摘要:
A proton conducting membrane having a high ionic conductivity and an excellent high temperature dimensional stability which can perform stably even at high temperatures, a method for producing the same and a solid polymer-based fuel cell comprising same are provided. In other words, the present invention concerns a method for producing a proton conducting membrane having a crosslinked structure formed by a silicon-oxygen covalent bond and having a sulfonic acid-containing crosslinked structure represented by the following formula (1) therein, which comprises a first step of preparing a mixture containing a mercapto group-containing oligomer (A) having a plurality of mercapto groups and a reactive group which can form a Si—O—Si bond by condensation reaction, a second step of forming said mixture into a membrane, a third step of subjecting said membrane-like material to condensation reaction in the presence of a catalyst to obtain a crosslinked gel and a fourth step of oxidizing the mercapto group in the membrane so that it is converted to a sulfonic acid group, a proton conducting membrane obtained by same and a fuel cell comprising same:
摘要:
To make an arrangement so as not to give any damage to the central part of a substrate during the operation for removing unnecessary film coated on the outer peripheral part of the substrate. The stage is provided therein with a refrigerant chamber 41 as a heat absorber and a refrigerant such as water is filled in the chamber. A wafer 90 is contacted with and supported on the support surface 10a of the stage 10. A reactive gas for removing unnecessary film is supplied the outer periphery of the wafer 90 through a reactive gas jet port 30b while heating the outer periphery of the wafer 90. On the other hand, the area inside the outer peripheral part of the wafer 90 is heat-absorbed by the heat absorber.
摘要:
To enhance a removing efficiency of unnecessary matters on a peripheral part of a substrate (90) such as wafer and to prevent particles from adhering to the substrate (90). A reactive gas is jetted out from a jet nozzle (75) toward a target spot (P) of the peripheral part of the substrate (90) in such a way that the reactive gas is made to flow approximately along a circumferential direction at the target spot (P) of the substrate (90) as viewed from a direction orthogonal to the substrate (90). Gases near the target spot (P) are sucked by a suction nozzle (76) along approximately the circumferential direction at a downstream side of the target spot (P).