公开(公告)号：US20150262800A1

公开(公告)日：2015-09-17

申请号：US14644430

申请日：2015-03-11

Applicant: SHIMADZU CORPORATION

Inventor： Hiroshi SUGAWARA

IPC: H01J49/00 ,  H01J49/42

CPC classification number: H01J49/0009 ,  H01J49/0031 ,  H01J49/005 ,  H01J49/4215

Abstract: A triple quadrupole mass spectrometer provided with: a calibration information storage section for storing mass calibration information showing the relationship between the mass-to-charge ratio and a calibration value, with a CID gas pressure as a parameter, for each measurement mode of an MS/MS analysis including a dissociating operation using a collision cell; and a controller for calibrating the mass-to-charge ratio of the ion to be detected by a detector, by reading, from the calibration information storage section, the mass calibration information corresponding to the measurement mode to be performed and a specified CID gas pressure and by driving each the front and rear quadrupoles and using that information.

Abstract translation: 三重四极杆质谱仪具有：校准信息存储部分，用于存储质量校准信息，该质量校准信息以CID气体压力为参数存储质量比与校正值之间的关系，用于MS的每个测量模式 / MS分析，包括使用碰撞池的解离操作; 以及控制器，用于通过从校准信息存储部读取与要执行的测量模式相对应的质量校准信息和指定的CID气体压力来校准由检测器检测的离子的质荷比， 并通过驱动前后四极杆并使用该信息。

公开(公告)号：US20140217280A1

公开(公告)日：2014-08-07

申请号：US13761933

申请日：2013-02-07

Applicant: SHIMADZU CORPORATION

Inventor： Hiroshi SUGAWARA

IPC: H01J49/02 ,  H01J49/24

CPC classification number: H01J49/24 ,  H01J49/005

Abstract: Vacuum gauges are arranged in intermediate vacuum chamber and analytical chamber 10 in which collision cell is installed, and gas pressure determination unit determines whether or not the gas pressures detected by vacuum gauges are at or below a threshold value prior to analysis, and issues an alert if they are at or below the threshold value. If the supply of CID gas into collision cell stagnates, the quantity of CID gas flowing out into the analytical chamber will decrease, and the degree of vacuum in the analytical chamber will thus become too high. Furthermore, if the heated capillary becomes clogged, the quantity of gas flow into the intermediate vacuum chamber from the ionization chamber, which has an ambient pressure atmosphere, will decrease, and thus the degree of vacuum inside the intermediate vacuum chamber will become too high.

Abstract translation: 真空计配置在中间真空室和分析室10中，其中安装了碰撞室，气体压力确定单元确定在分析前由真空计测得的气体压力是否在阈值以下，并发出警报 如果它们处于或低于阈值。 如果将CID气体供应到碰撞池中停滞，则流入分析室的CID气体的量将减少，因此分析室中的真空度将变得过高。 此外，如果加热的毛细管堵塞，则从具有环境压力气氛的电离室流入中间真空室的气体量将降低，因此中间真空室内的真空度将变得过高。

公开(公告)号：US20160209378A1

公开(公告)日：2016-07-21

申请号：US14914354

申请日：2013-08-26

Applicant: SHIMADZU CORPORATION

Inventor： Yuko KOBAYASHI ,  Hiroshi SUGAWARA ,  Tairo OGURA

IPC: G01N30/72 ,  H01J49/42

CPC classification number: G01N30/72 ,  G01N30/8644 ,  H01J49/0031 ,  H01J49/4225

Abstract: When setting analysis conditions, an analysis operator sets, on a dwell-time calculation/loop-time listing window, the target value of a loop time corresponding to the measurement-time interval to repeat an analysis for one ion, and clicks a dwell time calculation button. Then, a dwell time calculator computes the dwell time for each event, based on the target value of the loop time, the arrangement of events set at that point in time, the number of target ion species set in each event, and other conditional factors. The calculated result is displayed in a dwell time calculation result display field in a listing table. The largest and smallest values of the dwell time are displayed in the largest/smallest dwell time display field. The analysis operator checks this display and changes the target value of the loop time and/or the measurement time of the event so as to achieve an appropriate dwell time.

Abstract translation: 在设置分析条件时，分析算子在停留时间计算/循环时间列表窗口上设置与测量时间间隔相对应的循环时间的目标值，以重复对一个离子的分析，并且点击停留时间 计算按钮。 然后，驻留时间计算器基于循环时间的目标值，在该时间点设置的事件的排列，每个事件中设定的目标离子种类的数量以及其他条件因子来计算每个事件的停留时间 。 计算结果显示在列表表中的停留时间计算结果显示字段中。 驻留时间的最大和最小值显示在最大/最小的停留时间显示字段中。 分析操作员检查该显示并改变循环时间的目标值和/或事件的测量时间，以便达到适当的停留时间。