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1.发明申请FABRICATION METHOD OF ELECTRODE MATERIAL, ELECTRODE MATERIAL, AND NON-AQUEOUS LITHIUM ION SECONDARY BATTERY 审中-公开电极材料，电极材料和非水性锂离子二次电池的制造方法公开(公告)号：US20080299459A1
公开(公告)日：2008-12-04
申请号：US12128001
申请日：2008-05-28
申请人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
发明人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
CPC分类号： C01G31/00 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2006/40 , H01M4/485
摘要： The ions other than a lithium ion and having a greater ion radius is interposed, before the lithium ion is doped, as an interlayer securing member in a vanadium oxide having a layered crystal into which the lithium ion can be doped. Since the interlayer securing member is interposed, the dope or dedope of the lithium ion into or from the vanadium oxide afterward can smoothly be performed. A sodium ion or the like can be employed as the interlayer securing member.
摘要翻译： 除了锂离子之外并具有较大离子半径的离子在锂离子掺杂之前插入作为具有可掺杂锂离子的层状晶体的氧化钒中的层间固定构件。 由于中间层固定构件被插入，因此可以顺利地进行锂离子的掺杂或掺杂。 可以使用钠离子等作为层间固定构件。
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公开(公告)号：US20100330431A1
公开(公告)日：2010-12-30
申请号：US12873934
申请日：2010-09-01
申请人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
发明人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
CPC分类号： H01M4/131 , H01G11/46 , H01G11/50 , H01G11/86 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M10/0525 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108
摘要： An electrode laminate unit 12 of an electric storage device 10 is composed of positive electrodes 14 and negative electrodes 15, which are alternately laminated, and a lithium electrode 16 is arranged at the outermost part of the electrode laminate unit 12 so as to oppose to the negative electrode 15. A charging/discharging unit 21 having first and second energization control units 21a and 21b is connected to a positive-electrode terminal 18, negative-electrode terminal 19, and a lithium-electrode terminal 20. Electrons are moved from the lithium electrode 16 to the positive electrode 14 through the first energization control unit 21a, and lithium ions are doped into the positive electrode 14 from the lithium electrode 16. Electrons are moved from the lithium electrode 16 to the negative electrode 15 through the second energization control unit 21b, and lithium ions are doped into the negative electrode 15 from the lithium electrode 16. The lithium ions are doped into both of the positive electrode 14 and the negative electrode 15 as described above, whereby the doping time can dramatically be shortened.
摘要翻译： 蓄电装置10的电极层叠单元12由交替层叠的正极14和负极15构成，锂电极16配置在电极层叠单元12的最外侧，以与电极层叠单元12相对。 负极15.具有第一和第二通电控制单元21a和21b的充电/放电单元21连接到正极端子18，负极端子19和锂电极端子20.电子从锂 电极16通过第一通电控制单元21a连接到正极14，并且锂离子从锂电极16掺杂到正极14中。电子通过第二通电控制单元从锂电极16移动到负极15 21b，并且锂离子从锂电极16掺杂到负极15中。锂离子掺杂到两者中 如上所述，由此可以显着地缩短掺杂时间。
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公开(公告)号：US07846219B2
公开(公告)日：2010-12-07
申请号：US12127989
申请日：2008-05-28
申请人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
发明人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
CPC分类号： H01M4/131 , H01G11/46 , H01G11/50 , H01G11/86 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M10/0525 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108
摘要： An electrode laminate unit of an electric storage device is composed of positive electrodes and negative electrodes, which are alternately laminated, and a lithium electrode arranged at the outermost part of the electrode laminate unit so as to oppose the negative electrode. A charging/discharging unit having first and second energization control units connected to a positive-electrode terminal, negative-electrode terminal, and a lithium-electrode terminal. Electrons are moved from the lithium electrode to the positive electrode through the first energization control unit, and lithium ions are doped into the positive electrode from the lithium electrode. Electrons are moved from the lithium electrode to the negative electrode through the second energization control unit, and lithium ions are doped into the negative electrode from the lithium electrode. The lithium ions are doped into both of the positive and negative electrodes, whereby the doping time can be dramatically shortened.
摘要翻译： 蓄电装置的电极层叠单元由交替层叠的正极和负极以及布置在电极层叠单元的最外部的锂电极与负极相对。 具有连接到正极端子，负极端子和锂电极端子的第一和第二通电控制单元的充电/放电单元。 电子通过第一通电控制单元从锂电极移动到正电极，并且从锂电极将锂离子掺杂到正极中。 电子通过第二通电控制单元从锂电极移动到负极，并且锂离子从锂电极掺杂到负极中。 锂离子被掺杂到正电极和负电极中，由此可以显着缩短掺杂时间。
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4.发明申请公开(公告)号：US20090104534A1
公开(公告)日：2009-04-23
申请号：US12298410
申请日：2007-11-09
申请人： Satoko Kaneko , Masahiko Taniguchi , Asao Iwata , Ryuji Shiozaki , Nobuo Ando
发明人： Satoko Kaneko , Masahiko Taniguchi , Asao Iwata , Ryuji Shiozaki , Nobuo Ando
CPC分类号： H01M4/131 , H01M4/366 , H01M4/485 , H01M4/5815 , H01M4/602 , H01M10/0525 , H01M2004/021 , H01M2004/027 , Y10T29/49108
摘要： A crystal structure is provided to improve a characteristic of an electrode material, such as vanadium oxide. In the crystal structure, an amorphous state and a layered crystal state coexist at a predetermined ratio in a layered crystalline material such as vanadium oxide. In the layered crystalline material having such a layered crystal structure, layered crystal particles having a layer length L1 of 30 nm or shorter are formed. Ions are easily intercalated to and deintercalated from between the layers. When such a material is used for the positive electrode active material, a nonaqueous lithium secondary battery of which the discharge capacity and the cycle characteristic are good is manufactured.
摘要翻译： 提供晶体结构以改善诸如氧化钒的电极材料的特性。 在晶体结构中，在诸如氧化钒的层状结晶材料中，非晶态和层状晶体状态以预定比率共存。 在具有这种层状晶体结构的层状结晶材料中，形成层长L1为30nm以下的层状结晶粒子。 离子易于插入到层之间并从层之间脱嵌。 当将这种材料用于正极活性物质时，制造其放电容量和循环特性良好的非水锂二次电池。
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5.发明授权Electrode material, method of manufacturing thereof and nonaqueous lithium secondary battery 有权电极材料，其制造方法和非水系锂二次电池公开(公告)号：US08241792B2
公开(公告)日：2012-08-14
申请号：US12298410
申请日：2007-11-09
申请人： Satoko Kaneko , Masahiko Taniguchi , Asao Iwata , Ryuji Shiozaki , Nobuo Ando
发明人： Satoko Kaneko , Masahiko Taniguchi , Asao Iwata , Ryuji Shiozaki , Nobuo Ando
CPC分类号： H01M4/131 , H01M4/366 , H01M4/485 , H01M4/5815 , H01M4/602 , H01M10/0525 , H01M2004/021 , H01M2004/027 , Y10T29/49108
摘要： A crystal structure is provided to improve a characteristic of an electrode material, such as vanadium oxide. In the crystal structure, an amorphous state and a layered crystal state coexist at a predetermined ratio in a layered crystalline material such as vanadium oxide. In the layered crystalline material having such a layered crystal structure, layered crystal particles having a layer length L1 of 30 nm or shorter are formed. Ions are easily intercalated to and deintercalated from between the layers. When such a material is used for the positive electrode active material, a nonaqueous lithium secondary battery of which the discharge capacity and the cycle characteristic are good is manufactured.
摘要翻译： 提供晶体结构以改善诸如氧化钒的电极材料的特性。 在晶体结构中，在诸如氧化钒的层状结晶材料中，非晶态和层状晶体状态以预定比率共存。 在具有这种层状晶体结构的层状结晶材料中，形成层长L1为30nm以下的层状结晶粒子。 离子易于插入到层之间并从层之间脱嵌。 当将这种材料用于正极活性物质时，制造其放电容量和循环特性良好的非水锂二次电池。
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公开(公告)号：US20100173184A1
公开(公告)日：2010-07-08
申请号：US12298345
申请日：2007-11-09
申请人： Ryuji Shiozaki , Asao Iwata , Satoko Kaneko , Nobuo Ando , Masahiko Taniguchi
发明人： Ryuji Shiozaki , Asao Iwata , Satoko Kaneko , Nobuo Ando , Masahiko Taniguchi
CPC分类号： H01M10/0525 , C01G31/00 , C01P2002/72 , C01P2002/88 , C01P2004/03 , C01P2006/40 , H01M4/131 , H01M4/364 , H01M4/485 , H01M4/587 , H01M4/602 , H01M4/622 , H01M4/70 , H01M10/058
摘要： It has been found that when the potentials of the positive electrode and the negative electrode of the lithium ion secondary battery after the electrodes are short-circuited are each within a predetermined range, the battery produces high energy density. That is the present invention provides a lithium ion secondary battery having a positive electrode, a negative electrode and an electrolyte containing a lithium salt and an aprotic organic in which a positive electrode active material is a material allowing lithium ions and/or anions to be reversibly doped thereinto, and a negative electrode active material is a material allowing lithium ions to be reversibly doped thereinto, and the potentials of the positive electrode and the negative electrode after the positive electrode and the negative electrode are short-circuited are each selected to be within a range from 0.5 V to 2.0 V.
摘要翻译： 已经发现，当电极短路后锂离子二次电池的正极和负极的电位都在预定范围内时，电池产生高能量密度。 本发明提供一种具有正极，负极和含有锂盐和非质子性有机物的电解质的锂离子二次电池，其中正极活性物质是允许锂离子和/或阴离子可逆的材料 并且负极活性物质是允许锂离子被可逆地掺杂的材料，正极和负极之间的正极和负极的电位短路，分别选择在 范围从0.5 V到2.0 V.
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公开(公告)号：US20080299455A1
公开(公告)日：2008-12-04
申请号：US12127989
申请日：2008-05-28
申请人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
发明人： Ryuji Shiozaki , Nobuo Ando , Satoko Kaneko , Masahiko Taniguchi
CPC分类号： H01M4/131 , H01G11/46 , H01G11/50 , H01G11/86 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M10/0525 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108
摘要： An electrode laminate unit 12 of an electric storage device 10 is composed of positive electrodes 14 and negative electrodes 15, which are alternately laminated, and a lithium electrode 16 is arranged at the outermost part of the electrode laminate unit 12 so as to oppose to the negative electrode 15. A charging/discharging unit 21 having first and second energization control units 21a and 21b is connected to a positive-electrode terminal 18, negative-electrode terminal 19, and a lithium-electrode terminal 20. Electrons are moved from the lithium electrode 16 to the positive electrode 14 through the first energization control unit 21a, and lithium ions are doped into the positive electrode 14 from the lithium electrode 16. Electrons are moved from the lithium electrode 16 to the negative electrode 15 through the second energization control unit 21b, and lithium ions are doped into the negative electrode 15 from the lithium electrode 16. The lithium ions are doped into both of the positive electrode 14 and the negative electrode 15 as described above, whereby the doping time can dramatically be shortened.
摘要翻译： 蓄电装置10的电极层叠单元12由交替层叠的正极14和负极15构成，锂电极16配置在电极层叠单元12的最外侧，以与电极层叠单元12相对。 负极15.具有第一和第二通电控制单元21a和21b的充电/放电单元21连接到正极端子18，负极端子19和锂电极端子20.电子从锂 电极16通过第一通电控制单元21a连接到正极14，并且锂离子从锂电极16掺杂到正极14中。电子通过第二通电控制单元从锂电极16移动到负极15 21b，并且锂离子从锂电极16掺杂到负极15中。锂离子掺杂到两者中 如上所述，由此可以显着地缩短掺杂时间。
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8.发明授权Method of producing a metal phthalocyanine compound, and method of producing a phthalocyanine compound and an analogue thereof 有权金属酞菁化合物的制造方法以及酞菁类化合物的制造方法及其类似物公开(公告)号：US08703935B2
公开(公告)日：2014-04-22
申请号：US13620046
申请日：2012-09-14
IPC分类号： C07D487/22 , C07B47/00
CPC分类号： C07D487/22 , C09B47/063 , C09B47/0675
摘要： A method of producing a metal phthalocyanine compound, which contains: conducting a reaction between at least two compounds selected from among Compounds A to F of formula (I), and a metal compound, in a buffer solution of an organic base or an inorganic base and an acid, in the presence of a dehydrating agent: wherein R is a hydrogen atom or a substituent; 1 is an integer of 0 to 4; a plurality of Rs may be the same or different from each other when 1 is 2 to 4; and G is a group of atoms necessary for forming at least one of a 5- or 6-membered aromatic ring and a 5- or 6-membered hetero ring.
摘要翻译： 一种制备金属酞菁化合物的方法，其包含：在有机碱或无机碱的缓冲溶液中，在选自式（I）的化合物A至F中的至少两种化合物和金属化合物之间进行反应 和一种酸，在脱水剂存在下，其中R是氢原子或取代基; 1为0〜4的整数， 当1为2〜4时，多个Rs可以相同或不同; 并且G是形成5-或6-元芳环和5-或6-元杂环中的至少一个所必需的一组原子。
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9.发明授权Method of producing a metal phthalocyanine compound, and method of producing a phthalocyanine compound and an analogue thereof 有权金属酞菁化合物的制造方法以及酞菁类化合物的制造方法及其类似物公开(公告)号：US08299240B2
公开(公告)日：2012-10-30
申请号：US12088412
申请日：2006-05-17
IPC分类号： C07D487/22 , C07B47/00
CPC分类号： C07D487/22 , C09B47/063 , C09B47/0675
摘要： A method of producing a metal phthalocyanine compound, which contains: conducting a reaction between at least two compounds selected from among Compounds A to F of formula (I), and a metal compound, in a buffer solution of an organic base or an inorganic base and an acid, in the presence of a dehydrating agent: wherein R is a hydrogen atom or a substituent; l is an integer of 0 to 4; a plurality of Rs may be the same or different from each other when l is 2 to 4; and G is a group of atoms necessary for forming at least one of a 5- or 6-membered aromatic ring and a 5- or 6-membered hetero ring.
摘要翻译： 一种制备金属酞菁化合物的方法，其包含：在有机碱或无机碱的缓冲溶液中，在选自式（I）的化合物A至F中的至少两种化合物和金属化合物之间进行反应 和一种酸，在脱水剂存在下，其中R是氢原子或取代基; l为0〜4的整数; 当l为2〜4时，多个Rs可以相同或不同; 并且G是形成5-或6-元芳环和5-或6-元杂环中的至少一个所必需的一组原子。
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公开(公告)号：US08110597B2
公开(公告)日：2012-02-07
申请号：US11925228
申请日：2007-10-26
IPC分类号： A61K31/40 , C07D209/02
CPC分类号： C07D209/14 , C07D209/96 , C07D401/14 , C07D403/14 , C09B23/0008 , C09B23/0016 , C09B23/0025 , C09B23/0033 , C09B23/0041 , C09B23/0066 , C09B23/06 , C09B23/086
摘要： A radioactive isotope-labeled dye compound represented by the following general formula (I): wherein R1 and R2 represent a substituent, R3 to R6 represent a substituted or unsubstituted alkyl group; R7 and R8 represent a substituted or unsubstituted alkyl group; L1 to L3 represent a substituted or unsubstituted methine group; r represents an integer of 0 to 3; P and Q represent 123I, 124I, 125I, 131I or 18F; M represents hydrogen atom, Na, or K; and m and n represent an integer of 0 to 2.
摘要翻译： 由以下通式（I）表示的放射性同位素标记的染料化合物：其中R1和R2表示取代基，R3至R6表示取代或未取代的烷基; R7和R8表示取代或未取代的烷基; L1至L3表示取代或未取代的次甲基; r表示0〜3的整数， P和Q表示123I，124I，125I，131I或18F; M表示氢原子，Na或K; m和n表示0〜2的整数。
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