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    Generation of metal-carbonyl standards for the calibration of spectroscopic systems
    2.
    发明授权
    Generation of metal-carbonyl standards for the calibration of spectroscopic systems 失效
    生成用于校准光谱系统的金属 - 羰基标准品

    公开(公告)号：US06468446B1

    公开(公告)日：2002-10-22

    申请号：US09657395

    申请日：2000-09-08

    申请人： Tracey Jacksier ,  Reha Tepe ,  David N. Vassallo

    发明人： Tracey Jacksier ,  Reha Tepe ,  David N. Vassallo

    IPC分类号： C09K300

    CPC分类号： C01G49/16 ,  C01G1/04 ,  C01G53/02 ,  G01N21/278

    摘要： Methods and apparatus for preparing gaseous compositions comprising a metal carbonyl, preferably at ppm concentration, are disclosed. The methods comprise placing metal, preferably in the form of filings, of the metal carbonyl to be produced into a first test vessel at a first temperature, and then pressurizing the first test vessel with a gas comprising carbon monoxide from a carbon monoxide source vessel. The contents of the first vessel are then heated to a second temperature and at a rate sufficient to initiate metal carbonyl formation, thereby forming a gas composition comprising a metal carbonyl. The reaction is then quenched by transferring some of the gas composition comprising a metal carbonyl from the first test vessel to a second test vessel which is at a third temperature, the third temperature being lower than the second temperature. Finally, the gas composition is diluted in the second test vessel with an inert gas (preferably argon) from an inert gas source container.

    摘要翻译： 公开了用于制备包含金属羰基，优选以ppm浓度的气态组合物的方法和设备。 所述方法包括将待生产的金属羰基的金属（优选以填料形式）置于第一温度下的第一试验容器中，然后用包含一氧化碳源容器的一氧化碳的气体对第一试验容器加压。 然后将第一容器的内容物加热到第二温度并以足以引发金属羰基生成的速率，从而形成包含羰基金属的气体组合物。 然后通过将一些包含金属羰基的气体组合物从第一测试容器转移到处于第三温度，第三温度低于第二温度的第二测试容器来淬灭反应。 最后，将惰性气体（优选氩气）从惰性气体源容器中稀释到第二测试容器中。

    Collection of metal carbonyls
    7.
    发明授权
    Collection of metal carbonyls 失效
    收集金属碳

    公开(公告)号：US3688474A

    公开(公告)日：1972-09-05

    申请号：US3688474D

    申请日：1971-06-22

    申请人： INT NICKEL CO

    发明人： HEAD MICHAEL DAVID ,  THOMPSON JOHN ROBERT MICHAEL

    IPC分类号： C01G49/16 ,  C01G53/02 ,  B01D3/14 ,  C22B23/00

    CPC分类号： C01G53/02 ,  C01G49/16

    摘要： Gaseous streams of carbon monoxide containing nickel and iron carbonyls are contacted with cooled liquid iron pentacarbonyl to dissolve the carbonyls and to provide purified carbon monoxide. When the liquid iron pentacarbonyl has dissolved controlled amounts of nickel carbonyl, the solution is fractionally distilled to recover nickel carbonyl and liquid iron pentacarbonyl which can be recycled. The process can also be conducted under pressure and in conjunction with intermediate pressure carbonyl processes for recovering nickel.

    摘要翻译： 将含有一氧化碳的镍和铁羰基的气流与冷却的五羰基液体铁接触以溶解羰基并提供纯化的一氧化碳。 当液体铁五羰基溶解了可控量的羰基镍时，分馏出溶液以回收可回收的羰基镍和液态铁五羰基。 该方法也可以在压力下进行并与用于回收镍的中压羰基方法一起进行。