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公开(公告)号：US20140364558A1
公开(公告)日：2014-12-11
申请号：US14366959
申请日：2012-12-18
申请人： SOLVAY SA , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , UNIVERSITE PIERRE ET MARIE CURIE (PARIS 6) , UNIVERSITE CLAUDE BERNARD LYON 1
发明人： Jérme Vinas , Emilie Velasquez , Pierre-Emmanuel Dufils , Jutta Rieger , Francois Stoffelbach , Muriel Lansalot , Franck D'Agosto , Bernadette Charleux , Yves Vanderveken
IPC分类号： C08F214/08 , C09D127/22 , C08J5/18 , C08G81/02
CPC分类号： C08F214/08 , C08G81/021 , C08J5/18 , C08J2327/22 , C09D127/22
摘要： Process for the preparation of a vinylidene chloride polymer comprising polymerizing vinylidene chloride and optionally at least one ethylenically unsaturated monomer copolymerizable therewith under the control of a RAFT agent of formula (II).
摘要翻译： 制备偏二氯乙烯聚合物的方法，包括在式（II）的RAFT试剂的控制下聚合偏二氯乙烯和任选的至少一种可与其共聚的烯属不饱和单体。
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公开(公告)号：US20220332878A1
公开(公告)日：2022-10-20
申请号：US17632315
申请日：2020-07-27
申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , ECOLE SUPERIEURE DE CHIMIE PHYSIQUE ELECTRONIQUE DE LYON , UNIVERSITE CLAUDE BERNARD LYON 1
发明人： Emma Moreso , Julien Thuilliez , François Jean-Baptiste-Dit-Dominique , Christophe Boisson , Franck D'Agosto , Nicolas Baulu , Damien Montarnal
IPC分类号： C08F297/08
摘要： A diblock polymer composed of a first block and a second block is provided. The first block is a statistical copolymer comprising units of a 1,3-diene and more than 50 mol % of ethylene units. The second block is a polyethylene with a melting point above 90° C. and a number-average molar mass greater than or equal to 2000 g/mol and less than or equal to 10 000 g/mol. Such a diblock polymer has improved rheology compared to a statistical copolymer of the same microstructure and of the same macrostructure as the first block of the diblock polymer.
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公开(公告)号：US20150038647A1
公开(公告)日：2015-02-05
申请号：US14383404
申请日：2012-09-27
申请人： UNIVERSITE CLAUDE BERNARD LYON I , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , CPE LYON FORMATION CONTINUE ET RECHERCHE
发明人： Christophe Boisson , Franck D'Agosto , Ian German
CPC分类号： C08F8/42 , C07F3/02 , C07F3/06 , C07F5/062 , C08F2/38 , C08F8/00 , C08F8/04 , C08F8/22 , C08F8/30 , C08F8/34 , C08F110/02 , C08F2810/40 , C08F8/26
摘要： Telechelic polyolefin of formula(I) and its derivatives: CH2═CH—(CH2)p-A-Z (I) wherein: A represents a (co)polymer comprising at least 95 mol % of (CH2—CH2) units; Z is selected from the group comprising halogens, thiols and their derivatives, azides, amines, alcohols, the carboxylic acid function, isocyanates, silanes, phosphorous derivatives, dithioesters, dithiocarbamates, dithiocarbonates, trithiocarbonates, alkoxyamines, the vinyl function, dienes, and the group —A—(CH2)p-CH═CH2; p is a whole number between 1 and 20, most advantageously between 6 and 9.
摘要翻译： 式（I）的远电子聚烯烃及其衍生物：CH 2 = CH-（CH 2）p -A-Z（I）其中：A表示包含至少95mol％的（CH 2 -CH 2）单元的（共）聚合物; Z选自卤素，硫醇及其衍生物，叠氮化物，胺，醇，羧酸官能团，异氰酸酯，硅烷，磷衍生物，二硫代酯，二硫代氨基甲酸酯，二硫代碳酸酯，三硫代碳酸酯，烷氧基胺，乙烯基官能团，二烯类和 基团-A-（CH 2）p-CH = CH 2; p是1到20之间的整数，最有利地在6和9之间。
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4.发明申请公开(公告)号：US20170362354A1
公开(公告)日：2017-12-21
申请号：US15534668
申请日：2015-12-11
申请人： Universite Claude Bernard Lyon I , Centre National de la Recherche Scientifique , CPE Lyon Formation Continue ET Recherche
CPC分类号： C08F10/02 , C08F2/40 , C08F4/52 , C08F2500/02 , C08F110/02 , C08F2/38
摘要： The invention herein pertains to a telechelic polyolefin of formula (III) or (IV) and to a process for its preparation, Z-A-(CH2)p—B′ (III) Z-A-(CH2)p—B (IV) A being a polymer chain obtained by homopolymerization of ethylene or by copolymerization of ethylene and an alpha-monoolefin; B′ being selected from the group consisting of N(SiMe3)2; N(SiMe2CH2CH2SiMe2); para-C6H4(NMe2); para-C6H4(OMe); C6H4(N(SiMe3)2); ortho-CH2—C6H4NMe2; ortho-CH2—C6H4OMe; C6F5; C3F7; C6F13; CH(OCH2CH2O); B being the function B′ or a function derived from B′; p being an integer from 0 to 50, advantageously from 0 to 11; Z being a function selected from the group consisting of halogens; thiols; thiol derivatives; azides; amines; alcohols; carboxylic acid function; isocyanates; silanes; phosphorus derivatives; dithioesters; dithiocarbamates; dithiocarbonates; trithiocarbonates; alkoxyamines; vinyl function; dienes; and the group -A-(CH2)p—B′.
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公开(公告)号：US09598510B2
公开(公告)日：2017-03-21
申请号：US14383404
申请日：2012-09-27
申请人： UNIVERSITE CLAUDE BERNARD LYON I , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , CPE LYON FORMATION CONTINUE ET RECHERCHE
发明人： Christophe Boisson , Franck D'Agosto , Ian German
IPC分类号： C07F3/02 , C08F8/22 , C08F8/34 , C08F8/42 , C07F3/06 , C07F5/06 , C08F110/02 , C08F2/38 , C08F8/00 , C08F8/04 , C08F8/30
CPC分类号： C08F8/42 , C07F3/02 , C07F3/06 , C07F5/062 , C08F2/38 , C08F8/00 , C08F8/04 , C08F8/22 , C08F8/30 , C08F8/34 , C08F110/02 , C08F2810/40 , C08F8/26
摘要： Telechelic polyolefin of formula(I) and its derivatives: CH2═CH—(CH2)p-A-Z (I) wherein: A represents a (co)polymer comprising at least 95 mol % of (CH2—CH2) units; Z is selected from the group comprising halogens, thiols and their derivatives, azides, amines, alcohols, the carboxylic acid function, isocyanates, silanes, phosphorous derivatives, dithioesters, dithiocarbamates, dithiocarbonates, trithiocarbonates, alkoxyamines, the vinyl function, dienes, and the group -A-(CH2)p—CH═CH2; p is a whole number between 1 and 20, most advantageously between 6 and 9.
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公开(公告)号：US10266553B2
公开(公告)日：2019-04-23
申请号：US15528688
申请日：2015-12-11
申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , MICHELIN RECHERCHE ET TECHNIQUE, S.A. , UNIVERSITE CLAUDE BERNARD LYON 1 , CENTRE NATIONAL DE LA RECHERCE SCIENTIFIQUE , CPE LYON FORMATION CONTINUE ET RECHERCHE
摘要： A compound and the use thereof to prepare a functional or telechelic polyolefin is provided. The compound has the following formula (II): Y((CH2)p—B′)m (II), wherein m=2 or 3; Y being an alkaline earth metal or zinc when m=2, Y being aluminum when m=3; B′ being selected from the group comprising N(SiMe3)2; N(SiMe2CH2CH2SiMe2); C6F5; C3F7; C6F13; para-C6H4—NMe2; para-C6H4—O-Me; para-C6H4—N(SiMe3)2; and CH(OCH2CH2O); and p being an integer from 0 to 50.
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