公开(公告)号：US20150083223A1

公开(公告)日：2015-03-26

申请号：US14036189

申请日：2013-09-25

Applicant: Tohoku University ,  Showa Denko K.K.

Inventor： Tienan JIN ,  Weili Si ,  Yoshinori Yamamoto ,  Takeshi Igarashi

IPC: H01L51/00

CPC classification number: H01L51/0047 ,  C07C229/46 ,  C07C2604/00 ,  C07D217/04 ,  C07D295/096 ,  C07D295/155 ,  Y02E10/549 ,  Y02P70/521

Abstract: A fullerene derivative represented by the following formula (1): wherein “FLN” represents a fullerene core, R1 represents an optionally substituted C1-C24 alkyl group or an optionally substituted C7-C24 aralkyl group, R2 and R3 independently represent a hydrogen atom or an optionally substituted C1-C24 hydrocarbon group but excluding a case where both of R2 and R3 are hydrogen atoms, and R2 and R3 may combine together to form a ring.

Abstract translation: 由下式（1）表示的富勒烯衍生物：其中“FLN”表示富勒烯核，R1表示任选取代的C 1 -C 24烷基或任选取代的C 7〜C 24芳烷基，R 2和R 3分别表示氢原子或 任选取代的C 1 -C 24烃基，但不包括R 2和R 3均为氢原子的情况，并且R 2和R 3可以结合在一起形成环。

公开(公告)号：US09246104B2

公开(公告)日：2016-01-26

申请号：US14036189

申请日：2013-09-25

Applicant: SHOWA DENKO K.K. ,  Tohoku University

Inventor： Tienan Jin ,  Weili Si ,  Yoshinori Yamamoto ,  Takeshi Igarashi

IPC: H01L51/00

CPC classification number: H01L51/0047 ,  C07C229/46 ,  C07C2604/00 ,  C07D217/04 ,  C07D295/096 ,  C07D295/155 ,  Y02E10/549 ,  Y02P70/521

Abstract: A fullerene derivative represented by the following formula (1): wherein “FLN” represents a fullerene core, R1 represents an optionally substituted C1-C24 alkyl group or an optionally substituted C7-C24 aralkyl group, R2 and R3 independently represent a hydrogen atom or an optionally substituted C1-C24 hydrocarbon group but excluding a case where both of R2 and R3 are hydrogen atoms, and R2 and R3 may combine together to form a ring.

Abstract translation: 由下式（1）表示的富勒烯衍生物：其中“FLN”表示富勒烯核，R1表示任选取代的C 1 -C 24烷基或任选取代的C 7〜C 24芳烷基，R 2和R 3分别表示氢原子或 任选取代的C 1 -C 24烃基，但不包括R 2和R 3均为氢原子的情况，并且R 2和R 3可以结合在一起形成环。

公开(公告)号：US20200095209A1

公开(公告)日：2020-03-26

申请号：US16680570

申请日：2019-11-12

Applicant: Showa Denko K.K.

Inventor： Tienan Jin ,  Weili Si ,  Yoshinori Yamamoto ,  Takeshi Igarashi

IPC: C07D241/38 ,  C01B32/154 ,  C07C67/343 ,  C07C69/76 ,  C07C41/30 ,  C07C43/21 ,  C07D333/78 ,  C07C1/26 ,  C07C2/86 ,  C07D241/36 ,  C07C13/64 ,  C07C17/266 ,  C07C17/32 ,  C07C25/22 ,  C07D241/42 ,  A61K31/5377 ,  A61K31/55

Abstract: This method for producing a fullerene derivative is a method for producing a fullerene derivative having a partial structure shown by formula (1) by reacting a predetermined halogenated compound and two carbon atoms adjacent to each other for forming a fullerene skeleton in a mixed solvent of an aromatic solvent and an aprotic polar solvent having a C═O or S═O bond in the presence of at least one metal selected from the group comprising manganese, iron, and zinc; (in formula (1), C* are each carbon atoms adjacent to each other for forming a fullerene skeleton, A is a linking group having 1-4 carbon atoms for forming a ring structure with two C*, in which a portion thereof may be a substituted or condensed group).

公开(公告)号：US11603627B2

公开(公告)日：2023-03-14

申请号：US16757861

申请日：2018-10-17

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi Igarashi ,  Tomoyuki Takei ,  Yu Gao ,  Masumi Kuritani

IPC: D06M11/74 ,  D06M101/40

Abstract: By sequentially performing: a step (I) of dissolving fullerene C60 in a polyalkylene glycol to prepare a fullerene solution; a step (II) of immersing a material carbon fiber in the fullerene solution; and a step (III) of extracting the carbon fiber from the fullerene solution, washing the extracted carbon fiber with water, and drying the carbon fiber washed with water, a carbon fiber on which fullerene C60 adsorbs is obtained.

公开(公告)号：US11585043B2

公开(公告)日：2023-02-21

申请号：US16756250

申请日：2018-10-17

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi Igarashi ,  Tomoyuki Takei ,  Yu Gao ,  Masumi Kuritani

IPC: D06M11/74 ,  C01B32/05 ,  C08J5/06 ,  D06M23/10 ,  C01B32/152 ,  D06Q1/10 ,  D06M10/00 ,  C08K3/04 ,  D06M101/40

Abstract: By sequentially performing: a step (I) of dissolving fullerene C70 in an organic solvent to prepare a fullerene solution; a step (II) of immersing a material carbon fiber in the fullerene solution; and a step (III) of extracting the carbon fiber from the fullerene solution and drying the extracted carbon fiber, a carbon fiber on which fullerene C70 adsorbs is obtained.

公开(公告)号：US11512424B2

公开(公告)日：2022-11-29

申请号：US16757863

申请日：2018-10-17

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi Igarashi ,  Tomoyuki Takei ,  Yu Gao ,  Masumi Kuritani

IPC: D06M11/74 ,  C01B32/05 ,  C08J5/06 ,  D06M101/40

Abstract: A carbon fiber is obtained by sequentially performing: a step (I) of dissolving a fullerene mixture including fullerenes C60 and C70 in an organic solvent to prepare a fullerene solution; a step (II) of immersing a material carbon fiber in the fullerene solution; and a step (III) of extracting the carbon fiber from the fullerene solution and drying the extracted carbon fiber.

公开(公告)号：US11136298B2

公开(公告)日：2021-10-05

申请号：US16680570

申请日：2019-11-12

Applicant: SHOWA DENKO K.K. ,  MITSUBISHI CORPORATION

Inventor： Tienan Jin ,  Weili Si ,  Yoshinori Yamamoto ,  Takeshi Igarashi

IPC: C07C22/04 ,  C07D241/38 ,  C01B32/154 ,  C07C67/343 ,  C07C69/76 ,  C07C41/30 ,  C07C43/21 ,  C07D333/78 ,  C07C1/26 ,  C07C2/86 ,  C07D241/36 ,  C07C13/64 ,  C07C17/266 ,  C07C17/32 ,  C07C25/22 ,  C07D241/42 ,  A61K31/5377 ,  A61K31/55 ,  C07B61/00

Abstract: This method for producing a fullerene derivative is a method for producing a fullerene derivative having a partial structure shown by formula (1) by reacting a predetermined halogenated compound and two carbon atoms adjacent to each other for forming a fullerene skeleton in a mixed solvent of an aromatic solvent and an aprotic polar solvent having a C═O or S═O bond in the presence of at least one metal selected from the group comprising manganese, iron, and zinc; (in formula (1), C* are each carbon atoms adjacent to each other for forming a fullerene skeleton, A is a linking group having 1-4 carbon atoms for forming a ring structure with two C*, in which a portion thereof may be a substituted or condensed group).

公开(公告)号：US10526293B2

公开(公告)日：2020-01-07

申请号：US15509080

申请日：2015-09-04

Applicant: SHOWA DENKO K.K.

Inventor： Tienan Jin ,  Weili Si ,  Yoshinori Yamamoto ,  Takeshi Igarashi

IPC: C01B32/154 ,  C07D241/38 ,  C07C67/343 ,  C07C69/76 ,  C07C41/30 ,  C07C43/21 ,  C07D333/78 ,  C07C1/26 ,  C07C2/86 ,  C07D241/36 ,  C07C13/64 ,  C07C17/266 ,  C07C17/32 ,  C07C25/22 ,  A61K31/5377 ,  A61K31/55 ,  C07D241/42 ,  C07B61/00

Abstract: This method for producing a fullerene derivative is a method for producing a fullerene derivative having a partial structure shown by formula (1) by reacting a predetermined halogenated compound and two carbon atoms adjacent to each other for forming a fullerene skeleton in a mixed solvent of an aromatic solvent and an aprotic polar solvent having a C═O or S═O bond in the presence of at least one metal selected from the group comprising manganese, iron, and zinc; (in formula (1), C* are each carbon atoms adjacent to each other for forming a fullerene skeleton, A is a linking group having 1-4 carbon atoms for forming a ring structure with two C*, in which a portion thereof may be a substituted or condensed group).

公开(公告)号：US10343972B2

公开(公告)日：2019-07-09

申请号：US15116672

申请日：2015-02-20

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi Igarashi ,  Kentaro Watanabe

IPC: C07C69/65 ,  C07C69/753 ,  C07C69/76 ,  C10M105/54 ,  C10M107/38 ,  C07C69/88

Abstract: A fullerene derivative of the present invention has a fullerene skeleton and a plurality of perfluoropolyether chains in a molecule, wherein the perfluoropolyether chains are bonded to the fullerene skeleton via methano groups, and a lubricant and fluororesin composition of the present invention contain the derivative.

公开(公告)号：US10336764B2

公开(公告)日：2019-07-02

申请号：US15828987

申请日：2017-12-01

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi Igarashi ,  Yasuyuki Ueda ,  Kentaro Watanabe

IPC: C07D487/22 ,  C07D487/18 ,  C07D487/08 ,  C07D209/70 ,  C10M105/70 ,  C10M105/54 ,  C10M103/02 ,  C10M105/00

Abstract: A fullerene derivative, used as a lubricant, includes, in a molecule: a fullerene backbone; and n pyrrolidine rings each being condensed to the fullerene backbone, each of the pyrrolidine rings including one aryl group including a group including m perfluoropolyether chains, “m” being an integer from 2 to 5 and “n” being an integer from 1 to 5.