摘要:
Aryl ethers, e.g., cumylmethylether and anisole, are particularly effective additives for improving the octane number of motor fuels. These aryl ethers are especially useful in increasing the octane number of unleaded gasolines.
摘要:
Mononuclear aromatic hydrocarbons, e.g. benzene and analogs, are converted by hydroalkylation to the corresponding cycloalkyl aromatics by contacting the mononuclear aromatic hydrocarbons in the presence of hydrogen with a catalyst comprising a rare earth-exchanged Y-type zeolite support carrying a promoter comprising at least one of ruthenium, iridium, rhodium and palladium, the catalyst being calcined in an oxygen-containing atmosphere at a temperature of 250.degree. to 600.degree. C. prior to the hydroalkylation reaction.
摘要:
A fixed-bed catalytic material comprises iron impregnated Alundum carrying a coating of copper oxide on its outside surfaces. By means of the coating, the growth of carbon fibers as a result of the disproportionation of carbon monoxide is restricted to the interior surfaces of the catalyst particles.
摘要:
Hydroperoxides, such as cyclohexylbenzene hydroperoxide, are manufactured by the oxidation of aryl compounds, such as cyclohexylbenzene, in the presence of a catalyst selected from the group consisting of C.sub.6 -C.sub.18 primary amines and polyvinylpyrrolidone.
摘要:
Cyclohexenyl and alkenyl aromatic compounds, such as cyclohexene and styrene, are prepared by a process comprising contacting a corresponding cyclohexyl or alkyl aromatic carboxylic acid, such as cyclohexyl carboxylic acid or 2-phenyl propionic acid, with a decarboxylation catalyst of the formulaM.sub.a M'.sub.b O.sub.xwhereM is copper or a combination of copper and molybdenum, andM' is at least one promoter element, such as a Group IA element.
摘要:
1,1-diphenylethane or 1,1-diphenylethylene is oxidized to benzophenone by contacting the 1,1-diphenylethane or 1,1-diphenylethylene and oxygen with an antimonate catalyst.
摘要:
Hydroperoxides are catalytically decomposed using a novel metal complex of the formula: ##STR1## wherein M is a positively charged metal or metal compound;Z is S, O, P, S-P, or S-S;L is C, P, or N; andA is selected from the group consisting of halogens; hydrogen; N-R wherein R is selected from the group consisting of H, C.sub.1-30 alkyls and 4 to 8 membered aryls optionally substituted with one or more C.sub.1-20 alkyls and C.sub.1-20 alkoxys; and hydrocarbon groups containing up to 30 carbon atoms optionally substituted with halogen atoms, C.sub.1-12 hydroxy groups, C.sub.1-12 acid groups, C.sub.1-12 aldehyde groups, C.sub.1-12 ketone groups, and C.sub.1-10 nitrile groups; andwhereinn is 1 or 2; andb is 1, 2 or 3.These catalysts are especially effective in decomposing either cumene hydroperoxide or cyclohexylbenzene hydroperoxide to phenol.
摘要:
Mononuclear aromatic hydrocarbons, e.g. benzene and analogs, are converted by hydroalkylation to the corresponding cycloalkyl aromatics by contacting the mononuclear aromatic hydrocarbons in the presence of hydrogen with a catalyst comprising a rare earth-exchanged Y-type zeolite support carrying a promoter comprising at least one of ruthenium, iridium, rhodium and palladium, the catalyst being calcined in an oxygen-containing atmosphere at a temperature of 250.degree. to 600.degree. C. prior to the hydroalkylation reaction.
摘要:
This invention relates to an improved process for the dehydrogenation of diarylethanes to the corresponding diarylethylenes in the presence of oxygen and in the presence of a metal phosphate catalyst.
摘要:
Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.