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公开(公告)号：US09868797B2
公开(公告)日：2018-01-16
申请号：US14907923
申请日：2014-07-29
Inventor： Nedumbamana Sankaran , Prashant Sukumar Shinge , Sharankumar Shetty , Girish Chandra , Haif Al-Shammari , Abdulaziz Hamad Al-Humydi , Edward Joseph Nesakumar
IPC: C07F17/00 , C08F4/6592 , C08F10/00 , C08F4/76 , C07C211/48 , C07F5/02 , C07C211/52 , C08F10/02 , C08F4/659
CPC classification number: C08F4/76 , C07C211/48 , C07C211/52 , C07C2602/08 , C07F5/02 , C07F5/025 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/02 , C08F2420/02
Abstract: A metallocene complex according to formula 1 wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5, or 6, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, X is a cyclic bridging group that is bonded to a carbon atom of the cyclopentadienyl ligand and to nitrogen, Z1, and Z4 are hydrogen or a hydrocarbon radical with 1-20 carbon atoms; adjacent substituents Z2 and Z3 and are connected to form an indenyl or tetrahydroindenyl ring system and R is hydrogen or a hydrocarbon radical with 1-20 carbon atoms. Also described is a composition comprising the metallocene complex, a process for the preparation of the complex, and a process for the polymerization of olefin polymers in the presence of the metallocene complex.
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公开(公告)号：US09815917B2
公开(公告)日：2017-11-14
申请号：US14912631
申请日：2014-08-29
Inventor： Nedumbamana Sankaran , Prashant Sukumar Shinge , Sharankumar Shetty , Girish Chandra , Haif Al-Shammari , Abdulaziz Hamad Al-Humydi , Edward Joseph Nesakumar , Pradeep Jeevaji Nadkarni
IPC: C07F17/00 , C08F4/6592 , C08F110/02 , C07F7/00 , C08F4/659
CPC classification number: C08F110/02 , C07F7/00 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F2500/10
Abstract: The invention relates to a metallocene complex according to formula (1) wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, Z1, Z2, Z3 and Z4 are identical or different and can be chosen from the group consisting of hydrogen and a hydrocarbon radical with 1-20 carbon atoms, and adjacent substituents Z can form a ring system together with the carbon atoms of the Cp ring to which they are bound.
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公开(公告)号：US20140378694A1
公开(公告)日：2014-12-25
申请号：US14366691
申请日：2012-12-13
Applicant: Saudi Basic Industries Corporation
Inventor： Abdulaziz Hamad Al-Humydi , Atieh Aburaqabah , Christian Gorl , Helmut Alt
CPC classification number: C07F7/00 , C07C1/321 , C07C2102/08 , C07C2602/08 , C07F17/00 , C08F4/65912 , C08F110/02 , C07C13/465 , C08F4/65927
Abstract: A process to prepared bridged bis(indenyl)ligands, comprising the step of reacting a 2-indenylpinacolyl borane compound with a bromosubstituted compound in the presence of a Pd catalyst and a base to form the corresponding bridged bis(indenyl) ligand. The process may further comprise the step of reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base to form the corresponding 2-indenylpinacolylborane compound. These bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2′-bis(2-indenyl)biphenyl ZrCl2 and 1,2-bis(2-indenyl)benzene ZrCl2. These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more α-olefins, preferably for the polymerization of ethylene.
Abstract translation: 制备桥连双（茚基）配体的方法，包括在Pd催化剂和碱的存在下使2-茚基茚基甲硅烷基化合物与溴取代的化合物反应以形成相应的桥连双（茚基）配体的步骤。 该方法还可以包括在Pd催化剂和碱的存在下使2-溴茚化合物与频哪醇硼烷反应以形成相应的2-茚基茚基苯基硼烷化合物的步骤。 这些桥连的双（茚基）配体可适当地用于制备茂金属络合物，例如2,2'-双（2-茚基）联苯基ZrCl 2和1,2-双（2-茚基）苯ZrCl 2。 这些金属茂络合物可以用于聚合，任选地在助催化剂存在下一种或多种α-烯烃，优选用于乙烯的聚合。
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公开(公告)号：US09321864B2
公开(公告)日：2016-04-26
申请号：US14368431
申请日：2012-12-20
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Bart Albertus Hubertus van den Esschert , Maria Johanna Willems , Abdulaziz Hamad Al-Humydi , Yahya Banat , Atieh Aburaqabah , Said Fellahi
IPC: C08F4/64 , C08F2/00 , C08F210/16 , C08F110/02 , C08L23/06 , C08J5/22 , C08F10/00
CPC classification number: C08L23/06 , C08F2/002 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/02 , C08J5/2231 , C08J2335/04 , C08F4/65927 , C08F4/642 , C08F2500/08 , C08F2500/26 , C08F4/65904
Abstract: The present invention relates to a catalyst composition for the polymerisation of olefins comprising a support containing a single site catalyst component, a catalyst activator and a modifier wherein the modifier is the product of reacting an aluminum compound of general formula AI(R1, R2, R3) with an amine compound of general formula N(R4, R5, R6). The catalyst composition reduces fouling and/or sheeting when used to catalyse the polymerisation of olefins. The present invention also relates to a method for the polymerisation of olefins using the catalyst composition of the invention.
Abstract translation: 本发明涉及一种用于烯烃聚合的催化剂组合物，其包含含有单中心催化剂组分，催化剂活化剂和改性剂的载体，其中改性剂是使通式AI的铝化合物（R1，R2，R3 ）与通式为N（R4，R5，R6）的胺化合物反应。 催化剂组合物当用于催化烯烃的聚合时减少结垢和/或片材。 本发明还涉及使用本发明的催化剂组合物使烯烃聚合的方法。
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公开(公告)号：US09234054B2
公开(公告)日：2016-01-12
申请号：US14366690
申请日：2012-12-13
Applicant: Saudi Basic Industries Corporation
Inventor： Abdulaziz Hamad Al-Humydi , Atieh Aburaqabah , Christian Gorl , Helmut Alt
IPC: C07C13/36 , C07C13/38 , C07C1/32 , C07F17/00 , C08F4/6592 , C08F10/02 , C08F210/16 , C08F4/76 , C07C13/32 , C07C2/66 , C08F110/02
CPC classification number: C08F4/76 , C07C1/321 , C07C2/66 , C07C13/32 , C07C13/36 , C07C13/38 , C07F17/00 , C08F4/65927 , C08F110/02 , C08F4/65912
Abstract: A process comprising reacting a 2-indenylboranic acid (ester) with a bromosubstituted compound in the presence of the Pd catalyst bis(triphenylphosphin)palladium dichloride and a base to form the corresponding bridged bis(indenyl) ligand. Where the 2-indenylboranic acid (ester) is the pinacolester of 2-indenylboranic acid, the process may further comprise reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base to form the corresponding 2-indenylpinacolylborane compound. Bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2′-bis(2-indenyl)biphenyl ZrCl2 and 1,2-bis (2-indenyl)benzene ZrCl2. These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more α-olefins, preferably for the polymerization of ethylene.
Abstract translation: 一种方法包括在Pd催化剂双（三苯基膦）二氯化钯和碱的存在下使2-茚基硼烷酸（酯）与溴取代的化合物反应，形成相应的桥连双（茚基）配体。 当2-茚基硼烷酸（酯）是2-茚基硼烷酸的频哪醇酯时，该方法还可以包括在Pd催化剂和碱的存在下使2-溴茚化合物与频哪醇硼烷反应，形成相应的2-茚基茚基苯基硼烷化合物 。 桥连的双（茚基）配体可适当地用于制备茂金属络合物，例如2,2'-双（2-茚基）联苯基ZrCl 2和1,2-双（2-茚基）苯ZrCl 2。 这些金属茂络合物可以用于聚合，任选地在助催化剂存在下一种或多种α-烯烃，优选用于乙烯的聚合。
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Patent Agency Ranking
公开(公告)号：US20150031824A1
公开(公告)日：2015-01-29
申请号：US14368431
申请日：2012-12-20
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Bart Albertus Hubertus van den Esschert , Maria Johanna Willems , Abdulaziz Hamad Al-Humydi , Yahya Banat , Atieh Aburaqabah , Said Fellahi
IPC: C08F210/16
CPC classification number: C08L23/06 , C08F2/002 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/02 , C08J5/2231 , C08J2335/04 , C08F4/65927 , C08F4/642 , C08F2500/08 , C08F2500/26 , C08F4/65904
Abstract: The present invention relates to a catalyst composition for the polymerisation of olefins comprising a support containing a single site catalyst component, a catalyst activator and a modifier wherein the modifier is the product of reacting an aluminum compound of general formula AI(R1, R2, R3) with an amine compound of general formula N(R4, R5, R6). The catalyst composition reduces fouling and/or sheeting when used to catalyse the polymerisation of olefins. The present invention also relates to a method for the polymerisation of olefins using the catalyst composition of the invention.
Abstract translation: 本发明涉及一种用于烯烃聚合的催化剂组合物，其包含含有单中心催化剂组分，催化剂活化剂和改性剂的载体，其中改性剂是使通式AI的铝化合物（R1，R2，R3 ）与通式为N（R4，R5，R6）的胺化合物反应。 催化剂组合物当用于催化烯烃的聚合时减少结垢和/或片材。 本发明还涉及使用本发明的催化剂组合物使烯烃聚合的方法。
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公开(公告)号：US10513569B2
公开(公告)日：2019-12-24
申请号：US15788140
申请日：2017-10-19
Inventor： Nedumbamana Sankaran , Prashant Shinge , Sharankumar Shetty , Girish Chandra , Haif Al-Shammari , Abdulaziz Hamad Al-Humydi , Edward Joseph Nesakumar , Pradeep Jeevaji Nadkarni
IPC: C08F110/02 , C08F210/16 , C08F4/6592 , C07F17/00 , C07F7/00 , C08F4/659
Abstract: The invention relates to a metallocene complex according to formula (1) wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, Z1, Z2, Z3 and Z4 are identical or different and can be chosen from the group consisting of hydrogen and a hydrocarbon radical with 1-20 carbon atoms, and adjacent substituents Z can form a ring system together with the carbon atoms of the Cp ring to which they are bound.
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公开(公告)号：US09902845B2
公开(公告)日：2018-02-27
申请号：US14368426
申请日：2012-12-20
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Bart Albertus Hubertus van den Esschert , Maria Johanna Willems , Abdulaziz Hamad Al-Humydi , Yahya Banat , Said Fellahi
IPC: C08L23/06 , C08F110/02 , C08F210/16 , C08J5/22 , C08F10/00 , C08F2/00
CPC classification number: C08L23/06 , C08F2/002 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/02 , C08J5/2231 , C08J2335/04 , C08F4/65927 , C08F4/642 , C08F2500/08 , C08F2500/26 , C08F4/65904
Abstract: The invention relates to linear low density polyethylene having a density in the range from about 900 kg/m3 to less than about 940 kg/m3 as determined using IS01872-2, having a molecular weight distribution (Mw/Mn) in the range from 2.5 to 3.5, having an area under the peak in the temperature range from 20 to 40° C. determined using an analytical temperature rising elution fractionation analysis using 1,2-dichlorobenzene and a heating rate of 1° C./min, wherein the area is in the range from 5 to 20% of the sum of the areas under all peaks determined with the analytical temperature rising elution fractionation analysis.
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公开(公告)号：US09000200B2
公开(公告)日：2015-04-07
申请号：US14366691
申请日：2012-12-13
Applicant: Saudi Basic Industries Corporation
Inventor： Abdulaziz Hamad Al-Humydi , Atieh Aburaqabah , Christian Gorl , Helmut Alt
IPC: C07C1/32 , C07F17/00 , C07F7/00 , C08F110/02 , C08F4/659
CPC classification number: C07F7/00 , C07C1/321 , C07C2102/08 , C07C2602/08 , C07F17/00 , C08F4/65912 , C08F110/02 , C07C13/465 , C08F4/65927
Abstract: A process to prepared bridged bis(indenyl)ligands, comprising the step of reacting a 2-indenylpinacolyl borane compound with a bromosubstituted compound in the presence of a Pd catalyst and a base to form the corresponding bridged bis(indenyl) ligand. The process may further comprise the step of reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base to form the corresponding 2-indenylpinacolylborane compound. These bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2′-bis(2-indenyl)biphenyl ZrCl2 and 1,2-bis(2-indenyl)benzene ZrCl2. These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more α-olefins, preferably for the polymerization of ethylene.
Abstract translation: 制备桥连双（茚基）配体的方法，包括在Pd催化剂和碱的存在下使2-茚基茚基甲硅烷基化合物与溴取代的化合物反应以形成相应的桥连双（茚基）配体的步骤。 该方法还可以包括在Pd催化剂和碱的存在下使2-溴茚化合物与频哪醇硼烷反应以形成相应的2-茚基茚基苯基硼烷化合物的步骤。 这些桥连的双（茚基）配体可适当地用于制备茂金属络合物，例如2,2'-双（2-茚基）联苯基ZrCl 2和1,2-双（2-茚基）苯ZrCl 2。 这些金属茂络合物可以用于聚合，任选地在助催化剂存在下一种或多种α-烯烃，优选用于乙烯的聚合。
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公开(公告)号：US20150011702A1
公开(公告)日：2015-01-08
申请号：US14368426
申请日：2012-12-20
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Bart Albertus Hubertus van den Esschert , Maria Johanna Willems , Abdulaziz Hamad Al-Humydi , Yahya Banat , Said Fellahi
IPC: C08F110/02 , C08L23/06
CPC classification number: C08L23/06 , C08F2/002 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/02 , C08J5/2231 , C08J2335/04 , C08F4/65927 , C08F4/642 , C08F2500/08 , C08F2500/26 , C08F4/65904
Abstract: The invention relates to linear low density polyethylene having a density in the range from about 900 kg/m3 to less than about 940 kg/m3 as determined using IS01872-2, having a molecular weight distribution (Mw/Mn) in the range from 2.5 to 3.5, having an area under the peak in the temperature range from 20 to 40° C. determined using an analytical temperature rising elution fractionation analysis using 1,2-dichlorobenzene and a heating rate of 1° C./min, wherein the area is in the range from 5 to 20% of the sum of the areas under all peaks determined with the analytical temperature rising elution fractionation analysis.
Abstract translation: 本发明涉及使用IS01872-2测定的密度在约900kg / m 3至小于约940kg / m 3范围内的线性低密度聚乙烯，其分子量分布（Mw / Mn）为2.5 至3.5，在20〜40℃的温度范围内具有峰值以下的面积，使用1,2-二氯苯进行分析升温洗脱分级分析，加热速度为1℃/ min，其中， 在分析升温洗脱分馏分析确定的所有峰下面积的总和的5至20％的范围内。
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