公开(公告)号：US07456132B2

公开(公告)日：2008-11-25

申请号：US11572058

申请日：2005-07-12

申请人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada ,  Kunio Hayakawa ,  Shinya Kawahara ,  Hitoshi Shimbo

发明人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada ,  Kunio Hayakawa ,  Shinya Kawahara ,  Hitoshi Shimbo

IPC分类号： B41M5/333

CPC分类号： C07C275/34 ,  B41M5/305 ,  B41M5/323 ,  B41M5/3331 ,  B41M5/3335 ,  B41M5/3372 ,  B41M5/426 ,  B41M5/44 ,  B41M5/46 ,  B41M2205/36 ,  B41M2205/40

摘要： The present invention provides a reversible thermosensitive recording medium including a support and a thermosensitive recording layer thereon, in which the thermosensitive recording layer comprises an electron-donating coloring compound and an electron-accepting compound, and the thermosensitive recording layer is capable of forming a relatively developed condition and a relatively erased condition depending on at least one of the difference of heating temperatures and the difference of cooling rates following to heating, and in which the electron-accepting compound comprises a phenol compound represented by the General Formula (1): where, in the General Formula (1) “l” represents an integer of 1 to 3, “m” represents an integer of 1 or more, and “n” represents an integer of 7 or more.

摘要翻译： 本发明提供一种可逆热敏记录介质，其中包括支持体和热敏记录层，其中热敏记录层包含给电子着色化合物和受电子化合物，并且热敏记录层能形成相对 显影条件和相对擦除状态，这取决于加热温度的差异和加热后的冷却速度的差异中的至少一个，并且其中电子接受性化合物包含由通式（1）表示的酚化合物：其中 在通式（1）中，“1”表示1〜3的整数，“m”表示1以上的整数，“n”表示7以上的整数。

公开(公告)号：US20070225161A1

公开(公告)日：2007-09-27

申请号：US11572058

申请日：2005-07-12

申请人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada ,  Kunio Hayakawa ,  Shinya Kawahara ,  Hitoshi Shimbo

发明人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada ,  Kunio Hayakawa ,  Shinya Kawahara ,  Hitoshi Shimbo

IPC分类号： B41M5/24

CPC分类号： C07C275/34 ,  B41M5/305 ,  B41M5/323 ,  B41M5/3331 ,  B41M5/3335 ,  B41M5/3372 ,  B41M5/426 ,  B41M5/44 ,  B41M5/46 ,  B41M2205/36 ,  B41M2205/40

摘要： The present invention provides a reversible thermosensitive recording medium including a support and a thermosensitive recording layer thereon, in which the thermosensitive recording layer comprises an electron-donating coloring compound and an electron-accepting compound, and the thermosensitive recording layer is capable of forming a relatively developed condition and a relatively erased condition depending on at least one of the difference of heating temperatures and the difference of cooling rates following to heating, and in which the electron-accepting compound comprises a phenol compound represented by the General Formula (1): where, in the General Formula (1) “l” represents an integer of 1 to 3, m represents an integer of 1 or more, and n represents an integer of 7 or more.

摘要翻译： 本发明提供一种可逆热敏记录介质，其中包括支持体和热敏记录层，其中热敏记录层包含给电子着色化合物和受电子化合物，并且热敏记录层能形成相对 显影条件和相对擦除状态，这取决于加热温度的差异和加热后的冷却速度的差异中的至少一个，并且其中电子接受性化合物包含由通式（1）表示的酚化合物：其中 在通式（1）中，“1”表示1〜3的整数，m表示1以上的整数，n表示7以上的整数。

公开(公告)号：US07553796B2

公开(公告)日：2009-06-30

申请号：US11886200

申请日：2006-03-16

申请人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada

发明人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada

IPC分类号： B41M5/333

CPC分类号： C07C275/34 ,  B41J3/4075 ,  B41M5/305 ,  B41M5/323 ,  B41M5/3335 ,  B41M5/3372 ,  B41M5/42 ,  B41M5/426 ,  B41M5/46 ,  B41M2205/04 ,  B41M2205/40

摘要： The present invention provides a reversible thermosensitive recording medium including a support and a thermosensitive recording layer thereon, in which the thermosensitive recording layer contains an electron-donating coloring compound and an electron-accepting compound, and the thermosensitive recording layer is capable of forming a relatively developed condition and a relatively erased condition depending on at least one of the difference of heating temperatures and the difference of cooling rates following to heating, and in which the electron-accepting compound contains a phenol compound expressed by General Formula (1): where, in the General Formula (1), “l” represents an integer of 1 to 3 and “m” represents an integer of 23 or more.

摘要翻译： 本发明提供一种可逆热敏记录介质，其中包括支持体和热敏记录层，其中热敏记录层含有供电子着色化合物和电子接受性化合物，并且热敏记录层能形成相对 显影条件和相对擦除状态，这取决于加热温度的差异和加热后的冷却速度的差异中的至少一个，并且其中电子接受性化合物含有由通式（1）表示的酚化合物：其中， 在通式（1）中，“1”表示1〜3的整数，“m”表示23以上的整数。

公开(公告)号：US20080242539A1

公开(公告)日：2008-10-02

申请号：US11886200

申请日：2006-03-16

申请人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada

发明人： Satoshi Yamamoto ,  Kyoji Tsutsui ,  Hiromi Furuya ,  Kyohji Okada

IPC分类号： B41M5/20 ,  B41M5/26 ,  B41M5/24 ,  C07C275/36 ,  B41M5/50

CPC分类号： C07C275/34 ,  B41J3/4075 ,  B41M5/305 ,  B41M5/323 ,  B41M5/3335 ,  B41M5/3372 ,  B41M5/42 ,  B41M5/426 ,  B41M5/46 ,  B41M2205/04 ,  B41M2205/40

摘要： The present invention provides a reversible thermosensitive recording medium including a support and a thermosensitive recording layer thereon, in which the thermosensitive recording layer contains an electron-donating coloring compound and an electron-accepting compound, and the thermosensitive recording layer is capable of forming a relatively developed condition and a relatively erased condition depending on at least one of the difference of heating temperatures and the difference of cooling rates following to heating, and in which the electron-accepting compound contains a phenol compound expressed by General Formula (1): where, in the General Formula (1), “l” represents an integer of 1 to 3 and “m” represents an integer of 23 or more.

摘要翻译： 本发明提供一种可逆热敏记录介质，其中包括支持体和热敏记录层，其中热敏记录层含有供电子着色化合物和电子接受性化合物，并且热敏记录层能形成相对 显影条件和相对擦除状态，这取决于加热温度的差异和加热后的冷却速度的差异中的至少一个，并且其中电子接受性化合物含有由通式（1）表示的酚化合物：其中， 在通式（1）中，“1”表示1〜3的整数，“m”表示23以上的整数。

公开(公告)号：US07419934B2

公开(公告)日：2008-09-02

申请号：US11742771

申请日：2007-05-01

申请人： Satoshi Yamamoto ,  Hiromi Furuya ,  Kyohji Okada

发明人： Satoshi Yamamoto ,  Hiromi Furuya ,  Kyohji Okada

IPC分类号： B41M5/337

CPC分类号： B41M5/305 ,  B41M5/3335 ,  B41M5/3336 ,  B41M5/3375

摘要： A reversible thermosensitive coloring material which can reversibly achieve a relatively colored state and a relatively discolored state depending on a temperature to which the coloring material is heated or a cooling speed at which the coloring material is cooled after heated. The coloring material including an electron donating coloring agent; an electron accepting color developer configured to color the coloring agent; and a compound having a Zwitter ion in which a total of charges in a molecule of the compound is zero. A reversible thermosensitive recording material including a substrate and a reversible thermosensitive recording layer, which is located overlying the substrate and which includes the reversible thermosensitive coloring material.

摘要翻译： 一种可逆热敏着色材料，其可以根据着色材料被加热的温度或着色材料在加热后冷却的冷却速度，可逆地实现相对着色的状态和相对变色的状态。 着色材料包括给电子着色剂; 构造成使着色剂着色的电子接受彩色显影剂; 和具有其中化合物分子中的总电荷为零的两性离子的化合物。 一种可逆热敏记录材料，其包括基底和可逆热敏记录层，其位于衬底上并且包括可逆热敏着色材料。

公开(公告)号：US20070259782A1

公开(公告)日：2007-11-08

申请号：US11742771

申请日：2007-05-01

申请人： Satoshi YAMAMOTO ,  Hiromi Furuya ,  Kyohji Okada

发明人： Satoshi YAMAMOTO ,  Hiromi Furuya ,  Kyohji Okada

IPC分类号： B41M5/20

CPC分类号： B41M5/305 ,  B41M5/3335 ,  B41M5/3336 ,  B41M5/3375

摘要： A reversible thermosensitive coloring material which can reversibly achieve a relatively colored state and a relatively discolored state depending on a temperature to which the coloring material is heated or a cooling speed at which the coloring material is cooled after heated. The coloring material including an electron donating coloring agent; an electron accepting color developer configured to color the coloring agent; and a compound having a Zwitter ion in which a total of charges in a molecule of the compound is zero. A reversible thermosensitive recording material including a substrate and a reversible thermosensitive recording layer, which is located overlying the substrate and which includes the reversible thermosensitive coloring material.

摘要翻译： 一种可逆热敏着色材料，其可以根据着色材料被加热的温度或着色材料在加热后冷却的冷却速度，可逆地实现相对着色的状态和相对变色的状态。 着色材料包括给电子着色剂; 构造成使着色剂着色的电子接受彩色显影剂; 和具有其中化合物分子中的总电荷为零的两性离子的化合物。 一种可逆热敏记录材料，其包括基底和可逆热敏记录层，其位于衬底上方并且包括可逆热敏着色材料。

公开(公告)号：US06579826B2

公开(公告)日：2003-06-17

申请号：US09972860

申请日：2001-10-10

申请人： Hiromi Furuya ,  Tadafumi Tatewaki ,  Satoshi Arai ,  Takeshi Shibuya ,  Kyoji Tsutsui

发明人： Hiromi Furuya ,  Tadafumi Tatewaki ,  Satoshi Arai ,  Takeshi Shibuya ,  Kyoji Tsutsui

IPC分类号： B41M530

CPC分类号： B41M5/305 ,  B41M5/3372 ,  B41M5/41 ,  B41M5/443 ,  B41M5/46

摘要： A reversible thermosensitive recording medium including a substrate; a reversible thermosensitive recording layer on the substrate, which includes an electron donating coloring compound and an electron accepting compound, wherein the recording layer achieves a colored state when heated at a temperature not lower than an image forming temperature and then cooled at a first cooling speed, and the recording layer in the colored state achieves a non-colored state when heated at a temperature lower than the image forming temperature and not lower than an image erasing temperature or when heated at a temperature not lower than the image forming temperature and then cooled at a second cooling speed relatively slow compared to the first cooling speed; and a crosslinked polymer layer including a crosslinked polymer having an ultraviolet absorbing structure.

公开(公告)号：US5942377A

公开(公告)日：1999-08-24

申请号：US920953

申请日：1997-08-29

申请人： Masafumi Torii ,  Tadafumi Tatewaki ,  Hiroaki Matsui ,  Hiromi Furuya ,  Kyoji Tsutsui ,  Masaru Shimada ,  Katsushi Sugiyama ,  Katsuaki Kokubo ,  Katsuhisa Kamio ,  Kazuo Hosoda ,  Masafumi Moriya

发明人： Masafumi Torii ,  Tadafumi Tatewaki ,  Hiroaki Matsui ,  Hiromi Furuya ,  Kyoji Tsutsui ,  Masaru Shimada ,  Katsushi Sugiyama ,  Katsuaki Kokubo ,  Katsuhisa Kamio ,  Kazuo Hosoda ,  Masafumi Moriya

IPC分类号： B41M5/337 ,  B41M5/333 ,  B41M5/30

CPC分类号： B41M5/3335 ,  B41M5/305 ,  Y10S430/165

摘要： A reversible thermosensitive composition including a coloring agent and a developer and capable of assuming a colored state and a discolored state depending upon the thermal hysteresis thereof. The developer is a phenol compound represented by the formula: ##STR1## wherein R.sup.1 represents a substituted or non-substituted divalent hydrocarbon group having at least two carbon atoms, R.sup.2 represents a substituted or non-substituted hydrocarbon group, X and Y represent, independently from each other, a divalent group having a hetero atom and r is an integer of between 1 and 3. A reversible thermosensitive recording medium includes a support and a thermosensitive layer including the above composition.

摘要翻译： 一种可逆热敏组合物，其包含着色剂和显影剂，并且能够根据其热滞后而呈现着色状态和变色状态。 显影剂是由下式表示的酚化合物：其中R1表示具有至少两个碳原子的取代或未取代的二价烃基，R2表示取代或未取代的烃基，X和Y彼此独立地表示 ，具有杂原子的二价基团，r为1〜3的整数。可逆热敏记录介质包括载体和包含上述组成的热敏层。

公开(公告)号：US6001159A

公开(公告)日：1999-12-14

申请号：US114527

申请日：1998-07-13

申请人： Hiromi Furuya ,  Masafumi Torii ,  Kyoji Tsutsui ,  Masaru Shimada

发明人： Hiromi Furuya ,  Masafumi Torii ,  Kyoji Tsutsui ,  Masaru Shimada

IPC分类号： B41M5/30 ,  B41M5/333 ,  C09D11/00

CPC分类号： B41M5/305 ,  B41M5/3335 ,  B41M5/3336

摘要： A reversible thermosensitive coloring composition contains an electron-donating coloring compound and an electron-accepting compound, and is capable of reversibly assuming a color-developed state or a decolorized state depending upon the the temperature of the reversible thermosensitive coloring composition when heated, and/or the cooling rate of the reversible thermosensitive coloring composition when cooled after the heating thereof, with the electron-accepting compound being a compound of formula (I):A--R--X (I)wherein A represents a color-developing moiety; R represents an aliphatic hydrocarbon group comprising as the main chain thereof a straight chain hydrocarbon group having 8 or more carbon atoms, and may comprise a bivalent hetero-atom containing group and/or a bivalent aromatic group; and X represents a hetero-atom containing associative group. There is also provided a reversible thermosensitive recording medium comprising a support, and a thermosensitive recording layer formed thereon comprising the aforementioned reversible thermosensitive coloring composition.

摘要翻译： 可逆热敏着色组合物含有给电子着色化合物和电子接受性化合物，并且能够根据可逆热敏着色组合物的加热温度和/或可逆热敏着色组合物的温度，可逆地假设显色状态或脱色状态，和/ 或可逆热敏着色组合物在加热之后冷却时的冷却速率，其中电子接受性化合物为式（I）化合物：ARX（I）其中A表示显色部分; R表示含有8个以上碳原子的直链烃基作为主链的脂肪族烃基，可以含有2价含杂原子的基团和/或2价芳香族基团。 X表示含杂原子的缔合基团。 还提供了一种可逆热敏记录介质，其包括载体和形成在其上的热敏记录层，其包含上述可逆热敏着色组合物。

公开(公告)号：US5955225A

公开(公告)日：1999-09-21

申请号：US870973

申请日：1997-06-06

申请人： Hiromi Furuya ,  Masafumi Torii ,  Masaru Shimada ,  Fumio Kawamura ,  Kyoji Tsutsui ,  Katsushi Sugiyama ,  Katsuaki Kokubo ,  Katsuhisa Kamio ,  Kazuo Hosoda ,  Masafumi Moriya

发明人： Hiromi Furuya ,  Masafumi Torii ,  Masaru Shimada ,  Fumio Kawamura ,  Kyoji Tsutsui ,  Katsushi Sugiyama ,  Katsuaki Kokubo ,  Katsuhisa Kamio ,  Kazuo Hosoda ,  Masafumi Moriya

IPC分类号： B41M5/337 ,  B41M5/30 ,  B41M5/333

CPC分类号： B41M5/3335 ,  B41M5/305 ,  Y10S430/165

摘要： A reversible thermosensitive composition including a coloring agent and a developer and capable of assuming a colored state and a discolored state depending upon the thermal hysteresis thereof. The developer is a phenol compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.3 represent, independently from each other, a substituted or non-substituted hydrocarbon group, R.sup.2 represents a substituted or non-substituted aliphatic hydrocarbon group having at least two carbon atoms, with the proviso that the total number of carbon atoms of R.sup.1, R.sup.2 and R.sup.3 is at least 8, X and Y represent, independently from each other, a divalent group having a nitrogen atom or an oxygen atom and r is an integer of between 1 and 3.

摘要翻译： 一种可逆热敏组合物，其包含着色剂和显影剂，并且能够根据其热滞后而呈现着色状态和变色状态。 显影剂是由下式表示的酚化合物：其中R 1和R 3彼此独立地表示取代或未取代的烃基，R 2表示具有至少两个碳原子的取代或未取代的脂族烃基， 条件是R1，R2和R3的碳原子总数至少为8，X和Y彼此独立地表示具有氮原子或氧原子的二价基团，r是1和 3。