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公开(公告)号:US20240097278A1
公开(公告)日:2024-03-21
申请号:US18029779
申请日:2021-10-19
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Kaori OGITA , Tetsuji ISHITANI , Shuhei YOSHITOMI , Fumiko TANAKA , Shotaro MURATSUBAKI , Teppei OGUNI
IPC: H01M50/451 , H01M10/0525 , H01M50/403 , H01M50/434 , H01M50/491
CPC classification number: H01M50/451 , H01M10/0525 , H01M50/403 , H01M50/434 , H01M50/491
Abstract: A secondary battery with little deterioration is provided. A secondary battery with high safety is provided. A separator having excellent characteristics is provided. A separator achieving the secondary battery with high safety is provided. A novel separator is provided. In the separator, a polymer porous film and a layer including a ceramic-based material containing a metal oxide microparticle are stacked, the thickness of the layer including a ceramic-based material is greater than or equal to 1 μm and less than or equal to 100 μm, and the film thickness of the polymer porous film is greater than or equal to 4 μm and less than or equal to 50 μm.
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公开(公告)号:US20250105291A1
公开(公告)日:2025-03-27
申请号:US18773889
申请日:2024-07-16
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Takuya ISHIMOTO , Shotaro MURATSUBAKI , Naoto OKUZAWA , Tatsuyoshi TAKAHASHI , Masayuki KIMURA , Kazutaka KURIKI
IPC: H01M4/587 , H01M4/02 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569
Abstract: To provide a battery having excellent charge-discharge characteristics even in a low-temperature environment. The battery includes a positive electrode, a negative electrode, an electrolyte solution, and a separator. The electrolyte solution and the separator are included between the positive electrode and the negative electrode; the negative electrode includes a carbon material; and the electrolyte solution includes a lithium salt, a potassium salt, a fluorinated cyclic carbonate, a fluorinated linear carbonate, and at least one kind of anion. The carbon material includes graphite; the lithium salt includes LiPF6; the potassium salt includes KFSI; the fluorinated cyclic carbonate includes fluoroethylene carbonate; and the fluorinated linear carbonate includes methyl trifluoropropionate.
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公开(公告)号:US20240047751A1
公开(公告)日:2024-02-08
申请号:US18265913
申请日:2021-12-02
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kaori OGITA , Fumiko TANAKA , Shotaro MURATSUBAKI , Tetsuji ISHITANI , Shunpei YAMAZAKI
IPC: H01M10/0568 , H01M10/0525
CPC classification number: H01M10/0568 , H01M10/0525 , H01M2220/20
Abstract: A lithium-ion secondary battery with high capacity and excellent charge and discharge cycle performance is provided. A secondary battery with high capacity is provided. A secondary battery with excellent charge and discharge characteristics is provided. A secondary battery in which a reduction in capacity is inhibited even when a state being charged with a high voltage is held for a long time is provided. A secondary battery includes a positive electrode, a negative electrode, and an electrolyte, and the amount of moisture in the electrolyte is less than 1000 ppm.
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公开(公告)号:US20230402602A1
公开(公告)日:2023-12-14
申请号:US18327948
申请日:2023-06-02
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Shunpei YAMAZAKI , Shotaro MURATSUBAKI , Takayuki IKEDA
IPC: H01M4/525 , H01M4/505 , H01M50/46 , H01M4/62 , H01M10/0525
CPC classification number: H01M4/525 , H01M4/505 , H01M50/46 , H01M4/625 , H01M10/0525 , H01M2004/028
Abstract: One embodiment of the present invention further improves thermal safety of a lithium-ion secondary battery for stable power supply from the lithium-ion secondary battery. To improve thermal safety, fluorine is contained in a positive electrode active material or adsorbed on a surface portion of the positive electrode active material so that overheating or ignition of the lithium-ion secondary battery is inhibited. When fluorine is adsorbed on the surface of the positive electrode active material, the adsorbed fluorine can react with its vicinity electrolyte solution or the like, leading to inhibition of thermal decomposition or the like of the electrolyte solution.
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公开(公告)号:US20230231199A1
公开(公告)日:2023-07-20
申请号:US18001623
申请日:2021-06-30
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kaori OGITA , Hiroshi KADOMA , Fumiko TANAKA , Kazutaka KURIKI , Yumiko YONEDA , Shotaro MURATSUBAKI , Kaori FUJIE , Taku ICHINO
IPC: H01M10/0569 , H01M10/0568
CPC classification number: H01M10/0569 , H01M10/0568 , H01M2300/0034
Abstract: An object is to provide a nonaqueous solvent, a secondary battery, or a vehicle having a wide usable temperature range and high heat resistance. The nonaqueous solvent of the present invention contains an ionic liquid at greater than or equal to 50 vol % and less than or equal to 95 vol % and a fluorinated cyclic carbonate, and the ionic liquid contains an imidazolium cation. The nonaqueous solvent of the present invention has low viscosity at low temperatures and high heat resistance, thereby having a wide usable temperature range.
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公开(公告)号:US20220173429A1
公开(公告)日:2022-06-02
申请号:US17530763
申请日:2021-11-19
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Masayuki KIMURA , Kaori OGITA , Fumiko TANAKA , Shotaro MURATSUBAKI
IPC: H01M10/0525 , H01M4/525 , H01M10/0569 , H01M10/0568
Abstract: A storage battery that is less likely to be affected by the ambient temperature is provided. A storage battery that can be charged and discharged at low temperatures is provided. In the storage battery, a secondary battery that can be charged and discharged at low temperatures is provided adjacent to a general secondary battery. The storage battery having such a structure can use, as an internal heat source in a low temperature environment, heat generated by charging and discharging of the secondary battery that can be charged and discharged at low temperatures. Specifically, the storage battery includes a first lithium-ion secondary battery and a second lithium-ion secondary battery adjacent to each other. The first lithium-ion secondary battery contains at least one of an ionic liquid, a molecular crystalline electrolyte, a semi-solid-state electrolyte, an all-solid-state electrolyte, and lithium titanate. The second lithium-ion secondary battery contains an organic electrolyte solution.
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公开(公告)号:US20240266594A1
公开(公告)日:2024-08-08
申请号:US18562562
申请日:2022-05-24
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Shuhei YOSHITOMI , Kaori OGITA , Shotaro MURATSUBAKI , Atsushi KAWATSUKI , Mayumi MIKAMI , Yohei MOMMA , Tetsuya KAKEHATA , Shunpei YAMAZAKI
IPC: H01M10/0562 , H01M4/02 , H01M4/505 , H01M4/525 , H01M4/583 , H01M10/0525
CPC classification number: H01M10/0562 , H01M4/505 , H01M4/525 , H01M4/583 , H01M10/0525 , H01M2004/027 , H01M2004/028 , H01M2220/30
Abstract: Provided is a secondary battery having a favorable interface contact between an active material and an electrolyte. The secondary battery includes a positive electrode layer, a negative electrode layer, and an electrolyte layer positioned between the positive electrode layer and the negative electrode layer. The positive electrode layer contains a positive electrode active material and a first solid electrolyte, the negative electrode layer contains a negative electrode active material and a second solid electrolyte, the electrolyte layer contains a third solid electrolyte and an ionic liquid, and a space in the third solid electrolyte is impregnated with the ionic liquid. The secondary battery is bendable.
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公开(公告)号:US20240097194A1
公开(公告)日:2024-03-21
申请号:US18039505
申请日:2021-12-03
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Kaori OGITA , Kazuya SHIMADA , Takashi HIRAHARA , Fumiko TANAKA , Shotaro MURATSUBAKI , Satoshi SEO
IPC: H01M10/0569 , C01G53/00 , H01M4/525 , H01M10/0525 , H01M10/0567
CPC classification number: H01M10/0569 , C01G53/66 , H01M4/525 , H01M10/0525 , H01M10/0567 , C01P2002/72 , C01P2002/76 , C01P2006/40 , H01M2004/028
Abstract: A novel ionic liquid is provided. A highly safe secondary battery with high charge and discharge capacity is provided. The ionic liquid includes a cation represented by General Formula (G1) and an anion represented by Structural Formula (200). In the formula, X1 to X3 each independently represent any one of fluorine, chlorine, bromine, and iodine. One of X1 to X3 may be hydrogen. In addition, n and m each independently represent 0 to 5. Furthermore, a secondary battery including the above-described ionic liquid is provided.
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公开(公告)号:US20240021862A1
公开(公告)日:2024-01-18
申请号:US18252316
申请日:2021-11-09
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Shunpei YAMAZAKI , Tetsuya KAKEHATA , Tetsuji ISHITANI , Shotaro MURATSUBAKI
IPC: H01M10/052 , H01M4/525 , H01M10/42 , H01M10/0587 , B60L50/60
CPC classification number: H01M10/052 , H01M4/525 , H01M10/4235 , H01M10/0587 , B60L50/66 , H01M2004/028
Abstract: A secondary battery stable in a high-potential state and/or a high-temperature state is provided. The secondary battery includes a positive electrode and a negative electrode, and one or both of the positive electrode and the negative electrode contain an active material and a composite compound with a crystal structure. The composite compound has a function of a binder. The composite compound can also be used as an electrolyte. The composite compound with a crystal structure has typically a molecular crystal. The composite compound with a crystal structure can be obtained by mixing a first compound and a second compound while heating is performed at higher than or equal to a temperature at which a mixture of the first compound and the second compound is melted.
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公开(公告)号:US20230402601A1
公开(公告)日:2023-12-14
申请号:US18326655
申请日:2023-05-31
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Shunpei YAMAZAKI , Shotaro MURATSUBAKI , Takayuki IKEDA
IPC: H01M4/525 , H01M4/1315
CPC classification number: H01M4/525 , H01M4/1315 , H01M2004/028
Abstract: To provide a high-safety battery. The battery includes a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, and an electrolyte solution. The positive electrode active material includes a first region and a second region. The first region contains cobalt, magnesium, fluorine, and oxygen. The second region contains cobalt and oxygen. The first region is closer to a surface of the positive electrode active material than the second region is. The negative electrode active material contains graphite. The electrolyte solution contains a mixed organic solvent. When the battery in a fully charged state undergoes a nail penetration test in which the nail diameter is 3 mm and the nail penetration speed is 5 mm/sec, the voltage of the battery decreases from a first voltage Vb to a second voltage Vc and then exceeds the second voltage Vc.
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