US12668794

申请日：2008-07-14

申请人： Colin Li Pi Shan ,  Roger L. Kuhlman ,  Gary L. Rath ,  Pamela J. Kenny ,  Morgan M. Hughes ,  Rongjuan Cong

发明人： Colin Li Pi Shan ,  Roger L. Kuhlman ,  Gary L. Rath ,  Pamela J. Kenny ,  Morgan M. Hughes ,  Rongjuan Cong

IPC分类号： C08F210/00 ,  C08F210/02

CPC分类号： C08F210/16 ,  C08L23/02 ,  C08L23/08 ,  C08L23/0807 ,  C08L2205/02 ,  C08L2666/06 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/12

摘要： The invention is related to an ethylene/α-olefin interpolymer having at least a hard segment and at least a soft segment. The soft segment contains a higher amount of comonomers than the hard segment. The hard segment has low crystallinity. The copolymer has a number of unique characteristics disclosed herein. ethylene/α-olefin interpolymers containing low crystallinity hard blocks.

摘要翻译： 本发明涉及至少具有硬链段和至少一个软链段的乙烯/α-烯烃互聚物。 软链段含有比硬链段更高量的共聚单体。 硬链段结晶度低。 共聚物具有本文公开的许多独特特征。 含有低结晶度硬嵌段的乙烯/α-烯烃互聚物。

公开(公告)号：US20110003940A1

公开(公告)日：2011-01-06

申请号：US12814902

申请日：2010-06-14

申请人： Teresa P. Karjala ,  Rongjuan Cong ,  Colleen M. Tice ,  Sarah M. Hayne ,  Mehmet Demirors ,  Lori L. Kardos

发明人： Teresa P. Karjala ,  Rongjuan Cong ,  Colleen M. Tice ,  Sarah M. Hayne ,  Mehmet Demirors ,  Lori L. Kardos

IPC分类号： C08F210/14 ,  C08L23/06 ,  C08L23/08

CPC分类号： C08F10/02 ,  C08F10/00 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/06 ,  C08F4/64193 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/12 ,  C08F2500/20

摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions are useful for making many articles, especially including films. Formulations made into films comprising the new polymers are also disclosed, especially blends with synthetic polymer like LDPE where the % LDPE is less than 50% in which the MD shrink tension is greater than 15 cN, puncture is greater than 75 ft-lb/in3, and haze is less than 20%. The polymers are made using a metal complex of a polyvalent aryloxyether.

摘要翻译： 已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物可用于制备许多制品，特别是包括膜。 还公开了制备成包含新聚合物的膜的制剂，特别是与合成聚合物如LDPE的共混物，其中LDPE小于50％，MD收缩张力大于15cN，穿刺度大于75ft-lb / in3 ，雾度小于20％。 聚合物使用多价芳氧基醚的金属络合物制成。