Abstract:
A positive electrode for a lithium ion secondary battery, the positive electrode including: a coated particle including a positive active material particle and a reactive layer on the surface of the positive active material particle; and a sulfide-containing solid electrolyte particle which is in contact with the coated particle, wherein the reactive layer includes a reactive element other than lithium and oxygen, wherein the reactive element has a reactivity with the sulfide-containing solid electrolyte particle which is greater than with a reactivity of the reactive element with a transition metal element included in the positive active material particle, and wherein a ratio of a thickness of the reactive layer to a particle diameter of the positive active material particle is in a range of about 0.0010 to about 0.25.
Abstract:
A lithium battery including a negative electrode including a lithium metal or a lithium alloy; a positive electrode; and a polymer gel electrolyte contacting the negative electrode, wherein the polymer gel electrolyte has an ionic conductivity of about 10−3 S/cm or greater, a lithium ion transference number of about 0.15 or greater, and a lithium ion mobility of about 10−6 cm2/V×sec or greater, wherein the polymer gel electrolyte includes a lithium salt, a polymer capable of forming a complex with the lithium salt, an insulating inorganic filler, and an organic solvent, wherein the organic solvent is inert with respect to the lithium metal, wherein an anionic radius of the lithium salt is about 2.5 Angstroms or greater, and wherein a molecular weight of the lithium salt is about 145 or greater.
Abstract:
A positive electrode for a lithium ion secondary battery, the positive electrode including: a coated particle including a positive active material particle and a reactive layer on the surface of the positive active material particle; and a sulfide-containing solid electrolyte particle which is in contact with the coated particle, wherein the reactive layer includes a reactive element other than lithium and oxygen, wherein the reactive element has a reactivity with the sulfide-containing solid electrolyte particle which is greater than with a reactivity of the reactive element with a transition metal element included in the positive active material particle, and wherein a ratio of a thickness of the reactive layer to a particle diameter of the positive active material particle is in a range of about 0.0010 to about 0.25.
Abstract:
An electrolyte including a lithium ion conductive polymer, a lithium salt, and an ionic liquid including an anion represented by Formula 1 below: wherein, in Formula 1 above, R1 and R2 are defined herein.
Abstract:
A composite solid electrolyte includes: a lithium ion conductive solid electrolyte; and a polymer-containing electrolyte coating layer on a surface of a lithium ion conductive solid electrolyte, wherein the polymer-containing electrolyte coating layer includes an ion conductive polymer having an alkylene oxide segment.
Abstract:
An electrolyte composite including a first block copolymer and a lithium ion conductor, wherein the first block copolymer includes i) a structural domain and ii) at least one of a rubbery domain and an ion conductive domain, wherein the structural domain includes a polymer segment including a structural repeating unit, wherein the rubbery domain includes a polymer segment including a rubbery repeating unit, and wherein the ion conductive domain includes a polymer segment including an ion conductive repeating unit.
Abstract:
A protected anode for lithium air batteries and a lithium air battery including the protected anode are provided. The protected anode includes: an anode intercalates and deintercalates lithium ions; a lithium ion-conductive solid electrolyte membrane; and a polymer electrolyte disposed between the anode and the ion-conductive solid electrolyte membrane, wherein the polymer electrolyte includes a lithium ion-conductive polymer, a compound represented by Formula 1 having a number average molecular weight from about 300 to about 1,000, and a lithium salt, and an amount of the compound of Formula 1 is from about 10 parts to about 25 parts by weight based on 100 parts by weight of the polymer electrolyte: In Formula 1, R1 to R6, and n are the same as defined in the specification.