公开(公告)号：US3240839A

公开(公告)日：1966-03-15

申请号：US22327862

申请日：1962-09-12

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： KURT ZOSEL

IPC: C07C2/30 ,  C07C2/88

CPC classification number: C07C2/30 ,  C07C2/88 ,  C07C2531/14 ,  Y02P20/52 ,  Y10S585/925 ,  C07C11/113 ,  C07C11/10

公开(公告)号：US2930808A

公开(公告)日：1960-03-29

申请号：US64737957

申请日：1957-03-20

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： KURT ZOSEL

IPC: B01J8/20 ,  B01J8/22 ,  B01J10/00 ,  B01J19/24 ,  C01G49/16 ,  C07F3/02 ,  C07F5/06

CPC classification number: B01J8/20 ,  B01J8/22 ,  B01J10/002 ,  B01J19/242 ,  B01J2219/0011 ,  B01J2219/0015 ,  B01J2219/00166 ,  B01J2219/00186 ,  B01J2219/00777 ,  B01J2219/185 ,  B01J2219/1943 ,  C01G49/16 ,  C07F3/02 ,  C07F5/063

Abstract: A reaction between solids and liquids and/or gases is conducted in the liquid phase in a reactor A full of liquid wherein the reactor is divided by means of screening plates X with perforations of such a size that at any given speed of gas stream, gas-buffers are formed underneath the screening plates, resulting in the liquid being impeded in its path from the solid/liquid inleg g through the reactor, maintaining a uniformly distributed solid in the reaction space. An inert gas or an inert liquid may be used to provide the liquid/gas buffer in reactions in which the phase would normally be absent. A solution of iron pentacarbonyl in petroleum, free from iron particles, can be produced by circulating carbon monoxide through the reactor with finely divided iron suspended in petroleum.ALSO: Aluminium is reacted with olefins and hydrogen to produce aluminium trialkyls, the reaction being conducted in the liquid phase in a reactor (A) full of liquid wherein the reactor is divided by means of screening plates (X) having perforations of such a size that at any given speed of gas stream, gas-buffers are formed underneath the screening plates, resulting in the liquid being impeded in its path from the solid/liquid inlet (g) through the reactor and maintaining a uniformly distributed solid in the reaction space. An inert gas or an inert liquid may be used to provide the liquid/gas buffer in reactions in which the liquid phase would normally be absent. Exemplified products are aluminium tri-isohexyl, aluminium triethyl, aluminium di-ethyl hydride. In Example (4) finely divided magnesium in di-isobutyl ether is reacted with bromobenzene to yield phenyl magnesium bromide.