公开(公告)号：US07476990B2

公开(公告)日：2009-01-13

申请号：US12106392

申请日：2008-04-21

申请人： Hiroshi Nakagawa ,  Kazumichi Kato ,  Toshio Miki ,  Minoru Maeda ,  Takashi Fukunaga ,  Kozo Furutani ,  Toshiya Sugimoto

发明人： Hiroshi Nakagawa ,  Kazumichi Kato ,  Toshio Miki ,  Minoru Maeda ,  Takashi Fukunaga ,  Kozo Furutani ,  Toshiya Sugimoto

IPC分类号： H02K33/16 ,  H02K33/00 ,  F04B17/04

CPC分类号： H01F7/1615 ,  H01F7/081 ,  H01F7/122 ,  H02K7/085 ,  H02K21/44 ,  H02K33/16 ,  H02K41/033

摘要： An object of the present invention is to provide a linear actuator in which reliability is improved, and performance is also easily improved. The present invention provides a linear actuator including a stator, a movable element having an iron member, and being reciprocatable with respect to the stator, a permanent magnet fixed to the stator so as to be opposed to the iron member, and a coil fixed to the stator. Because both the coil and the permanent magnet are fixed to the stator, electrical current does not have to be supplied to the movable element, and the feeder lines connected to the coil will not be broken due to the movement of the movable element. In addition, the weight of the movable element will not be increased even when the weigh of the permanent magnet is increased in order to obtain high magnetic flux density for improvement in performance. Moreover, because the movable element does not include a magnet, a magnetizing operation does not have to be applied to the movable element. The permanent magnets may be a pair in which the directions the magnetic poles thereof differ from each other, and two pairs of permanent magnets may be provided. The number of magnetic fluxes that run through the magnetic pole elements and the iron member can be increased by providing a magnetic reluctance section around the permanent magnets.

摘要翻译： 本发明的目的是提供一种可靠性提高的线性致动器，并且性能也容易提高。 本发明提供了一种线性致动器，其包括定子，具有铁构件的可移动元件，并且能够相对于定子往复运动;固定到定子上以与铁构件相对的永磁体，以及固定到 定子。 由于线圈和永磁体均固定在定子上，所以不必向可动元件供电，并且由于可移动元件的移动而连接到线圈的馈线不会被破坏。 此外，为了提高性能，为了获得高的磁通密度，即使永磁体的重量增加，可移动元件的重量也不会增加。 此外，由于可动元件不包括磁体，因此不必对可动元件施加磁化操作。 永磁体可以是彼此不同的磁极方向的一对，并且可以设置两对永磁体。 可以通过在永磁体周围设置磁阻部分来增加穿过磁极元件和铁构件的磁通量的数量。

公开(公告)号：US07214756B2

公开(公告)日：2007-05-08

申请号：US10450845

申请日：2002-10-29

申请人： Shigeki Nomura ,  Toshiya Sugimoto ,  Masanori Nakamura ,  Kenji Yamauchi

发明人： Shigeki Nomura ,  Toshiya Sugimoto ,  Masanori Nakamura ,  Kenji Yamauchi

IPC分类号： C08G77/28

CPC分类号： C08G77/28 ,  C08G77/50 ,  C08J5/2275 ,  C08J2383/06 ,  H01B1/122 ,  H01M4/8605 ,  H01M8/1037 ,  H01M8/1051 ,  H01M8/1074 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02P70/56 ,  Y10T442/2467

摘要： The present invention provides relates to a crosslinkable, proton-conducting membrane having a crosslinked structure, excellent in heat resistance, durability, dimensional stability and fuel barrier characteristics, and showing excellent proton conductivity at high temperature, characterized by comprising (a) an organic/inorganic hybrid structure (A) covalently bonded to 2 or more silicon-oxygen crosslinks and, at the same time, having a carbon atom, and (b) an acid containing structure (B) having an acid group, covalently bonded to a silicon-oxygen crosslink and having an acidic group; and provides a fuel cell using the same membrane. The present invention also provides a method for producing the proton-conducting membrane, comprising steps of preparing a mixture containing an organic/inorganic hybrid, crosslinkable compound (C) and compound (D), the former having 2 or more crosslinkable silyl groups and carbon atoms each being bonded to the silyl group via the covalent bond and the latter having a crosslinkable silyl group and acid group, as the first step; forming the above mixture into a film as the second step; and hydrolyzing/condensing or only condensing the hydrolyzable silyl group contained in the mixture formed into the film to form a crosslinked structure as the third step.

摘要翻译： 本发明涉及具有交联结构，耐热性，耐久性，尺寸稳定性和燃料阻隔特性优异的交联性质子传导膜，并且在高温下显示出优异的质子传导性，其特征在于包括（a）有机/ 共价结合到2个以上的硅 - 氧交联基团，同时具有碳原子的无机杂化结构（A），和（b）具有酸基的含酸结构体（B），共价键合到硅 - 氧交联并具有酸性基团; 并提供使用相同膜的燃料电池。 本发明还提供一种生产质子传导膜的方法，包括以下步骤：制备含有有机/无机杂化物，可交联化合物（C）和化合物（D）的混合物，前者具有2个或更多个可交联甲硅烷基和碳 作为第一步，各自通过共价键与甲硅烷基键合的原子，后者具有交联性甲硅烷基和酸基; 将上述混合物形成为第二步骤的膜; 并将形成的混合物中所含的可水解甲硅烷基水解/缩合或缩合形成第三步的交联结构。

公开(公告)号：US20060219981A1

公开(公告)日：2006-10-05

申请号：US10554222

申请日：2004-04-23

申请人： Toshihito Miyama ,  Toshiya Sugimoto ,  Shigeki Nomura

发明人： Toshihito Miyama ,  Toshiya Sugimoto ,  Shigeki Nomura

IPC分类号： H01B1/12

CPC分类号： H01B1/122 ,  H01M8/0289 ,  H01M8/1037 ,  H01M8/1067 ,  H01M8/1074 ,  Y02P70/56

摘要： It is intended to provide a proton conducting membrane which is excellent in heat resistance, dimensional stability, fuel barrier properties, flexibility, etc. and exhibits an excellent protonic conductivity even at high temperatures, a method of producing same and a fuel cell which can operate stably at high temperatures, the proton conducting membrane of the present invention comprises a support filled with a proton conducting structure (β) comprising an acid-containing structure containing an acid group, which support being made of an organic-inorganic composite structure (α) having a crosslinked structure formed by a metal-oxygen bond and an open-cell structure having internally-formed pores connected continuously to each other by the crosslinked structure, and the use of this proton conducting membrane makes it possible to obtain a fuel cell having an excellent performance.

摘要翻译： 本发明提供一种耐热性，尺寸稳定性，燃料阻隔性，柔软性等优异的质子传导膜，即使在高温下也表现出优异的质子传导性，其制造方法和能够操作的燃料电池 稳定地在高温下，本发明的质子传导膜包括填充有质子传导结构（β）的载体，该质子传导结构（β）包含含有酸基团的含酸结构，其支持由有机 - 无机复合结构（α） 具有通过金属 - 氧键形成的交联结构和具有通过交联结构彼此连续连接的内部形成的孔的开孔结构，并且通过使用该质子传导膜，可以获得具有 出色表现。

公开(公告)号：US5552216A

公开(公告)日：1996-09-03

申请号：US132315

申请日：1993-10-06

申请人： Toshiya Sugimoto ,  Minoru Suezaki ,  Tokushige Shitiri ,  Kouji Maruyama

发明人： Toshiya Sugimoto ,  Minoru Suezaki ,  Tokushige Shitiri ,  Kouji Maruyama

IPC分类号： C09D5/24 ,  H01B1/12 ,  B32B5/16 ,  B32B27/30 ,  H01B1/20

CPC分类号： H01B1/128 ,  C09D5/24 ,  Y10T428/256 ,  Y10T428/31935

摘要： An electrically conductive composition of the invention comprises 100 parts by weight of a (meth)acrylate compound possessing at least two (meth)acryloyl groups, 1 to 100 parts by weight of an anilinic electrically conductive polymer, and 0.1 to 20 parts by weight of a photopolymerization initiator sensitized by active rays. This electrically conductive composition may also comprise an unsaturated compound possessing any one group selected from the group consisting of a phosphoric acid group, a sulfonic acid group and a carboxyl group. Between the surface of a form to be coated and the coating layer made of the electrically conductive composition formed thereon, an inorganic electrically conductive layer composed of the tin oxide powder containing antimony with mean particle size of 0.01 to 0.4 .mu.m, or the barium sulfate powder coated with tin oxide containing antimony with mean particle size of 0.01 to 2 .mu.m, and a synthetic resin may be provided.

摘要翻译： 本发明的导电组合物包含100重量份具有至少两个（甲基）丙烯酰基的（甲基）丙烯酸酯化合物，1至100重量份的苯胺系导电聚合物和0.1至20重量份的 由活性光线敏化的光聚合引发剂。 该导电性组合物还可以包含具有选自磷酸基，磺酸基和羧基中的任何一个基团的不饱和化合物。 在待涂覆形式的表面和由其上形成的导电组合物制成的涂层之间，由含有平均粒径为0.01至0.4μm的锑的氧化锡粉末或硫酸钡形成的无机导电层 粉末涂覆有平均粒度为0.01〜2μ​​m的含锑的氧化锡，可以提供合成树脂。

公开(公告)号：US20060035129A1

公开(公告)日：2006-02-16

申请号：US10540564

申请日：2004-02-05

申请人： Shigeki Nomura ,  Kenji Yamauchi ,  Satoshi Koma ,  Toshiya Sugimoto ,  Taira Hasegawa

发明人： Shigeki Nomura ,  Kenji Yamauchi ,  Satoshi Koma ,  Toshiya Sugimoto ,  Taira Hasegawa

IPC分类号： C08J5/22

CPC分类号： C08J5/2287 ,  C08G77/28 ,  C08G77/392 ,  C08J2383/00 ,  H01B1/122 ,  H01M8/0289 ,  H01M8/1007 ,  H01M8/1009 ,  H01M8/12 ,  H01M2300/0082 ,  Y02P70/56

摘要： A proton conducting membrane having a high ionic conductivity and an excellent high temperature dimensional stability which can perform stably even at high temperatures, a method for producing the same and a solid polymer-based fuel cell comprising same are provided. In other words, the present invention concerns a method for producing a proton conducting membrane having a crosslinked structure formed by a silicon-oxygen covalent bond and having a sulfonic acid-containing crosslinked structure represented by the following formula (1) therein, which comprises a first step of preparing a mixture containing a mercapto group-containing oligomer (A) having a plurality of mercapto groups and a reactive group which can form a Si—O—Si bond by condensation reaction, a second step of forming said mixture into a membrane, a third step of subjecting said membrane-like material to condensation reaction in the presence of a catalyst to obtain a crosslinked gel and a fourth step of oxidizing the mercapto group in the membrane so that it is converted to a sulfonic acid group, a proton conducting membrane obtained by same and a fuel cell comprising same:

摘要翻译： 提供了具有高离子导电性和优异的高温尺寸稳定性的质子传导膜，即使在高温下也能稳定地进行，其制造方法以及包含该固体聚合物的燃料电池。 换句话说，本发明涉及一种制造具有由硅 - 氧共价键形成的交联结构并具有由下式（1）表示的含磺酸交联结构的质子传导膜的方法，该方法包括： 制备含有具有多个巯基的含巯基低聚物（A）和通过缩合反应形成Si-O-Si键的反应性基团的混合物的混合物的第一步骤，将所述混合物形成膜 第三步，在催化剂存在下对所述膜状材料进行缩合反应，得到交联凝胶，第四步是将膜中的巯基氧化成磺酸基，质子 由其获得的导电膜和包含该膜的燃料电池：

公开(公告)号：US06864006B2

公开(公告)日：2005-03-08

申请号：US10038875

申请日：2002-01-08

申请人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

发明人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

IPC分类号： B01D69/14 ,  B01D71/70 ,  C08G77/04 ,  C08J5/22 ,  H01B1/06 ,  H01B13/00 ,  H01M8/02 ,  H01M8/10

CPC分类号： C08J5/2256 ,  B01D69/141 ,  B01D71/70 ,  C08J2383/10 ,  H01M8/1023 ,  H01M8/1037 ,  H01M8/1044 ,  H01M8/1048 ,  H01M8/1074 ,  Y02P70/56

摘要： A proton-conducting membrane, excellent in resistance to heat, durability, dimensional stability and fuel barrier characteristics, and showing excellent proton conductivity at high temperature and a method for producing the same. A proton-conducting membrane includes a carbon-containing compound and inorganic acid, characterized by a phase-separated structure containing a carbon-containing phase containing at least 80% by volume of the carbon-containing compound and inorganic phase containing at least 80% by volume of the inorganic acid, the inorganic phase forming the continuous ion-conducting paths. The method for producing the above proton-conducting membrane includes steps of preparing a mixture of a carbon-containing compound (D) having one or more hydrolyzable silyl groups and inorganic acid (C), forming the above mixture into a film, and hydrolyzing/condensing the hydrolyzable silyl group contained in the mixture formed into the film, to form a three-dimensionally crosslinked silicon-oxygen structure (A). The above proton-conducting membrane is incorporated in a fuel cell.

摘要翻译： 具有优异耐热性，耐久性，尺寸稳定性和燃料阻隔特性以及高温下优异的质子传导性的质子传导膜及其制造方法。 质子传导膜包括含碳化合物和无机酸，其特征在于相分离结构，其含有含碳相含有至少80体积％的含碳化合物和无机相的无机相含有至少80％ 无机酸的体积，形成连续离子传导路径的无机相。 制造上述质子传导膜的方法包括以下步骤：制备具有一个或多个可水解甲硅烷基的含碳化合物（D）和无机酸（C）的混合物，将上述混合物形成膜，并水解/ 将形成的混合物中所含的可水解甲硅烷基缩合成膜，形成三维交联的硅 - 氧结构（A）。 上述质子传导膜并入燃料电池中。

公开(公告)号：US06680138B1

公开(公告)日：2004-01-20

申请号：US09662909

申请日：2000-09-15

申请人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

发明人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

IPC分类号： H01M986

CPC分类号： C08J5/2256 ,  C08J2371/12 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1037 ,  H01M8/1044 ,  H01M8/1048 ,  H01M8/1051 ,  H01M8/1074 ,  Y02P70/56

摘要： It is an object of the present invention to provide a proton-conducting membrane excellent in resistance to heat and durability and showing excellent proton conductivity at high temperature. It is another object of the present invention to provide a method for producing the same and fuel cell using the same. The present invention provides a proton-conducting membrane, comprising an organic material (A), three-dimensionally crosslinked structure (B) containing a specific metal-oxygen bond, agent (C) for imparting proton conductivity, and water (D), wherein the organic material (A) has a number-average molecular weight of 56 to 30,000, and at least 4 carbon atoms connected in series in the main chain, and the organic material (A) and three-dimensionally crosslinked structure (B) are bound to each other via a covalent bond.

摘要翻译： 本发明的目的是提供耐热性和耐久性优异的质子传导膜，并且在高温下显示优异的质子传导性。 本发明的另一个目的是提供一种其制造方法和使用该方法的燃料电池。本发明提供一种质子传导膜，其包含有机材料（A），三维交联结构（B），其含有 特定的金属 - 氧键，用于赋予质子传导性的试剂（C）和水（D），其中有机材料（A）的数均分子量为56〜30,000，至少4个碳原子串联连接 在主链中，有机材料（A）和三维交联结构（B）通过共价键彼此结合。

公开(公告)号：US6020447A

公开(公告)日：2000-02-01

申请号：US828958

申请日：1997-03-28

申请人： Dietmar Seyferth ,  Toshiya Sugimoto ,  Pawel Czubarow

发明人： Dietmar Seyferth ,  Toshiya Sugimoto ,  Pawel Czubarow

IPC分类号： C04B35/571 ,  C08G77/60 ,  C08G77/04

CPC分类号： C04B35/571 ,  C08G77/60

摘要： A process is provided that involves reductive coupling of polysilane precursors to form polysilane in the presence of ultrasonification. The resulting precursors, upon pyrolysis, lead to improved SiC ceramic product. Ultrasonification can be used to produce oligosilanes from precursors thereof, or polysilanes from monomers, dimers, trimers, or oligomers. Precursors can include Si:C in a ratio of about 1:1, and the invention allows formation of SiC having a Si:C ratio of about 1:1.

摘要翻译： 提供了一种方法，其涉及聚硅烷前体的还原偶联以在超声波存在下形成聚硅烷。 所得前体在热解时导致改善的SiC陶瓷产品。 可以使用超声波从其前体制备低聚硅烷，或从单体，二聚体，三聚体或低聚物制备聚硅烷。 前体可以包括约1:1的Si:C，本发明允许形成Si：C比约为1:1的SiC。

公开(公告)号：US5429846A

公开(公告)日：1995-07-04

申请号：US256737

申请日：1994-10-25

申请人： Toshiya Sugimoto ,  Minoru Suezaki ,  Kouji Maruyama

发明人： Toshiya Sugimoto ,  Minoru Suezaki ,  Kouji Maruyama

IPC分类号： C08F2/44 ,  C08F2/48 ,  C08F2/50 ,  C08F261/12 ,  C08F290/00 ,  C08F299/02 ,  C09D4/00 ,  C09D4/06 ,  C09D5/00 ,  C09D5/24 ,  H01B1/20 ,  C09D133/04 ,  C09D159/00 ,  H01B1/22

CPC分类号： H01B1/20 ,  C08F261/12 ,  C09D5/24 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/1321

摘要： The present invention provides a photo-setting conductive coating composition which is used as an antistatic material constituting articles wherein static electrification must be avoided, such as storage vessels for semi-conductor wafers, electronic/electric parts, floor/wall coverings for a production factory of semi-conductors, etc.The photo-setting conductive coating composition comprising 100 parts by weight of an antimony oxide-containing tin oxide powder (a) having a particle size of 0.01 to 0.4 .mu.m, 10 to 100 parts by weight of a (meth)acrylate compound (b) having at least two (meth)acryloyl groups in a molecule, 10 to 100 parts by weight of an acetal resin (c) having a residual hydroxyl group of 20 to 80 molar %, 0.1 to 10 parts by weight of a photopolymerization initiator (d) and 100 to 1000 parts by weight of an organic solvent (e).

摘要翻译： PCT No.PCT / JP93 / 01749 Sec。 371日期：1994年10月25日 102（e）日期1994年10月25日PCT提交1993年12月1日PCT公布。 第WO94 / 13745号公报 日期：1994年6月23日。本发明提供一种光固化导电涂料组合物，其用作构成制品的抗静电材料，其中必须避免静电，例如用于半导体晶片的储存容器，电子/电气部件，地板 /半导体生产厂的墙面涂料等。该光固化性导电性涂料组合物包含100重量份的粒径为0.01〜0.4μm的含氧化锑的氧化锡粉末（a），10重量份 相对于100重量份在分子中具有至少两个（甲基）丙烯酰基的（甲基）丙烯酸酯化合物（b），10〜100重量份残留羟基的缩醛树脂（c）为20〜80重量份 摩尔％，0.1〜10重量份的光聚合引发剂（d）和100〜1000重量份的有机溶剂（e）。

公开(公告)号：US07382067B2

公开(公告)日：2008-06-03

申请号：US10497678

申请日：2002-11-26

申请人： Hiroshi Nakagawa ,  Kazumichi Kato ,  Toshio Miki ,  Minoru Maeda ,  Takashi Fukunaga ,  Kozo Furutani ,  Toshiya Sugimoto

发明人： Hiroshi Nakagawa ,  Kazumichi Kato ,  Toshio Miki ,  Minoru Maeda ,  Takashi Fukunaga ,  Kozo Furutani ,  Toshiya Sugimoto

IPC分类号： H02K33/16 ,  H02K33/00 ,  F04B17/04

CPC分类号： H01F7/1615 ,  H01F7/081 ,  H01F7/122 ,  H02K7/085 ,  H02K21/44 ,  H02K33/16 ,  H02K41/033

摘要： An object of the present invention is to provide a linear actuator in which reliability is improved, and performance is also easily improved. The present invention provides a linear actuator including a stator, a movable element having an iron member, and being reciprocatable with respect to the stator, a permanent magnet fixed to the stator so as to be opposed to the iron member, and a coil fixed to the stator. Because both the coil and the permanent magnet are fixed to the stator, electrical current does not have to be supplied to the movable element, and the feeder lines connected to the coil will not be broken due to the movement of the movable element. In addition, the weight of the movable element will not be increased even when the weigh of the permanent magnet is increased in order to obtain high magnetic flux density for improvement in performance. Moreover, because the movable element does not include a magnet, a magnetizing operation does not have to be applied to the movable element. The permanent magnets may be a pair in which the directions the magnetic poles thereof differ from each other, and two pairs of permanent magnets may be provided. The number of magnetic fluxes that run through the magnetic pole elements and the iron member can be increased by providing a magnetic reluctance section around the permanent magnets.

摘要翻译： 本发明的目的是提供一种可靠性提高的线性致动器，并且性能也容易提高。 本发明提供了一种线性致动器，其包括定子，具有铁构件的可移动元件，并且能够相对于定子往复运动;固定到定子上以与铁构件相对的永磁体，以及固定到 定子。 由于线圈和永磁体均固定在定子上，所以不必向可动元件供电，并且由于可移动元件的移动而连接到线圈的馈线不会被破坏。 此外，为了提高性能，为了获得高的磁通密度，即使永磁体的重量增加，可移动元件的重量也不会增加。 此外，由于可动元件不包括磁体，因此不必对可动元件施加磁化操作。 永磁体可以是彼此不同的磁极方向的一对，并且可以设置两对永磁体。 可以通过在永磁体周围设置磁阻部分来增加穿过磁极元件和铁构件的磁通量的数量。