摘要:
The invention pertains to a fluoroelastomer composition including at least a nitrile-containing (per)fluoropolyether compound and at least one bis-amino(thio)phenol compound of formula (I), wherein: A is —SO2—, —O—, —C(O)— or divalent hydrocarbon groups of 1 to 10 carbon atoms, E is independently oxygen or sulphur and —NH2 groups are in ortho with respect to EH groups; to a process for manufacturing a (per)fluoropolyether-based thermoset and to a (per)fluoropolyether-based thermoset obtained therefrom.
摘要:
The present invention relates to a method for manufacturing semiconductor devices, including a step wherein a semi-conductor device exchanges heat with a heat transfer fluid. The heat transfer fluid comprises one or more chemical compounds having the general formula: Ph(ORf)x (I) wherein Ph is an aromatic ring linked to one or more ether groups —ORf where each —Rf: — is a monovalent fluorinated alkyl group comprising at least one C—F bond, — has a carbon chain, preferably a C1-C10 carbon chain, which can be linear or can comprise branches and/or cycles, and, optionally, can comprise in chain heteroatoms selected from O, N or S, and wherein, when X>1, the —Rf groups on the same molecule can be equal to or different from each other.
摘要:
A method for the manufacture of fluorinated polymers and polymers obtainable therefrom are herein disclosed. The method envisages the reaction of a) first reagent [reagent (R1)] which is an alcohol selected from a (per)fluoropolyether (PFPE) alcohol a fluoroalkylene diol and a mixture thereof; b) a second reagent [reagent (R2)] which is a sulfonic ester of a PFPE, a sulfonic diester of a fluoroalkylene diol or a mixture thereof and, optionally, c) a third reagent which is a mono-functional (per)haloalkyl alcohol or a sulfonic ester thereof in the presence of an organic or inorganic base. At least reagent (R1) is a PFPE alcohol (A) or at least reagent (R2) is a PFPE sulfonic ester (B) and the overall equivalents of alcohols are the same as the overall equivalents of sulfonic esters. The method allows to obtain in a convenient way non-functional polymers comprising at least a PFPE segment and having high molecular weight.
摘要:
The present invention relates to a method for exchanging heat with an object said method comprising using a heat transfer fluid wherein said heat transfer fluid comprises one or more chemical compounds having the general formula: (I) wherein: R1, R2, R3, R4 can be the same or different, linear or branched, partially fluorinated alkyl groups having a C1-C6 carbon chain.
摘要:
The present invention relates to a method for exchanging heat with a battery comprising the use of a heat transfer fluid, which comprises one or more chemical compounds having the general formula: Ph(ORf)x (I) wherein Ph is an aromatic ring linked to one or more ether groups —ORf where each —Rf: —is a monovalent fluorinated alkyl group comprising at least one C—F bond, —has a carbon chain, preferably a C1-C10 carbon chain, which can be linear or can comprise branches and/or cycles, and, optionally, can comprise in chain heteroatoms selected from O, N or S, and wherein, when X>1, the —Rf groups on the same molecule can be equal to or different from each other.
摘要:
Disclosed are mixtures containing: mono- and bi-functional polymers [polymers (P-A) and (P-B)] comprising a plurality of (per)fluoropolyether segments [segments (SRF)] joined together by hydrogenated (poly)ether segments [segments (SH)], said polymers having two ends, wherein one or both ends comprises a hydroxy or a leaving group; a non-functional polymer comprising a plurality of (per)fluoropolyether segments (S) joined together by hydrogenated (poly)ether segments (SB), with the proviso that the hydrogenated (poly)ether segments (SRF) are not segments of formula —CH2OCH2OCH2—. Disclosed are also monofunctional polymers (P-A) that can be isolated from such mixtures. Methods for the obtainment of the mixtures and for separating the polymers therein contained are also provided, as well as methods of using the mixtures or each polymer therein contained as intermediates or building blocks for the synthesis of other polymers or as ingredients of compositions.
摘要:
The invention pertains to a multi-step process for making polyfunctional aromatic compounds comprising two phenyl rings bearing reactive groups susceptible of polycondensation reaction to provide polycondensed polymers, said method using economic raw materials, and possessing high selectivity and overall yield.
摘要:
A polymer [polymer (P)] comprising a plurality of (per)fluoropolyether (PFPE) segments [segments (SRF)] joined together by hydrogenated (poly)ether segments [segments (SH)], said polymers (P) having two end groups [groups (E)], each group (E) comprising a hydroxy or a leaving group, with the proviso that the hydrogenated (polytether segment (SH) is not a segment of formula —CH2OCH2 2 OCH2— is herein disclosed. Disclosed is also a method for the manufacture of polymer (P) and a polymer obtainable by full or partial fluorination of polymer (P). Polymer (P) and polymers obtainable therefrom by full or partial fluorination can be conveniently used in the manufacture of lubricant compositions or of compositions for imparting hydro-/oleo-repellence to substrates. Said polymers can also be used as intermediates for the manufacture of other polymers or block copolymers.
摘要:
The invention relates to a process for the manufacture of a-iodoperfluoroalkanes and α,ω-diiodoperfluoroalkanes of general formula: (1) A(C2F4)n1, wherein: A is selected from F, CF3 and I and n is an integer equal to or higher than 1, with the proviso that, when A is F, n is an integer higher than 1 said process comprising heating a mixture [mixture (M1)] containing: —a compound selected from I2, CF3I, CF3CF2I and C2F4I2; —TFE; —and CO2 at definite temperatures and concentrations of CO2.
摘要翻译:本发明涉及一种制备α-碘全氟烷烃和α,ω-二碘全氟烷烃的方法,通式为:(1)A(C2F4)n1,其中:A选自F,CF3和I,n为等于 或高于1,条件是当A为F时,n为高于1的整数,所述方法包括加热含有:选自I 2,CF 3 I,CF 3 CF 2 I和C 2 F 4 I 2的化合物的混合物[混合物(M1)]; -TFE; 和二氧化碳在确定的温度和二氧化碳的浓度。