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    Nickel-copper-molybdenum methanation catalyst
    3.
    发明授权
    Nickel-copper-molybdenum methanation catalyst 失效
    镍 - 铜 - 莫来石甲烷催化剂

    公开(公告)号：US3962140A

    公开(公告)日：1976-06-08

    申请号：US556808

    申请日：1975-03-10

    申请人： William R. Alcorn ,  Leonard A. Cullo

    发明人： William R. Alcorn ,  Leonard A. Cullo

    IPC分类号： C07C1/02 ,  B01J23/88 ,  B01J23/885 ,  B01J31/00 ,  B01J31/16 ,  C07B61/00 ,  C07C1/00 ,  C07C1/04 ,  C07C9/04 ,  C07C67/00 ,  C10K3/04 ,  B01J23/84

    CPC分类号： C10K3/04 ,  B01J23/885 ,  C07C1/0435 ,  C07C2523/28 ,  C07C2523/72 ,  C07C2523/755 ,  C07C2523/885

    摘要： A supported methanation catalyst and a process for utilizing the catalyst are disclosed. The catalyst yields a product containing a major proportion of methane and some ethane. Methanation of a gaseous feed stream containing from about 10 to about 50 mole percent carbon monoxide, and from about 1.0 to about 3.0 times as much hydrogen as carbon monoxide, is effected at elevated temperature and high pressure continuously over a prolonged period of time, while a conversion of carbon monoxide in excess of 80 mole percent is maintained. Thermal stability at elevated temperature and pressure permits essentially continuous use of the catalyst for extended periods of time without time-consuming shutdowns. High conversion of gaseous feed and thermal stability of catalyst permits economical process design which utilizes a minimal recycle, if any.The supported catalyst consists essentially of a complex of oxides of nickel, copper and molybdenum which complex is reduced on the support prior to or during use. The complex of oxides consists of from about 5 to about 20 percent by weight molybdenum oxide, and from about 5 to about 40 percent by weight nickel oxide, each amount based on total catalyst, present in a weight ratio of nickel oxide to copper oxide in the range from 1:1 to about 9:1, and preferably in the range from about 1 to about 3.

    METHOD FOR ISOMERIZING OLEFINS
    5.
    发明申请
    METHOD FOR ISOMERIZING OLEFINS 审中-公开
    异烯烃方法

    公开(公告)号：US20100286458A1

    公开(公告)日：2010-11-11

    申请号：US12738034

    申请日：2008-10-15

    申请人： Stefan Iselborn ,  Thomas Heidemann

    发明人： Stefan Iselborn ,  Thomas Heidemann

    IPC分类号： C07C5/03 ,  C07C5/25

    CPC分类号： C07C11/06 ,  C07C5/2512 ,  C07C6/04 ,  C07C2521/04 ,  C07C2523/85 ,  C07C2523/885 ,  C07C2523/888 ,  C07C11/08

    摘要： The present invention relates to a process for isomerizing olefins in olefin-comprising hydrocarbon mixtures having from 4 to 20 carbon atoms at temperatures of from 20 to 200° C. and pressures of from 1 to 200 bar in the liquid phase in the presence of a heterogeneous catalyst, wherein a catalyst comprising from 1 to 20% by weight of nickel in oxidic form and from 1 to 20% by weight of at least one element of group VIB on an aluminum oxide support is used.

    摘要翻译： 本发明涉及一种使含烯烃的烃混合物中的烯烃异构化的方法，该烃混合物在20〜200℃的温度和1〜200巴的压力下，在液相中，在 使用非均相催化剂，其中使用包含1至20重量％的氧化物形式的镍和1至20重量％的至少一种氧化铝载体上VIB族元素的催化剂。

    Ni hydrogenation catalysts, manufacture and use
    6.
    发明授权
    Ni hydrogenation catalysts, manufacture and use 有权
    镍氢化催化剂，制造和使用

    公开(公告)号：US07022645B2

    公开(公告)日：2006-04-04

    申请号：US10633867

    申请日：2003-08-04

    申请人： J. Yong Ryu ,  Hugh M. Putman

    发明人： J. Yong Ryu ,  Hugh M. Putman

    IPC分类号： B01J23/755

    CPC分类号： C07C5/05 ,  C07C5/09 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/84 ,  C07C2523/85 ,  C07C2523/885

    摘要： Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m2/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

    摘要翻译： 公开了用于氢化反应的改进的Ni催化剂。 该催化剂可用于氢化，例如在粗烯烃和二烯烃流中的炔属杂质的选择性氢化。 催化剂通过在具有以下具体物理性质的多孔载体上沉积镍来制备; BET表面积为30至约100m 2 / g，总氮孔体积为0.4至约0.9cc / g，平均孔径为约110至450有或没有 一种或多种选自Cu，Re，Pd，Zn，Mg，Mo，Ca和Bi的元素的改性剂。

    Ni hydrogenation catalysts, manufacture and use
    10.
    发明申请
    Ni hydrogenation catalysts, manufacture and use 有权

    公开(公告)号：US20060030482A1

    公开(公告)日：2006-02-09

    申请号：US11249867

    申请日：2005-10-13

    申请人： J. Ryu ,  Hugh Putman

    发明人： J. Ryu ,  Hugh Putman

    IPC分类号： B01J23/00

    CPC分类号： C07C5/05 ,  C07C5/09 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/84 ,  C07C2523/85 ,  C07C2523/885

    摘要： Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m2/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.