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    Coproduction of vinylidene alcohols and vinylidene hydrocarbons
    4.
    发明授权
    Coproduction of vinylidene alcohols and vinylidene hydrocarbons 失效
    亚乙烯基醇和亚乙烯基烃的共同生产

    公开(公告)号：US5731480A

    公开(公告)日：1998-03-24

    申请号：US552638

    申请日：1995-11-03

    申请人： Kaung-Far Lin

    发明人： Kaung-Far Lin

    IPC分类号： B01J31/14 ,  C07B61/00 ,  C07C2/30 ,  C07C2/88 ,  C07C11/02 ,  C07C29/10 ,  C07C29/54 ,  C07C31/02 ,  C07C29/04

    CPC分类号： C07C2/30 ,  C07C2/88 ,  C07C29/54 ,  C07C2531/14

    摘要： A process is described for coproducing vinylidene alcohol and vinylidene olefin. The process involves dimerizing one or more vinylolefins with an alkyl aluminum catalyst to form a first product mixture comprising at least vinylidene olefin and alkyl aluminum compound. The vinylidene olefin is then reacted with the alkyl aluminum compound under displacement conditions to form 1-olefin while concurrently removing the 1-olefin from the displacement reaction mixture to form a second product mixture comprising at least beta-branched alkyl aluminum compound. The second product mixture is treated with air or oxygen under mild oxidation conditions to form a third product mixture comprising at least beta-branched aluminum alkoxide. The beta-branched aluminum alkoxide is then hydrolyzed to form vinylidene alcohol. The process makes effective use of the alkyl aluminum catalyst both as a catalyst and as a reactant, and requires only a relatively small amount of reaction equipment.

    摘要翻译： 描述了用于共聚亚乙烯醇和亚乙烯基烯烃的方法。 该方法包括使一种或多种烯烃与烷基铝催化剂二聚，以形成至少包含亚乙烯基烯烃和烷基铝化合物的第一产物混合物。 然后将亚乙烯基烯烃与置换条件下的烷基铝化合物反应以形成1-烯烃，同时从置换反应混合物中除去1-烯烃以形成至少包含β-支链烷基铝化合物的第二产物混合物。 第二产物混合物在温和氧化条件下用空气或氧气处理以形成至少包含β-支链烷醇铝的第三产物混合物。 然后将β-支链的烷氧基铝水解形成亚乙烯基醇。 该方法有效地利用烷基铝催化剂作为催化剂和作为反应物，并且仅需要相对少量的反应设备。

    Combined process for preparing alumina and alpha-olefins
    6.
    发明授权
    Combined process for preparing alumina and alpha-olefins 失效
    用于制备氧化铝和α-烯烃的组合方法

    公开(公告)号：US4455289A

    公开(公告)日：1984-06-19

    申请号：US405973

    申请日：1982-08-06

    申请人： R. L. Poe ,  D. J. Royer

    发明人： R. L. Poe ,  D. J. Royer

    IPC分类号： C01F7/36 ,  C07C2/88 ,  C07F5/06 ,  C01F7/02 ,  C07C2/02

    CPC分类号： C07F5/069 ,  C01F7/36 ,  C07C2/88 ,  C07C2523/44 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2525/02 ,  C07C2531/22

    摘要： A combined process for preparing alumina and alpha-olefins (.alpha.-olefins) is disclosed. The process comprises:(a) reacting tri-(C.sub.2 to C.sub.24) alkylaluminum with ethylene in the presence of nickel catalyst to form triethylaluminum and C.sub.2 to C.sub.24 .alpha.-olefins,(b) adding aluminum tri-(C.sub.4 to C.sub.8) alcoholate to the reaction product of step (a),(c) equilibrating the admixture of step (b) so that substantially all of the triethylaluminum is converted into aluminum ethyl alcoholates, compounds with at least one C.sub.4 to C.sub.8 alcoholate group per molecule,(d) subjecting the equilibrated mixture of step (c) to a fractionation to recover, (1) a C.sub.2 to C.sub.24 .alpha.-olefin fraction, and (2) an aluminum ethyl alcoholate fraction (a mixture of compounds with the general formula Al(C.sub.2 H.sub.6).sub.X (OC.sub.6 H.sub.13).sub.Y (where X is 0 to 2 and Y is 3 to 1) and X+Y=3).(e) adding C.sub.4 to C.sub.8 alcohol to the aluminum ethyl alcoholate fraction to form aluminum tri-(C.sub.4 to C.sub.8) alcoholate and ethane,(f) separating the ethane and aluminum tri-(C.sub.4 to C.sub.8) alcoholate by fractionation, and(g) hydrolyzing the aluminum tri-(C.sub.4 to C.sub.8) alcoholate to form C.sub.4 to C.sub.8 alcohols and the desired alumina,and process being characterized further in that preferably the tri-(C.sub.2 to C.sub.24) alkylaluminum is prepared by:(1) preparing triethylaluminum from aluminum, ethylene and hydrogen, in two stages, and(2) reacting with triethylaluminum of step (1) with ethylene to form tri-(C.sub.2 to C.sub.24) alkylaluminum.

    摘要翻译： 公开了一种用于制备氧化铝和α-烯烃（α-烯烃）的组合方法。 该方法包括：（a）在镍催化剂存在下使三 - （C 2至C 24）烷基铝与乙烯反应形成三乙基铝和C 2至C 24α-烯烃，（b）将三（C 8 -C 8） 步骤（a）的反应产物，（c）平衡步骤（b）的混合物，使得基本上所有的三乙基铝转化成乙醇铝，每分子具有至少一个C 4至C 8醇盐基的化合物，（d） 步骤（c）的平衡混合物至分馏以回收，（1）C 2至C 24α-烯烃部分，和（2）乙醇酸铝部分（通式Al（C 2 H 6）X OC6H13）Y（其中X为0至2，Y为3至1），X + Y = 3）。 （e）将C4至C8醇加入到乙醇醇化物部分中以形成三（C4至C8）醇铝和乙烷三铝，（f）通过分馏分离乙烷和三（C4至C8）醇化物，和（g ）将水解三（C4至C8）醇化物形成C4至C8醇和所需的氧化铝，其进一步的特征在于，优选通过以下方法制备三 - （C 2至C 24）烷基铝：（1）由 铝，乙烯和氢的两个阶段，和（2）与步骤（1）的三乙基铝与乙烯反应形成三 - （C 2至C 24）烷基铝。