公开(公告)号：US20170081258A1

公开(公告)日：2017-03-23

申请号：US15183001

申请日：2016-06-15

Applicant: SHELL OIL COMPANY

Inventor： Steven Sangyun LIM ,  Peter Tanev TANEV ,  David Morris HAMILTON, JR. ,  Suchismita SANYAL

IPC: C07C2/76

CPC classification number: C07C2/76 ,  B01J21/063 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/92 ,  B01J29/40 ,  B01J29/65 ,  B01J29/7034 ,  B01J29/7042 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/42 ,  B01J2523/00 ,  C07C2521/06 ,  C07C2523/22 ,  C07C2523/28 ,  C10G35/095 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/04 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/67

Abstract: Implementations of the disclosed subject matter provide a process for the aromatization of a methane-containing gas stream that includes contacting the methane-containing gas stream in a reaction zone of an aromatization reactor comprising an aromatization catalyst and a titanium alloy hydrogen acceptor under methane-containing gas aromatization conditions to produce a product stream comprising aromatics and hydrogen, wherein at least a portion of the produced hydrogen is bound by the titanium alloy hydrogen acceptor in the reaction zone and removed from the product and the reaction zone as titanium hydride, and wherein the titanium alloy hydrogen acceptor is a single phase alloy.

公开(公告)号：US20160368835A1

公开(公告)日：2016-12-22

申请号：US15182864

申请日：2016-06-15

Applicant: SHELL OIL COMPANY

Inventor： Steven Sangyun LIM ,  Peter Tanev TANEV ,  Shaojun MIAO ,  Anthony Tyler SIMPSON ,  Daniel Edward GERWIEN

IPC: C07C2/76 ,  B01J29/48

CPC classification number: C07C2/76 ,  B01J29/48 ,  C07C2521/06 ,  C07C2529/48 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/24

Abstract: Implementations of the disclosed subject matter provide a process for the aromatization of a methane-containing gas stream that includes contacting the methane-containing gas stream in a reaction zone of an aromatization reactor comprising an aromatization catalyst and a titanium hydrogen acceptor under methane-containing gas aromatization conditions to produce a product stream comprising aromatics and hydrogen, wherein at least a portion of the produced hydrogen is bound by the titanium hydrogen acceptor in the reaction zone and removed from the product and the reaction zone as titanium hydride, and wherein the weight ratio of titanium hydrogen acceptor to the aromatization catalyst is at least 1:1.

Abstract translation: 所公开的主题的实施提供了一种含甲烷气流的芳构化方法，该方法包括在包含芳构化催化剂和钛氢受体的含甲烷气体的芳构化反应器的反应区中使含甲烷的气流接触 芳族化条件以产生包含芳族化合物和氢气的产物流，其中至少一部分所产生的氢在反应区中被钛氢受体结合，并从产物和反应区中除去氢化钛，并且其中重量比 对于芳构化催化剂的钛氢受体为至少1:1。

公开(公告)号：US20160368836A1

公开(公告)日：2016-12-22

申请号：US15182954

申请日：2016-06-15

Applicant: SHELL OIL COMPANY

Inventor： Peter Tanev TANEV ,  Daniel Edward GERWIEN ,  Shaojun MIAO ,  Anthony Tyler SIMPSON ,  Elizabeth Colquhoun HOWLAND ,  Steven Sangyun LIM

IPC: C07C2/76 ,  B01J29/90 ,  B01J38/10 ,  B01J29/48

CPC classification number: C07C2/76 ,  B01J21/20 ,  B01J23/28 ,  B01J29/48 ,  B01J29/90 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J38/04 ,  B01J38/10 ,  B01J38/12 ,  B01J38/72 ,  B01J2229/40 ,  C07C2521/06 ,  C07C2529/48 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/24 ,  C07C15/04

Abstract: Implementations of the disclosed subject matter provide a process for the aromatization of a methane-containing gas stream that includes contacting the methane-containing gas stream in a reaction zone of an aromatization reactor comprising an aromatization catalyst and a zirconium hydrogen acceptor under methane-containing gas aromatization conditions to produce a product stream comprising aromatics and hydrogen, wherein at least a portion of the produced hydrogen is bound by the zirconium hydrogen acceptor in the reaction zone and removed from the product and the reaction zone as zirconium hydride, and wherein the weight ratio of zirconium hydrogen acceptor to the aromatization catalyst is at least 1:1.

Abstract translation: 所公开的主题的实施方案提供了含甲烷气流的芳构化方法，该方法包括在包含芳构化催化剂和锆氢受体的芳构化反应器的含甲烷气体的反应区内使含甲烷的气流接触 芳族化条件以产生包含芳族化合物和氢气的产物流，其中所产生的氢的至少一部分由反应区中的锆氢受体结合，并且作为氢化锆从产物和反应区除去，并且其中重量比 的锆氢受体与芳构化催化剂的摩尔比为至少1:1。