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    Ion exchange membrane having lamellar morphology and process of making the same
    1.
    发明授权
    Ion exchange membrane having lamellar morphology and process of making the same 有权
    具有层状形态的离子交换膜及其制造方法

    公开(公告)号：US08048963B2

    公开(公告)日：2011-11-01

    申请号：US12551272

    申请日：2009-08-31

    申请人： Timothy J. Fuller ,  Sean M MacKinnon ,  Michael R. Schoeneweiss

    发明人： Timothy J. Fuller ,  Sean M MacKinnon ,  Michael R. Schoeneweiss

    IPC分类号： C08F114/18

    CPC分类号： H01M8/1039 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1081 ,  H01M2300/0082 ,  Y02P70/56

    摘要： An ion exchange membrane is prepared from a block copolymer comprising a hydrophobic polymer segment and a polar polymer segment. The ion exchange membrane is formed by placing a film layer in steam, water or an electric field at a temperature greater than about 40° C. for sufficient amount of time to develop a bicontinuous morphology. The ion exchange membrane is also formed from a film layer comprising a block copolymer and a solvent. The film layer is placed in an electric field at an elevated temperature and dried therein. The film layer is thereby converted into an ion exchange membrane with bicontinuous morphology. The ion exchange membrane prepared according to these processes exhibits improved mechanical and electrochemical properties.

    摘要翻译： 离子交换膜由包含疏水性聚合物链段和极性聚合物链段的嵌段共聚物制备。 通过在大于约40℃的温度下将膜层置于蒸汽，水或电场中形成足够的时间以形成双连续形态来形成离子交换膜。 离子交换膜也由包含嵌段共聚物和溶剂的膜层形成。 将膜层放置在高温下的电场中并干燥。 由此将膜层转化为具有双连续形态的离子交换膜。 根据这些方法制备的离子交换膜表现出改进的机械和电化学性能。

    Polyelectrolyte membranes derived from soluble perfluorocyclobutane polymers with sulfonyl chloride groups
    3.
    发明授权
    Polyelectrolyte membranes derived from soluble perfluorocyclobutane polymers with sulfonyl chloride groups 有权
    衍生自具有磺酰氯基团的可溶性全氟环丁烷聚合物的聚电解质膜

    公开(公告)号：US07989512B1

    公开(公告)日：2011-08-02

    申请号：US12726061

    申请日：2010-03-17

    申请人： Timothy J. Fuller ,  Sean M MacKinnon ,  Michael R. Schoeneweiss

    发明人： Timothy J. Fuller ,  Sean M MacKinnon ,  Michael R. Schoeneweiss

    IPC分类号： C08F214/14 ,  C08J5/22

    CPC分类号： C08F214/18 ,  C08J5/2262 ,  C08J2371/12 ,  H01M8/1025

    摘要： A method of forming an ionomeric membrane includes a step of reacting a first polymer in chlorosulfonic acid to form a first precipitate. The first precipitate comprising a polymer including a polymer unit having at least one —SO2Cl moiety attached thereto and includes a step of dissolving the first precipitate in a polar aprotic solvent to form the first solution. A polymeric membrane is then formed from the first solution such that the membrane includes the polymer unit having at least one —SO2Cl. The polymer including a polymer unit a polymer unit having at least one —SO2Cl is then reacted with a nucleophilic compound to form the polymeric membrane.

    摘要翻译： 形成离聚物膜的方法包括使第一聚合物在氯磺酸中反应形成第一沉淀物的步骤。 所述第一沉淀物包含聚合物，所述聚合物包含具有至少一个与其结合的-SO 2 Cl部分的聚合物单元，并且包括将所述第一沉淀溶解在极性非质子溶剂中以形成所述第一溶液的步骤。 然后从第一溶液形成聚合物膜，使得膜包括具有至少一个-SO 2 Cl的聚合物单元。 包括具有至少一个-SO 2 Cl的聚合物单元的聚合物单元的聚合物然后与亲核化合物反应以形成聚合物膜。