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公开(公告)号:US20130137881A1
公开(公告)日:2013-05-30
申请号:US13814320
申请日:2011-07-27
IPC分类号: C07D327/00
CPC分类号: C07D327/00
摘要: The present invention provides a method for producing a methylene disulfonate compound including reacting, in the presence of an acid and a dehydrating agent, a formaldehyde compound with at least one salt of alkanedisulfonic acid selected from the group consisting of alkali metal salts of alkanedisulfonic acid and alkaline earth metal salts of alkanedisulfonic acid each represented by a specific formula. According to the method of the present invention, a methylene disulfonate compound can be obtained in a simple manner at low cost.
摘要翻译: 本发明提供一种亚甲基二磺酸酯化合物的制造方法,其特征在于,在酸和脱水剂的存在下,使甲醛化合物与至少一种选自烷二磺酸的碱金属盐和链烷二磺酸的碱金属盐和 各种由特定配方表示的烷二磺酸的碱土金属盐。 根据本发明的方法,可以以简单的方式以低成本获得亚甲基二磺酸酯化合物。
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公开(公告)号:US08501966B2
公开(公告)日:2013-08-06
申请号:US13814320
申请日:2011-07-27
IPC分类号: C07D327/00
CPC分类号: C07D327/00
摘要: The present invention provides a method for producing a methylene disulfonate compound including reacting, in the presence of an acid and a dehydrating agent, a formaldehyde compound with at least one salt of alkanedisulfonic acid selected from the group consisting of alkali metal salts of alkanedisulfonic acid and alkaline earth metal salts of alkanedisulfonic acid each represented by a specific formula. According to the method of the present invention, a methylene disulfonate compound can be obtained in a simple manner at low cost.
摘要翻译: 本发明提供一种亚甲基二磺酸酯化合物的制造方法,其特征在于,在酸和脱水剂的存在下,使甲醛化合物与至少一种选自烷二磺酸的碱金属盐和链烷二磺酸的碱金属盐和 各种由特定配方表示的烷二磺酸的碱土金属盐。 根据本发明的方法,可以以简单的方式以低成本获得亚甲基二磺酸酯化合物。
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公开(公告)号:US09365507B2
公开(公告)日:2016-06-14
申请号:US13583730
申请日:2011-03-09
申请人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
发明人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
IPC分类号: C07C317/14 , C07C323/65
CPC分类号: C07C323/65
摘要: The present invention provides a diaryl sulfone compound represented by Formula (1): wherein R1 to R4 and R1′ to R4′ are the same or different, and each represents hydrogen, C1-4 alkyl, or halogen, and R5 represents C2-6 alkenyl, C1-4 alkyl, or aromatic heterocyclic group; a method for producing the diaryl sulfone compound represented by Formula (1) by reacting a 4,4′-dihaloarylsulfone compound with thiol salt compound having an alkylene group; and a method for producing the diaryl sulfone compound represented by Formula (1) by reacting a 4,4′-dihaloarylsulfone compound with a thiol salt compound having a hydroxyl group, and subjecting the resulting compound to reaction with a halogenating agent, followed by a dehydrohalogenation reaction.
摘要翻译: 本发明提供由式(1)表示的二芳基砜化合物:其中R1至R4和R1'至R4'相同或不同,各自表示氢,C1-4烷基或卤素,R5表示C2-6 烯基,C 1-4烷基或芳族杂环基; 通过使4,4'-二卤代芳基砜化合物与具有亚烷基的硫醇盐化合物反应制备由式(1)表示的二芳基砜化合物的方法; 以及通过使4,4'-二卤代芳基砜化合物与具有羟基的硫醇盐化合物反应制造由式(1)表示的二芳基砜化合物的方法,并使所得化合物与卤化剂反应,接着, 脱卤化氢反应。
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4.
公开(公告)号:US20130005982A1
公开(公告)日:2013-01-03
申请号:US13583730
申请日:2011-03-09
申请人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
发明人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
IPC分类号: C07C323/65 , C07D277/74 , C07C319/14
CPC分类号: C07C323/65
摘要: The present invention provides a diaryl sulfone compound represented by Formula (1): wherein R1 to R4 and R1′ to R4′ are the same or different, and each represents hydrogen, C1-4 alkyl, or halogen, and R5 represents C2-6 alkenyl, C1-4 alkyl, or aromatic heterocyclic group; a method for producing the diaryl sulfone compound represented by Formula (1) by reacting a 4,4′-dihaloarylsulfone compound with thiol salt compound having an alkylene group; and a method for producing the diaryl sulfone compound represented by Formula (1) by reacting a 4,4′-dihaloarylsulfone compound with a thiol salt compound having a hydroxyl group, and subjecting the resulting compound to reaction with a halogenating agent, followed by a dehydrohalogenation reaction.
摘要翻译: 本发明提供由式(1)表示的二芳基砜化合物:其中R1至R4和R1'至R4'相同或不同,各自表示氢,C1-4烷基或卤素,R5表示C2-6 烯基,C 1-4烷基或芳族杂环基; 通过使4,4'-二卤代芳基砜化合物与具有亚烷基的硫醇盐化合物反应制备由式(1)表示的二芳基砜化合物的方法; 以及通过使4,4'-二卤代芳基砜化合物与具有羟基的硫醇盐化合物反应制造由式(1)表示的二芳基砜化合物的方法,并使所得化合物与卤化剂反应,接着, 脱卤化氢反应。
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公开(公告)号:US09040724B2
公开(公告)日:2015-05-26
申请号:US13583725
申请日:2011-03-09
申请人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
发明人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
IPC分类号: C07C323/65 , C07C327/06 , C07D331/02 , C07C319/06
CPC分类号: C07C323/65 , C07C319/06 , C07C327/06 , C07D331/02
摘要: The present invention provides a diaryl sulfone compound represented by Formula (1) below: wherein R1 to R4 and R1′ to R4′ are the same or different; each represents hydrogen, C1-4 alkyl, or halogen; and R5 is (thio)glycidyl, acryloyl, or the like; and a method for producing the same. According to the present invention, a novel compound useful as a monomer for producing synthetic resin having a high refractive index and excellent transparency for optical materials can be efficiently produced with a simple production process, using an inexpensive material as a starting material.
摘要翻译: 本发明提供由下式(1)表示的二芳基砜化合物:其中R1至R4和R1'至R4'相同或不同; 各自表示氢,C 1-4烷基或卤素; 并且R 5为(硫基)缩水甘油基,丙烯酰基等; 及其制造方法。 根据本发明,通过使用廉价的材料作为原料,可以通过简单的制造方法有效地制造用作制备具有高折射率和优异的光学材料透明性的合成树脂的单体的新型化合物。
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6.
公开(公告)号:US20130005993A1
公开(公告)日:2013-01-03
申请号:US13583725
申请日:2011-03-09
申请人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
发明人: Paul Kuad , Hisaaki Kanda , Takeshi Fujiwara , Hiroyuki Shiraishi
IPC分类号: C07D405/12 , C07C315/04 , C07C321/28 , C07C319/02 , C07D409/12 , C07C317/24
CPC分类号: C07C323/65 , C07C319/06 , C07C327/06 , C07D331/02
摘要: The present invention provides a diaryl sulfone compound represented by Formula (1) below: wherein R1 to R4 and R1′ to R4′ are the same or different; each represents hydrogen, C1-4 alkyl, or halogen; and R5 is (thio)glycidyl, acryloyl, or the like; and a method for producing the same.According to the present invention, a novel compound useful as a monomer for producing synthetic resin having a high refractive index and excellent transparency for optical materials can be efficiently produced with a simple production process, using an inexpensive material as a starting material.
摘要翻译: 本发明提供由下式(1)表示的二芳基砜化合物:其中R1至R4和R1'至R4'相同或不同; 各自表示氢,C 1-4烷基或卤素; 并且R 5为(硫基)缩水甘油基,丙烯酰基等; 及其制造方法。 根据本发明,通过使用廉价的材料作为原料,可以通过简单的制造方法有效地制造用作制备具有高折射率和优异的光学材料透明性的合成树脂的单体的新型化合物。
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公开(公告)号:US09004534B2
公开(公告)日:2015-04-14
申请号:US13379480
申请日:2011-09-07
CPC分类号: B62D1/195
摘要: Provided is construction of a steering apparatus for an automobile that is capable of simplifying tuning for stabilizing forward displacement in the forward direction of a steering wheel during a secondary collision, and preventing damage to the component members of the section that supports a bracket 12b on the column side with respect to the bracket 11 on the vehicle side. In construction where the bracket on the vehicle side 11 and the bracket 12b on the column side are connected at only one location in the center section in the width direction of the both brackets by a locking capsule, the top edges of a pair of protruding sections 63 that protrude to both the left and right sides of the bracket 12b on the column side closely face the bottom edge of a bent section 56 of the bracket 11 on the vehicle side. The bracket 12b on the column side is prevented from inclining excessively even when a large moment is applied to the bracket 12b on the column side when an attempt is made to rotate the steering wheel with a steering lock apparatus in the locked state.
摘要翻译: 提供一种用于汽车的转向装置的结构,其能够简化用于在二次碰撞期间在方向盘的向前方向上的前进位移的调整,并且防止对支撑在第二碰撞的支架12b的部分的部件构成损坏 相对于车辆侧的托架11的列侧。 在车辆侧11的支架和列侧的支架12b通过锁定胶囊在两个支架的宽度方向上的中心部分的一个位置处连接的结构中,一对突出部分的顶部边缘 柱体侧的支架12b的左右两侧突出,与支架11的车辆侧的弯曲部56的底部边缘紧贴。 即使在转向锁定装置处于锁定状态的情况下试图使方向盘旋转时,即使在立柱侧的托架12b施加大的力矩时,也能够防止柱侧的支架12b倾斜。
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公开(公告)号:US08585089B2
公开(公告)日:2013-11-19
申请号:US13379491
申请日:2011-09-26
IPC分类号: B62D1/19
CPC分类号: B62D1/195
摘要: An assembly method for a steering column support apparatus is achieved that simplifies tuning for stabilizing forward displacement of a steering wheel during a secondary collision, eliminates space in the engagement section between a bracket 11 on the vehicle side and a locking capsule 47a, and suppresses rocking displacement of the steering column due to that space. Of a plurality of small through holes 49a, 49b on the capsule side and a plurality of small notch sections 55a, 55b, part of the small through holes 49a and the small notch sections 55a are aligned, and pin shaped members 58 are formed so as to span these small through holes and small notch sections. After that, the locking capsule 47a and bracket 11 on the vehicle side are put into the final assembled position, shearing the pin shaped members 58 in the process. The remaining small though holes 49b, the remaining small notch sections 55b and small through holes 54 are aligned, and locking pins 50, 50a that shear during a secondary collision are formed so as to span these holes.
摘要翻译: 实现了一种用于转向柱支撑装置的组装方法,其简化了用于在二次碰撞期间稳定方向盘向前位移的调谐,消除了车辆侧的支架11与锁定胶囊47a之间的接合部分中的空间,并且抑制了摇摆 由于该空间导致转向柱的位移。 在胶囊侧的多个小通孔49a,49b和多个小切口部55a,55b中,小通孔49a和小切口部55a的一部分对准,销形状部件58形成为 跨越这些小通孔和小切口部分。 之后,将锁定胶囊47a和车辆侧的支架11置于最终组装位置,在该过程中剪切销形状构件58。 剩余的小通孔49b,剩余的小切口部分55b和小通孔54对准,并且在二次碰撞期间剪切的锁定销50,50a形成为跨越这些孔。
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公开(公告)号:US20130037131A1
公开(公告)日:2013-02-14
申请号:US13642885
申请日:2012-01-27
IPC分类号: F16K31/122
CPC分类号: F15B13/0402 , F15B13/042 , F16K3/26 , F16K11/07 , F16K31/122 , Y10T137/7762 , Y10T137/8663 , Y10T137/86702 , Y10T137/8671
摘要: A control valve includes a signal pressure passage that transmits a pilot pressure of first and second pilot chambers as a signal pressure of another device, a connecting groove that is formed in a spool and connects the first pilot chamber to the signal pressure passage when the spool is in a neutral position, a connecting hole that is formed in the spool and connects the second pilot chamber to the signal pressure passage, and a check valve that is interposed in the connecting hole and permits a flow only from the second pilot chamber to the signal pressure passage. The connecting groove connects the first pilot chamber to the signal pressure passage when the pilot pressure is led into the first pilot chamber, and blocks communication between the first pilot chamber and the signal pressure passage when the pilot pressure is led into the second pilot chamber.
摘要翻译: 控制阀包括将第一和第二引导室的先导压力作为另一装置的信号压力传递的信号压力通道,形成在阀芯中的连接槽,并且当阀芯 处于中立位置,形成在阀芯中并将第二先导室连接到信号压力通道的连接孔,以及设置在连接孔中的止回阀,仅允许从第二先导室流向 信号压力通道。 当先导压力被引导到第一先导室中时,连接槽将第一先导室连接到信号压力通道,并且当先导压力被引导到第二先导室时,阻止第一先导室和信号压力通道之间的连通。
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公开(公告)号:US20120267884A1
公开(公告)日:2012-10-25
申请号:US13386658
申请日:2011-11-09
IPC分类号: B62D1/19
CPC分类号: B62D1/195
摘要: Construction of a steering column support apparatus is achieved that simplifies tuning for stabilizing forward displacement of a steering wheel during a secondary collision, lowers and stabilizes the break away load, and when necessary, prevents the steering wheel from dropping excessively after a secondary collision. A locking cutout section 27 that extends in the forward/backward direction is formed in a bracket 11a on the vehicle side, top and bottom sliding plate sections 31a, 31b that are formed on outside and inside sliding plates 51, 52 of a sliding member 28 are located on both the top and bottom surfaces of the portions on both sides of the locking cutout section 27. A bolt that is inserted from the top through these sliding plate sections 31a, 31b and a nut 30 connect the top plate section 23 of a bracket 12b on the column side to the bracket 11a on the vehicle side. During a secondary collision, the outside sliding plate 51 slides and moves in the forward direction with respect to the inside sliding plate 52, and the bracket 12b on the column side breaks away from the bracket 11a on the vehicle side with little force.
摘要翻译: 实现转向柱支撑装置的构造,其简化了调整,以便在二次碰撞期间稳定方向盘的向前位移,降低并稳定分离载荷,并且在必要时防止方向盘在二次碰撞之后过度下落。 在车辆侧的支架11a中形成有向前后方向延伸的锁定切口部27,形成在滑动部件28的滑动板51,52的外侧和内侧的上部和下部滑动板部31a,31b 位于锁定切口部分27两侧的部分的顶表面和底表面上。从顶部穿过这些滑板部分31a,31b和螺母30插入的螺栓将顶板部分23连接到 在支柱侧的支架12b与车辆侧的支架11a相连。 在二次碰撞期间,外侧滑动板51相对于内侧滑动板52向前方滑动移动,柱侧的支架12b以较小的力从车辆侧的支架11a脱离。
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