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公开(公告)号：US3515733A
公开(公告)日：1970-06-02
申请号：US54577666
申请日：1966-04-27
Applicant: SANDOZ AG
Inventor： ENTSCHEL ROLAND , MUELLER CURT , WEHRLI WALTER
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Patent Agency Ranking2.发明授权Basic monoazo dyes containing an n-methylpyridinium,2- or 4-dimethylene group 失效含有N-甲基吡啶，2-或4-二甲基的基本单氧基染料
公开(公告)号：US3518247A
公开(公告)日：1970-06-30
申请号：US3518247D
申请日：1965-08-20
Applicant: SANDOZ AG
Inventor： ALTERMATT RUDOLF , ENTSCHEL ROLAND , MULLER CURT
IPC: C09B1/20 , C09B1/50 , C09B23/00 , C09B43/00 , C09B43/11 , C09B44/00 , C09B51/00 , C09B69/00 , C09B1/28 , C09B29/36
CPC classification number: C09B1/20 , C09B1/50 , C09B23/00 , C09B43/006 , C09B43/11 , C09B44/005 , C09B51/00 , C09B69/00 , C09B69/001 , Y10S8/919 , Y10S8/927
Abstract: The invention comprises dyes of the formula where A is a dyestuff residue free from sulphonic acid groups; R1 and R2 are H or alkyl; y is a direct bond or a bivalent radical; -CZ is an aromatic heterocycle which contains a quaternary nitrogen and may contain further hetero atoms or substituents, or be condensed with further rings; n is 1 or 2 and m is an integer greater than or equal to n. The compounds are prepared either by reacting compounds of the formulae where -CZ1 is -CZ or an unquaternized version thereof, B is A or is the residue of a compound capable of forming A, or by first reacting the above vinyl compound with ammonia or a primary amine to give where R is H or optionally substituted hydrocarbon which is then reacted with a dyestuff or dyestuff intermediate containing a reactive group to give a compound of the formula and if necessary B is then converted to A and the dyestuff quaternated.
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公开(公告)号：US3459728A
公开(公告)日：1969-08-05
申请号：US3459728D
申请日：1967-01-20
Applicant: SANDOZ AG
Inventor： ENTSCHEL ROLAND , MUELLER CURT , WEHRLI WALTER
IPC: C09B44/04 , C09B29/00 , C07C107/06
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4.发明授权
公开(公告)号：US3888850A
公开(公告)日：1975-06-10
申请号：US34946073
申请日：1973-04-09
Applicant: SANDOZ AG
Inventor： ENTSCHEL ROLAND , KAEPPELI VIKTOR
IPC: C09B23/14
CPC classification number: C09B23/145 , Y10S8/927
Abstract: Dyes of the formula
WHEREIN R is lower alkyl or substituted lower alkyl, R'' is hydrogen or methyl, R1 is alkyl of at least two carbon atoms, haloalkyl of at least two carbon atoms, aryl, substituted aryl, benzyl or substituted benzyl, R2 is methyl or ethyl, and A is an anion, are useful for dyeing and printing polymers and copolymers of acrylonitrile and polyamides and polyesters which have been modified by the introduction of acid groups.-
公开(公告)号：US3457260A
公开(公告)日：1969-07-22
申请号：US58571766
申请日：1966-10-06
Applicant: SANDOZ AG
Inventor： ENTSCHEL ROLAND , MUELLER CURT , WEHRLI WALTER
IPC: B21D53/04 , C08K5/00 , C08K5/29 , C09B1/00 , C09B1/28 , C09B1/32 , C09B1/50 , C09B1/51 , C09B1/54 , C09B25/00 , C09B43/40 , C09B44/02 , C09B44/04 , C09B51/00 , C09B62/66 , C09B69/00 , C09B23/10
CPC classification number: C09B69/002 , B21D53/04 , C08K5/0041 , C08K5/29 , C09B1/002 , C09B1/28 , C09B1/32 , C09B1/50 , C09B1/51 , C09B1/542 , C09B25/00 , C09B43/40 , C09B44/02 , C09B44/04 , C09B51/00 , C09B62/66 , C09B69/00 , Y10S8/927
Abstract: The invention comprises basic dyes of formula wherein R1 is hydrogen or a C1-C8 alkyl group, R2 is a methyl or ethyl group, R3 is a chlorine or bromine atom, or cyano or C1-C8 alkyl-sulphonyl group, R4 is a hydrogen, chlorine or bromine atom and Z is a C1-C3 alkylene or -CHOH.CH2-group. The dyes are prepared by diazotizing an amine of formula and coupling the diazonium compound with a compound of formula The dyes are preferably used to colour articles made from polymers composed of more than 80% acrylonitrile in red, blue or brown shades.
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公开(公告)号：US3402167A
公开(公告)日：1968-09-17
申请号：US42635365
申请日：1965-01-18
Applicant: SANDOZ AG
Inventor： ENTSCHEL ROLAND
IPC: C09B44/04
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