公开(公告)号：US3929922A

公开(公告)日：1975-12-30

申请号：US46308874

申请日：1974-04-22

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  HEIMBACH PAUL

IPC: B01J31/16 ,  B01J31/18 ,  C07C13/277 ,  C07C13/32 ,  C07C13/54 ,  C07C13/605 ,  C07C45/34 ,  C07C13/00

CPC classification number: B01J31/185 ,  B01J2231/20 ,  B01J2531/847 ,  C07C13/277 ,  C07C13/32 ,  C07C13/54 ,  C07C13/605 ,  C07C45/34 ,  C07C2601/20 ,  C07C2602/32 ,  C07C2603/38 ,  C07C2603/84 ,  Y10S435/898 ,  C07C49/185

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

Abstract translation: 一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。 虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。 它们是特别好的交联剂。 这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。 不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

公开(公告)号：US3660440A

公开(公告)日：1972-05-02

申请号：US3660440D

申请日：1969-09-22

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  HEIMBACH PAUL ,  DELLIEHAUSEN CLAUS

IPC: C07C69/587 ,  C07C67/00 ,  C07C69/52

CPC classification number: C07C69/587

Abstract: THEREIS PROVIDED AS A NEW COMPOUND NONADECAPENTA1,6,9,13,18-ENE-10-METHYL CARBOXYLATE. THIS IS PREPARED BY REACTION OF METHYL METHACRYLATE WITH BUTADIENE IN THE PRESENCE OF ZERO-VALENT NICKEL OR BY REACTION OF BUTADIENE WITH UNDERCATRI-1,5,10-EE-2-METHYL CARBOXYLATE FORMED AS AN INTERMEDIATE WHICH MAY BE ISOLATED OR NOT AS DISIRED.

公开(公告)号：US3594434A

公开(公告)日：1971-07-20

申请号：US3594434D

申请日：1968-04-03

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  HEIMBACH PAUL ,  BRENNER WOLF-BERND

IPC: C07C2/44 ,  B01J31/00 ,  C07C1/00 ,  C07C2/46 ,  C07C13/06 ,  C07C67/00 ,  C07C3/10

CPC classification number: C07C13/06 ,  C07C2/465 ,  C07C2531/12 ,  C07C2531/16 ,  C07C2601/04

Abstract: A PROCESS FOR THE CATALYTIC DIMERISATION OF 1,3-DIOLEFINES IS DISCLOSED. PREFERRED DIOLEFINES ARE BUTADIENE, ISOPRENE AND PIPERYLENE. THE CATALYSTS USED ARE ONES FORMED BY MIXING A REDUCIBLE NICKEL COMPOUND AND A METAL HAVING A REDUCING ACTION WITH RESPECT TO THE REDUCIBLE NICKEL COMPOUND OR A HALOGEN-FREE ORGANOMETALLIC COMPOUND, OF WHICH METAL ALKYLS, METAL ARYLS OR METAL HYDRIDES ARE EXAMPLES, AND AN ELECTRON DONOR. THEY MAY ALSO BE FORMED BY MIXING A NICKEL COMPLEX COMPOUND WHICH CONTAINS O-VALENT NICKEL WITH AN ELECTRON DONOR. THE ELECTRON DONOR MAY BE AN ESTER OF A PHOSPHOROUS ACID OR A DIOLEFINE. THE PROCESS IS CARRIED OUT WITH INCOMPLETE CONVERSION OF THE 1,3-DIOLEFINE.

公开(公告)号：US3450732A

公开(公告)日：1969-06-17

申请号：US3450732D

申请日：1968-08-21

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  MULLER ERNST WILLI ,  KRONER MICHAEL ,  HEIMBACH PAUL ,  BREIL HEINZ

IPC: B01J31/16 ,  B01J31/22 ,  B01J31/24 ,  C07C2/40 ,  C07C2/46 ,  C07C2/52 ,  C07F9/00 ,  C07F9/02 ,  C07F9/50 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C07F17/00 ,  C07F11/00 ,  C07C3/20

CPC classification number: B01J31/2234 ,  B01J31/2291 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2/406 ,  C07C2/465 ,  C07C2/52 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2601/16 ,  C07C2601/18 ,  C07F9/005 ,  C07F9/02 ,  C07F9/5045 ,  C07F15/02 ,  C07F15/025 ,  C07F15/04 ,  C07F15/045 ,  C07F15/06 ,  C07F15/065 ,  C07F17/00 ,  C07C11/21 ,  C07C13/263 ,  C07C13/20

公开(公告)号：US3422128A

公开(公告)日：1969-01-14

申请号：US3422128D

申请日：1964-08-06

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER

IPC: C07F15/04 ,  C07F17/00 ,  C08F2/00 ,  C08F4/619 ,  C08F4/80 ,  C08F10/00 ,  C08F1/32 ,  C07F15/00

CPC classification number: C07F17/00 ,  C07F15/04 ,  C08F4/619 ,  C08F10/00

公开(公告)号：US3920762A

公开(公告)日：1975-11-18

申请号：US46308974

申请日：1974-04-22

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  HEIMBACH PAUL

IPC: C07C13/32 ,  C07C13/605 ,  C07C45/34 ,  C07C13/00

CPC classification number: C07C13/605 ,  C07C13/32 ,  C07C45/34 ,  C07C2601/20 ,  C07C2602/32 ,  C07C2603/38 ,  C07C2603/84 ,  C07C49/185

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

公开(公告)号：US3573292A

公开(公告)日：1971-03-30

申请号：US3573292D

申请日：1967-12-15

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  HEIMBACH PAUL ,  SCHOTT HERBERT

IPC: C07F9/02 ,  C07F15/00 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06

CPC classification number: C07F9/02 ,  C07F15/0066 ,  C07F15/0093 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065

Abstract: ZERO-VALENT COMPLEXES OF GROUP VIII METALS, OXYGEN AND AN ELECTRON DONOR SUCH AS, FOR EXAMPLE, A GROUP V METAL TRIVALENT COMPOUND, E.G., TRIPHENYL PHOSPHINE; PRODUCTION OF SUCH ZERO-VALENT COMPLEXES BY REACTING A ZEROVALENT COMPOUND OF A GROUP VIII METAL AND AN ELECTRON DONOR WITH MOLECULAR OXYGEN PREFERABLY AT A TEMPERATURE OF ABOUT - 100 TO ABOUT 75*C. THESE COMPLEXES CAN BE USED AS OXYGEN TRANSFER AGENTS AND FOR THE PREPARATION OF FINELY DIVIDED, HIGHLY ACTIVE METALS OF SUB-GROUP VIII OF THE PERIODIC TABLE.

公开(公告)号：US3511863A

公开(公告)日：1970-05-12

申请号：US3511863D

申请日：1967-08-11

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  BOGDANOVIC BORISLAV ,  BIRKENSTOCK UDO ,  PAULING HORST

IPC: C07F15/04

CPC classification number: C07F15/04

公开(公告)号：US3912786A

公开(公告)日：1975-10-14

申请号：US44494974

申请日：1974-02-22

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  BOGDANOVIC BORISLAV ,  NUSSEL HANS-GEORG

IPC: B01J31/14 ,  B01J31/22 ,  B01J31/26 ,  C07C5/31 ,  C07C13/00

CPC classification number: B01J31/2226 ,  B01J31/143 ,  B01J31/2234 ,  B01J31/2291 ,  B01J31/2295 ,  B01J31/26 ,  B01J2231/52 ,  B01J2531/847 ,  C07C5/31 ,  C07C13/44

Abstract: Bicyclo-(3,3,0)-octene-(2) is prepared with quantitative conversion and in high yields at substantially room temperature and high reaction rate with the use of a catalytic mixture of nickel compounds and aluminum compounds. The resulting bicyclooctene is a valuable monomer for the production of a high molecular weight polyolefin or a starting material for alicyclic dicarboxylic acids.

公开(公告)号：US3629347A

公开(公告)日：1971-12-21

申请号：US3629347D

申请日：1969-07-29

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： WILKE GUNTHER ,  HEIMBACH PAUL

IPC: C07C2/02 ,  C07C2/42 ,  C07C2/46 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C3/10

CPC classification number: C07C13/605 ,  C07C2/02 ,  C07C2/42 ,  C07C2/46 ,  C07C2/465 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2601/18 ,  C07C2601/20 ,  C07C2603/84

Abstract: PROCESS OF CYCLOCO-OLIGOMERIZATION OF A CONJUGATED DIOLEFIN, SUCH AS BUTADIENE OR A SUBSTITUTED BUTADIENE, WITH A DIFFERENT CYCLIC UNSATURATED HYDROCARBON, WHICH IS AN ACETYLENE AND/OR A NON-CONJUGATED OLEFIN, PREFERABLY A MONOOLEFIN, TO PRODUCE MULTICYCLIC PRODUCTS HAVING OLEFINIC UNSATURATION IN AT LEAST ONE OF THE RINGS. THESE PRODUCTS ARE MADE BY REACTING THE ABOVE-MENTIONED REACTANTS TOGETHER IN CONTACT WITH A CARBONYL-FREE, O-VALENT NICKEL COMPOUND CATALYST. MANY OF THE NEW PRODUCTS FORMED BY THIS PROCESS ARE DESCRIBED, CHARACTERIZED AND CLAIMED.