公开(公告)号：US3912786A

公开(公告)日：1975-10-14

申请号：US44494974

申请日：1974-02-22

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  BOGDANOVIC BORISLAV ,  NUSSEL HANS-GEORG

IPC: B01J31/14 ,  B01J31/22 ,  B01J31/26 ,  C07C5/31 ,  C07C13/00

CPC classification number: B01J31/2226 ,  B01J31/143 ,  B01J31/2234 ,  B01J31/2291 ,  B01J31/2295 ,  B01J31/26 ,  B01J2231/52 ,  B01J2531/847 ,  C07C5/31 ,  C07C13/44

Abstract: Bicyclo-(3,3,0)-octene-(2) is prepared with quantitative conversion and in high yields at substantially room temperature and high reaction rate with the use of a catalytic mixture of nickel compounds and aluminum compounds. The resulting bicyclooctene is a valuable monomer for the production of a high molecular weight polyolefin or a starting material for alicyclic dicarboxylic acids.

公开(公告)号：US3919325A

公开(公告)日：1975-11-11

申请号：US33598673

申请日：1973-02-26

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： BOGDANOVIC BORISLAV

IPC: B27L11/00 ,  B27C5/00 ,  B27L11/02 ,  C07C1/00 ,  C07C13/02 ,  C07C67/00 ,  C07C401/00 ,  C07C403/02 ,  C07F5/06 ,  C07F9/535 ,  C07F9/54 ,  C07F9/28

CPC classification number: B27L11/02 ,  C07F5/066 ,  C07F9/5352 ,  C07F9/5428

Abstract: Allylidene phosphoranes are prepared by a new process comprising reacting dialkyl aluminum alkylidene amides or bis(N-dialkyl aluminum-imino)alkanes which are obtainable from saturated aliphatic nitriles or dinitriles and dialkyl aluminum hydrides with alkylidene phosphoranes R3CH PR34. The allylidene phosphoranes are useful as intermediate products in the synthesis of 1,3-dienes which include insect attracting substances and flavoring agents, and in the synthesis of 1,5-dienes such as squalene.

Abstract translation: 通过新的方法制备烯丙基膦，其包括可从饱和脂族腈或二腈和二烷基氢化铝得到的二烷基铝亚烷基酰胺或双（N-二烷基铝 - 亚氨基）烷烃与亚烷基膦R3CH = PR34反应。 烯丙基磷烷可用作合成1,3-二烯的中间产物，其包括昆虫吸引物质和调味剂，以及合成1,5-二烯如角鲨烯。

公开(公告)号：US3511863A

公开(公告)日：1970-05-12

申请号：US3511863D

申请日：1967-08-11

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  BOGDANOVIC BORISLAV ,  BIRKENSTOCK UDO ,  PAULING HORST

IPC: C07F15/04

CPC classification number: C07F15/04

公开(公告)号：US3644558A

公开(公告)日：1972-02-22

申请号：US3644558D

申请日：1969-10-20

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  BOGDANOVIC BORISLAV

IPC: C07C5/22 ,  C07C5/24

CPC classification number: C07C5/2286 ,  C07C5/2293 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24

Abstract: PROCESS FOR ISOMERIZING OLEFINS BY SUBJECTING AN ISOMERIC MIXTURE OF AT LEAST ONE OLEFIN TO CONTACT AT LOW TEMPERATURES FOR AN EXTENDED PERIOD OF TIME WITH AN $-ALLYL NICKEL COMPOUND, A LEWIS ACID AND A PHOSPHINE.