公开(公告)号：US20190276372A1

公开(公告)日：2019-09-12

申请号：US16463468

申请日：2017-06-07

Applicant: Shenzhen University

Inventor： Zhu Ding ,  Bingyao Tian ,  Mingyan Wang ,  Zhiwei Zhou ,  Chen Sun

IPC: C04B41/46 ,  C04B41/63 ,  C04B41/48 ,  C04B41/50

Abstract: The present invention provides a concrete protective agent and a preparation method thereof, and a concrete protective film and a preparation method thereof. The concrete protective agent provided in the present invention includes the following components: water, oxalic acid, a defoaming agent, and a film-forming agent. When the concrete protective agent provided in the present invention is used for concrete protection, oxalic acid in the protective agent can react with calcium ions in concrete for in situ generation of calcium oxalate monohydrate inside and on a surface of concrete to obtain a protective film with strong adhesion to concrete. The film-forming agent in the protective agent is used as a template to adjust and control growth of calcium oxalate crystals, so as to improve waterproof performance and corrosion resistance to sulfate and chloride ions of the protective film. Preparation methods provided in the present invention are simple and practical and are suitable for mass production.

公开(公告)号：US10851024B2

公开(公告)日：2020-12-01

申请号：US16463468

申请日：2017-06-07

Applicant: Shenzhen University

Inventor： Zhu Ding ,  Bingyao Tian ,  Mingyan Wang ,  Zhiwei Zhou ,  Chen Sun

IPC: C04B41/46 ,  C04B41/48 ,  C04B41/50 ,  C04B41/63

Abstract: The present invention provides a concrete protective agent and a preparation method thereof, and a concrete protective film and a preparation method thereof. The concrete protective agent provided in the present invention includes the following components: water, oxalic acid, a defoaming agent, and a film-forming agent. When the concrete protective agent provided in the present invention is used for concrete protection, oxalic acid in the protective agent can react with calcium ions in concrete for in situ generation of calcium oxalate monohydrate inside and on a surface of concrete to obtain a protective film with strong adhesion to concrete. The film-forming agent in the protective agent is used as a template to adjust and control growth of calcium oxalate crystals, so as to improve waterproof performance and corrosion resistance to sulfate and chloride ions of the protective film. Preparation methods provided in the present invention are simple and practical and are suitable for mass production.

公开(公告)号：US09957162B2

公开(公告)日：2018-05-01

申请号：US15188964

申请日：2016-06-21

Applicant: SHENZHEN UNIVERSITY

Inventor： Feng Xing ,  Ning Zhang ,  Zhu Ding ,  Biao Liu ,  Ningxu Han ,  Weilun Wang ,  Dawang Li ,  Wujian Long ,  Biqin Dong ,  Xiaodong Wang

IPC: C01B25/45 ,  C04B35/624 ,  C30B1/02 ,  C30B29/14 ,  C30B29/22 ,  C04B35/447 ,  C04B28/02 ,  C04B35/645 ,  C30B1/04 ,  C30B1/10 ,  C04B103/44

CPC classification number: C01B25/45 ,  C01B25/32 ,  C01B25/34 ,  C01B37/065 ,  C04B12/02 ,  C04B28/02 ,  C04B35/447 ,  C04B35/624 ,  C04B35/6455 ,  C04B2103/445 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/447 ,  C04B2235/6567 ,  C04B2235/661 ,  C30B1/02 ,  C30B1/04 ,  C30B1/10 ,  C30B29/14 ,  C30B29/22 ,  C04B22/16 ,  C04B18/023

Abstract: Provided is a ternary inorganic compound crystal having a molecular formula of Ca8Al12P2O31, and a preparation method thereof comprising the following steps: weighing calcium salts, aluminum salts and phosphate respectively according to the molar ratio of calcium, aluminum and phosphorus in the molecular formula Ca8Al12P2O31; calcining at 1550˜1570° C., cooling, and grinding to obtain the ternary inorganic compound crystal. Also provided is an application of the ternary inorganic compound in gelling materials and molecular sieves, nonlinear optical crystals, and photochromic materials.

公开(公告)号：US20160297680A1

公开(公告)日：2016-10-13

申请号：US15188964

申请日：2016-06-21

Applicant: SHENZHEN UNIVERSITY

Inventor： Feng Xing ,  Ning Zhang ,  Zhu Ding ,  Biao Liu ,  Ningxu Han ,  Weilun Wang ,  Dawang Li ,  Wujian Long ,  Biqin Dong ,  Xiaodong Wang

IPC: C01B25/45 ,  C04B35/624 ,  C30B29/22 ,  C30B1/04 ,  C30B1/10 ,  C04B35/447 ,  C04B35/645

CPC classification number: C01B25/45 ,  C01B25/32 ,  C01B25/34 ,  C01B37/065 ,  C04B12/02 ,  C04B28/02 ,  C04B35/447 ,  C04B35/624 ,  C04B35/6455 ,  C04B2103/445 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/447 ,  C04B2235/6567 ,  C04B2235/661 ,  C30B1/02 ,  C30B1/04 ,  C30B1/10 ,  C30B29/14 ,  C30B29/22 ,  C04B22/16 ,  C04B18/023

Abstract: Provided is a ternary inorganic compound crystal having a molecular formula of Ca8Al12P2O31, and a preparation method thereof comprising the following steps: weighing calcium salts, aluminum salts and phosphate respectively according to the molar ratio of calcium, aluminum and phosphorus in the molecular formula Ca8Al12P2O31; calcining at 1550˜1570° C., cooling, and grinding to obtain the ternary inorganic compound crystal. Also provided is an application of the ternary inorganic compound in gelling materials and molecular sieves, nonlinear optical crystals, and photochromic materials.

Abstract translation: 本发明提供一种分子式为Ca8Al12P2O31的三元无机化合物晶体及其制备方法，其特征在于包括以下步骤：分子式Ca8Al12P2O31中钙，铝和磷的摩尔比分别称重钙盐，铝盐和磷酸盐; 在1550〜1570℃下煅烧，冷却，研磨，得到三元无机化合物结晶。 还提供了三元无机化合物在胶凝材料和分子筛，非线性光学晶体和光致变色材料中的应用。