公开(公告)号：US20230048457A1

公开(公告)日：2023-02-16

申请号：US17789006

申请日：2020-12-24

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Douglas Henry Lenz ,  Lawrence D'Souza ,  Lohith Kenchaiah ,  Salkod Parameshwar Mallika ,  Bedour Al-Sabban

IPC: B01J23/32 ,  B01J21/10 ,  B01J27/232 ,  B01J35/10 ,  B01J37/08

Abstract: A catalyst precursor composition for forming a phenol alkylation catalyst, the composition comprising: 70 to 98 weight percent of abase oxide comprising: magnesium oxide with a Brunauer-Emmett-Teller surface area from 75 meter2/gram to 220 meter2/gram, preferably from 75 meter2/gram to 140 meter2/gram, more preferably from 90 meter2/gram to 130 meter2/gram; or magnesium carbonate with a Brunauer-Emmett-Teller surface area of from 100 meter2/gram to 220 meter2/gram, preferably from 120 meter2/gram to 200 meter2/gram; or a combination thereof; at least one metal promoter precursor comprising an iron precursor, a manganese, a vanadium precursor, or a copper precursor; and a pore former, a lubricant, a coke inhibitor; and optionally, a strength additive; and optionally a binder, and a method of alkylating phenol using a catalyst derived from the catalyst precursor.

公开(公告)号：US20230174738A1

公开(公告)日：2023-06-08

申请号：US17924487

申请日：2021-05-11

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Lohith Kenchaiah ,  Peter Vollenberg ,  Kaushal Gandhi ,  Ranjith CHOORIKKAT ,  Vinod KN

IPC: C08J11/24 ,  C08L67/02 ,  C08G63/183 ,  C08G63/83 ,  C08G63/84 ,  C08G63/19 ,  C08G63/199

CPC classification number: C08J11/24 ,  C08L67/02 ,  C08G63/183 ,  C08G63/83 ,  C08G63/84 ,  C08G63/19 ,  C08G63/199 ,  C08J2367/02 ,  C08L2207/20

Abstract: A method includes depolymerizing post-consumer or post-industrial recycled polyethylene terephthalate (rPET) to form bis(2-hydroxyethyl) terephthalate (BHET), and reacting at least a portion of the BHET with a catalyst to form an alcohol. The alcohol includes cyclohexanedimethanol (CHDM) or 1,4-phenylenedimethanol (PDM). Further steps of the method include polymerizing the alcohol in the presence of additional BHET to form a polyester. The polyester may include poly(cyclohexylenedimethylene terephthalate (PCT), polyethylene terephthalate glycol (PETG) copolyester, polycyclohexylene dimethylene terephthalate glycol (PCTG) copolyester, polycyclohexylene dimethylene terephthalate acid (PCTA), or a monomer having repeating units with the structure (I), wherein n is an integer having a value of at least 20.

公开(公告)号：US20230183472A1

公开(公告)日：2023-06-15

申请号：US17924725

申请日：2021-05-12

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Peter Vollenberg ,  Kaushal Gandhi ,  Lohith Kenchaiah ,  Gaurav Mediratta ,  Ranjan DASH

IPC: C08L67/02 ,  C08K3/22 ,  C08J11/24

CPC classification number: C08L67/02 ,  C08K3/22 ,  C08J11/24 ,  C08L2207/20 ,  C08L2205/02 ,  C08K2003/2241 ,  C08J2367/02

Abstract: Thermoplastic compositions include from about 15 wt % to about 99 wt % of a polybutylene terephthalate (PBT) component; and from 0.01 wt % to about 85 wt % of at least one additional component, wherein: the PBT component comprises PBT derived from a post-consumer or post-industrial recycled (PCR) polyethylene terephthalate (PET) depolymerized to a high purity purified terephthalic acid (PTA) monomer and the thermoplastic composition exhibits an L* color value of at least about 74.