公开(公告)号：US20220024867A1

公开(公告)日：2022-01-27

申请号：US17311033

申请日：2019-12-19

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Stefana MUSIO ,  Ivan Diego WLASSICS ,  Serena CARELLA ,  Marco AVATANEO

IPC: C07C407/00 ,  C08F4/34 ,  C08F110/02 ,  C08F114/18

Abstract: A process for the preparation of perhaloacyl peroxides from perhaloacyl halides which is performed in the presence of a hydrofluoroether as the solvent.

公开(公告)号：US20190194455A1

公开(公告)日：2019-06-27

申请号：US16329199

申请日：2017-08-09

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Ritu AHUJA ,  Chinmay NARDELE ,  Claudio Adolfo Pietro TONELLI ,  Ivan Diego WLASSICS

IPC: C08L77/02 ,  C08L77/06 ,  C08K7/14 ,  C08G69/40 ,  C08G69/42

CPC classification number: C08L77/02 ,  B29C45/0001 ,  B29K2077/00 ,  C08G69/40 ,  C08G69/42 ,  C08K7/14 ,  C08L77/06 ,  C08L2203/02 ,  C08L2203/20

Abstract: Thermoplastic polyamides [polyamides (PA)] comprising (per)fluoropolyether and polyorganosiloxane recurring units are herein disclosed. Thanks to the use of appropriate amounts and ratios of (per)fluoropolyether and polyorganosiloxane monomers in the polymerization, polyamides (PA) are endowed with high hydro- and oleo-repellence, favourable mechanical properties and resistance to stain, which makes them suitable for a variety applications, including the manufacture and/or surface treatment of medical articles, fuel line hoses, miniature circuit breakers, electrical switches, smart devices, devices for printers, and food packagings.

公开(公告)号：US20200317525A1

公开(公告)日：2020-10-08

申请号：US16755080

申请日：2018-10-09

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Ivan Diego WLASSICS ,  Stefano MILLEFANTI ,  Davide VICINO

IPC: C01B32/194 ,  C01B32/198 ,  C08F292/00

Abstract: The present invention relates to novel fluoro-modified graphene compounds and to the processes for the preparation thereof. The invention also provides fluoro-modified graphene oxide that can be used as intermediate in the preparation of said fluoro-modified graphene compounds.

公开(公告)号：US20200291147A1

公开(公告)日：2020-09-17

申请号：US16084120

申请日：2017-02-28

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Stefano BOSSOLO ,  Ivan Diego WLASSICS ,  Liubov CHERNYSHEVA ,  Davide VICINO

IPC: C08F114/26 ,  C08F114/22

Abstract: The invention pertains to a polyunsaturated compound having formula (I) [compound (DAIC-PFPE)]: TA-O—Rf-TA′ wherein: —Rf is (per)fluoropolyoxyalkylene chain [chain (Rf)] comprising recurring units having at least one catenary ether bond and Sat least one fluorocarbon moiety; TA and TA′, equal to or different from each other, are selected from the group consisting of: (i) C1-C24 (hydro)(fluoro)carbon groups, possibly comprising one or more than one of H, O, and Cl; and (ii) (hydro)(fluoro)carbon group comprising at least one diallylisocyanurate group of formula (A) wherein each of R1, R2, R3, R4, R5, and R6 is, independently, a hydrogen atom or a C1-C3 hydrocarbon group, preferably a hydrogen atom (group TDAIC), with the provisio that at least one of TA and TA′ is a group TDAIC, to a process for its manufacture and its use for curing fluoroelastomers, to fluoroelastomer compositions comprising the same, as well as to a process for producing fluororubber mouldings therefrom.

公开(公告)号：US20190100619A1

公开(公告)日：2019-04-04

申请号：US15743129

申请日：2016-07-07

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Claudio Adolfo Pietro TONELLI ,  Ivan Diego WLASSICS ,  Giuseppe MARCHIONNI

IPC: C08G65/333 ,  C08G65/00 ,  C08G65/325

CPC classification number: C08G65/33306 ,  C08G65/007 ,  C08G65/3255 ,  C08G65/3346 ,  C08G2650/48 ,  C08G2650/50

Abstract: A process for the manufacture of a (per)fluoropolyether amine comprising reacting a sulfonic ester of a (per)fluoropolyether alcohol with an excess of ammonia or organic amine at selected temperature is herein disclosed. The process allows obtaining (per)fluoropolyether amines, in particular primary, secondary and tertiary (per)fluoropolyether amines with high yields and selectivity and can be conveniently applied on an industrial scale.

公开(公告)号：US20180319982A1

公开(公告)日：2018-11-08

申请号：US15773380

申请日：2016-10-28

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Claudio Adolfo Pietro TONELLI ,  Ritu AHUJA ,  Giuseppe MARCHIONNI ,  Ivan Diego WLASSICS ,  Sibdas SINGHAMAHAPATRA

IPC: C08L77/06 ,  C08G69/42 ,  C08G81/00 ,  C08G65/22

CPC classification number: C08L77/06 ,  C08G65/223 ,  C08G69/40 ,  C08G69/42 ,  C08G81/00

Abstract: A method for providing a fluorinated polyamide is herein provided. The method envisages the copolymerization of a (per)fluoropolyether comprising amino or acid functional groups with a mixture of a hydrogenated dicarboxylic acid and a diamine and/or an aminoacid or lactam in the presence of a hydrogenated monocarboxylic acid and/or a hydrogenated monoamine. By appropriate selection of the functionality of the reaction mixture, fluorinated polyamides having an average molecular weight (Mw) lower than 16,000 and a content of PFPE segments ranging from 5% to 50% wt are obtained. These polyamides can be advantageously used as additives for other polyamides, in particular for non-fluorinated polyamides to provide blends that can be formed into shaped articles.

公开(公告)号：US20220017736A1

公开(公告)日：2022-01-20

申请号：US17311023

申请日：2019-12-16

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Aldo SANGUINETI ,  Marco MIRENDA ,  Ivan Diego WLASSICS

IPC: C08L27/18 ,  C08L81/02 ,  C08G65/26 ,  C08L27/10 ,  C08K3/22 ,  C08K5/00 ,  C08K5/03 ,  C08K5/14

Abstract: The present invention relates to a curable composition comprising: at least one polymer comprising cure sites [polymer (E)], at least one thermoplastic polymer [thermoplastic (P)] different from said polymer (E) and at least one 1,5 enediyne curing agent [agent (C)], and to a blend obtained by dynamic vulcanization of said composition.

公开(公告)号：US20200165392A1

公开(公告)日：2020-05-28

申请号：US16608179

申请日：2018-04-19

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Ritu AHUJA ,  Trupti NALAWADE ,  Emanuele DI NICOLO' ,  Giovanni FONTANA ,  Ivan Diego WLASSICS ,  Giuseppe MARCHIONNI ,  Claudio Adolfo Pietro TONELLI

IPC: C08G75/23 ,  C08G65/40 ,  C08G65/334 ,  B01D71/80 ,  B01D61/24 ,  B01D69/04 ,  B01D69/08

Abstract: A fluorinated aromatic sulfone polymer [polymer (F-PS)] comprising: recurring units [units (A)] derived from at least one dihalo-diaryl sulfone [monomer (A)]; recurring units [units (B)] derived from at least one aromatic diol [monomer (B)]; at least one unit [units (PFPE)] derived from at least one fully or partially fluorinated polyether alcohol (PFPE alcohol), said polymer (F-PS) having a fluorine content ranging from 0.1% to 10% wt, is herein disclosed. Films and membranes obtained from (F-PS) are also disclosed, as well as their use in filtration methods.

公开(公告)号：US20190062496A1

公开(公告)日：2019-02-28

申请号：US16079090

申请日：2017-02-20

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Claudio Adolfo Pietro TONELLI ,  Ivan Diego WLASSICS ,  Stefano MILLEFANTI ,  Letanzio BRAGANTE ,  Solange BARBIERI ,  Giuseppe MARCHIONNI

IPC: C08G65/00 ,  C08G65/334

Abstract: A method for the manufacture of fluorinated polymers and polymers obtainable therefrom are herein disclosed. The method envisages the reaction of a) first reagent [reagent (R1)] which is an alcohol selected from a (per)fluoropolyether (PFPE) alcohol a fluoroalkylene diol and a mixture thereof; b) a second reagent [reagent (R2)] which is a sulfonic ester of a PFPE, a sulfonic diester of a fluoroalkylene diol or a mixture thereof and, optionally, c) a third reagent which is a mono-functional (per)haloalkyl alcohol or a sulfonic ester thereof in the presence of an organic or inorganic base. At least reagent (R1) is a PFPE alcohol (A) or at least reagent (R2) is a PFPE sulfonic ester (B) and the overall equivalents of alcohols are the same as the overall equivalents of sulfonic esters. The method allows to obtain in a convenient way non-functional polymers comprising at least a PFPE segment and having high molecular weight.