公开(公告)号：US20090171127A1

公开(公告)日：2009-07-02

申请号：US12087884

申请日：2007-01-12

申请人： Seiichiro Murata ,  Keisuke Kokin ,  Takehiro Sonoi

发明人： Seiichiro Murata ,  Keisuke Kokin ,  Takehiro Sonoi

IPC分类号： C07C43/12

CPC分类号： C07C41/26 ,  C07C43/137

摘要： A novel fluorine-containing ether alcohol having a terminal perfluoromethoxy group represented by the following general formula: CF3O[CF(CF3)CF2O]nCF(CF3)CH2OH (where n is an integer of 0-12) can be produced by reduction reaction of a fluorine-containing ether carboxylic acid alkyl ester represented by the following general formula: CF3O[CF(CF3)CF2O]nCF(CF3)COOR (where R is an alkyl group, and n is an integer of 0-12), and the fluorine-containing ether alcohol alone or as a mixture with a fluorine-containing ether alcohol having a terminal perfluoroethoxy group or a terminal perfluoropropoxy group is expected to show a peculiar surfactant characteristic owing to the peculiarity of reaction at the terminal position, and can be used as a dispersing agent or a levelling agent.

摘要翻译： 具有由以下通式表示的末端全氟甲氧基的新型含氟醚醇：<？in-line-formula description =“In-line formula”end =“lead”→> CF 3 O [CF（CF 3）CF 2 O] n CF （CF 3）CH 2 OH <β在线式描述=“在线式”末端=“尾”→（其中n为0-12的整数）可以通过含氟醚羧酸的还原反应 酸性烷基酯由以下通式表示：<？in-line-formula description =“In-line formula”end =“lead”？> CF 3 O [CF（CF 3）CF 2 O] n CF（CF 3）COOR < -formulae description =“In-line Formulas”end =“tail”？>（其中R是烷基，n是0-12的整数），单独的含氟醚醇或与 具有末端全氟乙氧基或末端全氟丙氧基的含氟醚醇预期由于末端反应特性而表现出特殊的表面活性剂特征，可用作分散剂 歌手或流平剂。

公开(公告)号：US07772443B2

公开(公告)日：2010-08-10

申请号：US11921343

申请日：2006-05-22

申请人： Keisuke Kokin ,  Kimihiko Urata ,  Takehiro Sonoi

发明人： Keisuke Kokin ,  Kimihiko Urata ,  Takehiro Sonoi

IPC分类号： C07C43/12

CPC分类号： C07C41/22 ,  C07C43/126

摘要： An iodine-containing fluoropolyether represented by the following general formula [I]: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nI  [I] (where Rf is a perfluoroalkyl group having 1-3 carbon atoms, m is an integer of 0-10, and n is an integer of 3-12), is a novel compound having a perfluoropolyetheralkyl group capable of giving a flexibility to the molecule chain through the etheral bond, said perfluoropolyether alkyl group being bonded to the alkyl iodide having an alkyl group having 3 or more carbon atoms, and can be produced by reaction of a fluoropolyether group-containing alcohol represented by the following general formula [II]: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nOH  [II] (Where Rf, m, and n have the same meanings as defined above) with a metal iodide, preferably potassium iodide.

摘要翻译： 由以下通式[I]表示的含碘含氟聚醚：RfO [CF（CF 3）CF 2 O] m CF（CF 3）（CH 2）n I [I]（其中Rf是具有1-3个碳原子的全氟烷基，m是 是0〜10的整数，n为3〜12的整数）是具有通过醚键赋予分子链柔性的全氟聚醚烷基的新化合物，所述全氟聚醚烷基与烷基碘键合 具有3个以上碳原子的烷基，可以通过由以下通式[II]表示的含氟聚醚基团的醇反应来制造：RfO [CF（CF 3）CF 2 O] m CF（CF 3）（CH 2）n OH [II]（其中Rf，m和n具有与上述相同的含义）与金属碘化物，优选碘化钾。

公开(公告)号：US20080090977A1

公开(公告)日：2008-04-17

申请号：US11630227

申请日：2005-04-21

申请人： Keisuke Kokin ,  Takehiro Sonoi

发明人： Keisuke Kokin ,  Takehiro Sonoi

IPC分类号： C08F14/18

CPC分类号： C07C43/17

摘要： A fluorine-containing vinyl ether compound, represented by the following general formula: RfO(C3F6O)a(CnF2n)(CmH2m)bCH2OCH═CH2(where Rf is a polyfluoroalkyl group having 1 or more carbon atoms, a is 0, or an integer of 1-30, b is an integer of 1-10, and n and m each are 1 or 2), is produced by subjecting a fluorine-containing alcohol, represented by the following general formula: RfO(C3F6O)a(CnF2n)(CmH2m)bCH2OHand an alkyl vinyl ether, represented by the following general formula: XCH2CH2OCH═CH2 (where X is a halogen atom, a hydrogen atom, or an alkyl group having 1-10 carbon atoms) to XCH2CH2OH-elimination reaction in the presence of a palladium-based catalyst, and has a fluorine-containing polyether group originating from the hexafluoropropene oxide polymer, and thus is not so rigid as the perfluoroalkyl alkyl group of perfluoroalkyl vinyl ether, rather more flexible, and furthermore has distinguished thermal and chemical stabilities, and also good optical properties and surface-active characteristics together.

公开(公告)号：US07566806B2

公开(公告)日：2009-07-28

申请号：US11991049

申请日：2006-08-09

申请人： Keisuke Kokin ,  Takehiro Sonoi ,  Kimihiko Urata

发明人： Keisuke Kokin ,  Takehiro Sonoi ,  Kimihiko Urata

IPC分类号： C07C209/08 ,  C07C217/04 ,  C07C217/08 ,  C07C217/26

CPC分类号： C07C217/26

摘要： An alkylamino group-terminated fluoroether compound, represented by the following general formula: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nNR1R2 (where Rf is a perfluoro lower-alkyl group, R1 is an alkyl group having 1-12 carbon atoms, R2 is a hydrogen atom, or an alkyl group having 1-12 carbon atoms, m is an integer of 0-10, and n is an integer of 3-8) is a novel compound, and is produced by reaction of an iodide-terminated fluoroether compound, represented by the following general formula: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nI with an alkylamine compound, represented by the following general formula: NHR1R2.

摘要翻译： 由以下通式表示的烷基氨基封端的氟醚化合物：＆lt;线内公式说明=“在线式”末端=“铅”→RfO [CF（CF 3）CF 2 O] m CF（CF 3） CH2）nNR1R2 <βin-line-formula description =“In-line Formulas”end =“tail”？>（其中Rf是全氟低级烷基，R1是具有1-12个碳原子的烷基，R2是 氢原子或具有1-12个碳原子的烷基，m为0-10的整数，n为3-8的整数）是新化合物，通过碘化物封端的氟醚 化合物，由以下通式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> RfO [CF（CF 3）CF 2 O] m CF（CF 3）（CH 2）nI < -line-formula description =“In-line formula”end =“tail”？>与烷基胺化合物，由以下通式表示：<？in-line-formula description =“In-line Formulas”end =“lead “？> NHR1R2。<？in-line-formula description =”In-line Formulas“end =”tail“？>

公开(公告)号：US20090048469A1

公开(公告)日：2009-02-19

申请号：US11921343

申请日：2006-05-22

申请人： Keisuke Kokin ,  Kimihiko Urata ,  Takehiro Sonoi

发明人： Keisuke Kokin ,  Kimihiko Urata ,  Takehiro Sonoi

IPC分类号： C07C43/12

CPC分类号： C07C41/22 ,  C07C43/126

摘要： An iodine-containing fluoropolyether represented by the following general formula [I]: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nI  [I] (where Rf is a perfluoroalkyl group having 1-3 carbon atoms, m is an integer of 0-10, and n is an integer of 3-12), is a novel compound having a perfluoropolyetheralkyl group capable of giving a flexibility to the molecule chain through the etheral bond, said perfluoropolyether alkyl group being bonded to the alkyl iodide having an alkyl group having 3 or more carbon atoms, and can be produced by reaction of a fluoropolyether group-containing alcohol represented by the following general formula [II]: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nOH  [II] (Where Rf, m, avd n have the same meanings as defined above) with a metal iodide, preferably potassium iodide.

摘要翻译： 由以下通式[I]表示的含碘含氟聚醚：<？in-line-formula description =“In-line formula”end =“lead”→RfO [CF（CF 3）CF 2 O] m CF（CF 3） CH2）nI [I] <？in-line-formula description =“In-line Formulas”end =“tail”？>（其中Rf是具有1-3个碳原子的全氟烷基，m是0-10的整数 ，n为3-12的整数），是具有通过醚键赋予分子链柔性的全氟聚醚烷基的新型化合物，所述全氟聚醚烷基与具有3个烷基的烷基碘键合 或更多个碳原子，并且可以通过由以下通式[II]表示的含氟聚醚基团的醇反应来制备：<？in-line-formula description =“In-line Formulas”end =“lead”？> RfO [CF（CF 3）CF 2 O] m CF（CF 3）（CH 2）n OH [II] <βin-line-formula description =“In-line formula”end =“tail”？>（其中Rf，m，avd n具有 与上述相同的含义）与金属碘化物 碘化钾。

公开(公告)号：US20080221360A1

公开(公告)日：2008-09-11

申请号：US11991049

申请日：2006-08-09

申请人： Keisuke Kokin ,  Takehiro Sonoi ,  Kimihiko Urata

发明人： Keisuke Kokin ,  Takehiro Sonoi ,  Kimihiko Urata

IPC分类号： C07C213/02 ,  C07C217/02

CPC分类号： C07C217/26

摘要： An alkylamino group-terminated fluoroether compound, represented by the following general formula: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nNR1R2 (where Rf is a perfluoro lower-alkyl group, R1 is an alkyl group having 1-12 carbon atoms, R2 is a hydrogen atom, or an alkyl group having 1-12 carbon atoms, m is an integer of 0-10, and n is an integer of 3-8) is a novel compound, and is produced by reaction of an iodide-terminated fluoroether compound, represented by the following general formula: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nI with an alkylamine compound, represented by the following general formula: NHR1R2

摘要翻译： 由以下通式表示的烷基氨基封端的氟醚化合物：<？in-line-formula description =“In-line formula”end =“lead”？> RfO [CF（CF 3） ）CF 2 CF 2 CF 2 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 α-in-line-formula description =“In-line Formulas”end =“tail”？>（其中Rf是全氟低级烷基 基团R 1是具有1-12个碳原子的烷基，R 2是氢原子或具有1-12个碳原子的烷基，m是 0〜10的整数，n为3-8的整数）是新化合物，通过以下通式表示的碘化物封端的氟醚化合物的反应制备： “在线公式”end =“lead”？> RfO [CF（CF 3 3）CF 2 O] CF（CF 3） （“2”）在线公式描述=“在线公式”end =“tail”？> 与烷基胺化合物，由以下所示代表 g通用公式：<？in-line-formula description =“In-line formula”end =“lead”？> NHR <1>

公开(公告)号：US20120041201A1

公开(公告)日：2012-02-16

申请号：US13265356

申请日：2010-04-16

申请人： Keisuke Kokin ,  Seiichiro Murata ,  Hideki Abe ,  Yusuke Takahashi

发明人： Keisuke Kokin ,  Seiichiro Murata ,  Hideki Abe ,  Yusuke Takahashi

IPC分类号： C07D239/42 ,  C07D213/75 ,  C07D235/30

CPC分类号： C08G65/007 ,  C08G65/33313 ,  C08G65/33317 ,  C10M133/38 ,  C10M133/40 ,  C10M133/44 ,  C10M133/46 ,  C10M149/12 ,  C10M2215/082 ,  C10M2215/221 ,  C10M2215/223 ,  C10M2215/224 ,  C10M2215/30 ,  C10N2220/021 ,  C10N2240/204

摘要： A fluorine-containing polyether carboxylic acid amide represented by the general formula: CnF2n+1O(C3F6O)mRfCONHAr, wherein Rf is a fluorocarbon group having 1 to 2 carbon atoms, Ar is a nitrogen-containing heterocyclic group, n is an integer of 1 to 3, and m is an integer of 10 to 30, is produced by reacting a fluorine-containing polyether carboxylic acid fluoride represented by the general formula: CnF2n+1(C3F6O)mRfCOF, wherein Rf, n, and m are as defined above, with a nitrogen-containing heterocyclic amine compound represented by the general formula: ArNH2, wherein Ar is as defined above; wherein the reaction is carried out while a reaction temperature is first increased to 80 to 100° C., and then increased at a temperature increase rate that produces a temperature difference of 3 to 5° C. after 48 hours.

摘要翻译： 由通式C n F 2n + 1 O（C 3 F 6 O）m R f CONHAr表示的含氟聚醚羧酸酰胺，其中，Rf是碳原子数1〜2的氟烃基，Ar是含氮杂环基，n是1的整数 至3，m为10〜30的整数，通过使由通式C n F 2n + 1（C 3 F 6 O）m R f COF表示的含氟聚醚羧酸氟化物，其中Rf，n和m如上定义而制备 与由以下通式表示的含氮杂环胺化合物：ArNH 2，其中Ar如上所定义; 其中反应在反应温度首先升高至80〜100℃的同时进行，然后以48小时后产生3〜5℃的温度差的升温速度升高。

公开(公告)号：US09024077B2

公开(公告)日：2015-05-05

申请号：US13822718

申请日：2011-08-24

申请人： Soichiro Murakami ,  Keisuke Kokin ,  Seiichiro Murata

发明人： Soichiro Murakami ,  Keisuke Kokin ,  Seiichiro Murata

IPC分类号： C07C43/17 ,  C07C41/09 ,  C07C41/14

CPC分类号： C07C43/17 ,  C07C41/09 ,  C07C41/14

摘要： A fluorine-containing vinyl ether compound of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCH═CH2 is produced by subjecting a fluorine-containing alcohol of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOH wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, and 2-haloethyl vinyl ether of the formula: XCH2CH2OCH═CH2 to XCH2CH2OH-elimination reaction in the presence of a palladium-based catalyst and an aliphatic amine. The fluorine-containing vinyl ether compound contain a perfluoroalkyl group having 6 or less carbon atoms, which is said to have low bioaccumulation potential.

摘要翻译： 通过使下式的含氟醇（C 1 F 2 n + 1（CH 2 CF 2）a（CF 2 CF 2））（CH 2 CH 2）a（CF 2 CF 2）b（CH 2 CH 2）c OCH = CH 2 ）b（CH 2 CH 2）cOH其中n为1至6的整数，a为1至4的整数，b为1至3的整数，c为1至3的整数，和2-卤代乙基乙烯基醚 在钯基催化剂和脂族胺存在下，XCH2CH2OCH = CH2至XCH2CH2OH消除反应。 含氟乙烯基醚化合物含有具有6个或更少碳原子的全氟烷基，据说具有低的生物累积潜力。

公开(公告)号：US20130178659A1

公开(公告)日：2013-07-11

申请号：US13822718

申请日：2011-08-24

申请人： Soichiro Murakami ,  Keisuke Kokin ,  Seiichiro Murata

发明人： Soichiro Murakami ,  Keisuke Kokin ,  Seiichiro Murata

IPC分类号： C07C43/17 ,  C07C41/09

CPC分类号： C07C43/17 ,  C07C41/09 ,  C07C41/14

摘要： A fluorine-containing vinyl ether compound of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCH═CH2 is produced by subjecting a fluorine-containing alcohol of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOH wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, and 2-haloethyl vinyl ether of the formula: XCH2CH2OCH═CH2 to XCH2CH2OH-elimination reaction in the presence of a palladium-based catalyst and an aliphatic amine. The fluorine-containing vinyl ether compound contain a perfluoroalkyl group having 6 or less carbon atoms, which is said to have low bioaccumulation potential.

摘要翻译： 通过使下式的含氟醇（CnF2n + 1（CH2CF2）a（CF2CF2））（CF2CF2）b（CH2CH2）a（CF2CF2）b（CH2CH2）cOCH = CH2得到的含氟乙烯基醚化合物 ）b（CH 2 CH 2）cOH其中n为1至6的整数，a为1至4的整数，b为1至3的整数，c为1至3的整数，和2-卤代乙基乙烯基醚 在钯基催化剂和脂族胺存在下，XCH2CH2OCH = CH2至XCH2CH2OH消除反应。 含氟乙烯基醚化合物含有具有6个或更少碳原子的全氟烷基，据说具有低的生物累积潜力。

公开(公告)号：US08476435B2

公开(公告)日：2013-07-02

申请号：US13265356

申请日：2010-04-16

申请人： Keisuke Kokin ,  Seiichiro Murata ,  Hideki Abe ,  Yusuke Takahashi

发明人： Keisuke Kokin ,  Seiichiro Murata ,  Hideki Abe ,  Yusuke Takahashi

IPC分类号： C07D239/02

CPC分类号： C08G65/007 ,  C08G65/33313 ,  C08G65/33317 ,  C10M133/38 ,  C10M133/40 ,  C10M133/44 ,  C10M133/46 ,  C10M149/12 ,  C10M2215/082 ,  C10M2215/221 ,  C10M2215/223 ,  C10M2215/224 ,  C10M2215/30 ,  C10N2220/021 ,  C10N2240/204

摘要： A fluorine-containing polyether carboxylic acid amide represented by the general formula: CnF2n+1O(C3F6O)mRfCONHAr, wherein Rf is a fluorocarbon group having 1 to 2 carbon atoms, Ar is a nitrogen-containing heterocyclic group, n is an integer of 1 to 3, and m is an integer of 10 to 30, is produced by reacting a fluorine-containing polyether carboxylic acid fluoride represented by the general formula: CnF2n+1(C3F6O)mRfCOF, wherein Rf, n, and m are as defined above, with a nitrogen-containing heterocyclic amine compound represented by the general formula: ArNH2, wherein Ar is as defined above; wherein the reaction is carried out while a reaction temperature is first increased to 80 to 100° C., and then increased at a temperature increase rate that produces a temperature difference of 3 to 5° C. after 48 hours.

摘要翻译： 由通式C n F 2n + 1 O（C 3 F 6 O）m R f CONHAr表示的含氟聚醚羧酸酰胺，其中，Rf是碳原子数1〜2的氟烃基，Ar是含氮杂环基，n是1的整数 至3，m为10〜30的整数，通过使由通式C n F 2n + 1（C 3 F 6 O）m R f COF表示的含氟聚醚羧酸氟化物，其中Rf，n和m如上定义而制备 与由以下通式表示的含氮杂环胺化合物：ArNH 2，其中Ar如上所定义; 其中反应在反应温度首先升高至80〜100℃的同时进行，然后以48小时后产生3〜5℃的温度差的升温速度升高。