公开(公告)号：US20070287066A1

公开(公告)日：2007-12-13

申请号：US11808159

申请日：2007-06-07

申请人： Tadaya Okada ,  Shigeto Noya ,  Isao Abe ,  Minoru Shiraoka

发明人： Tadaya Okada ,  Shigeto Noya ,  Isao Abe ,  Minoru Shiraoka

IPC分类号： H01M4/52

CPC分类号： H01M4/52 ,  H01M4/06 ,  H01M4/46 ,  H01M6/08

摘要： An alkaline primary battery includes a positive electrode containing at least nickel oxyhydroxide as a positive electrode active material, a negative electrode containing zinc or a zinc alloy as a negative electrode active material, a separator arranged between the positive electrode and the negative electrode, and an alkaline electrolyte. The nickel oxyhydroxide contains at least manganese and calcium as elements forming solid solution or eutectic crystal with the nickel oxyhydroxide.

摘要翻译： 碱性一次电池包括至少含有作为正极活性物质的氢氧化正镍的正极，含有锌或锌合金的负极作为负极活性物质，配置在正极和负极之间的隔膜，以及 碱性电解液。 羟基氧化镍至少含有锰和钙作为与氢氧化正镍形成固溶体或共晶晶体的元素。

公开(公告)号：US20080193843A1

公开(公告)日：2008-08-14

申请号：US11883618

申请日：2006-08-07

申请人： Shigeto Noya ,  Tadaya Okada ,  Isao Abe ,  Minoru Shiraoka

发明人： Shigeto Noya ,  Tadaya Okada ,  Isao Abe ,  Minoru Shiraoka

IPC分类号： H01M6/06 ,  H01M4/52 ,  H01M4/50 ,  H01M4/42 ,  H01M2/14

CPC分类号： H01M4/32 ,  H01M4/244 ,  H01M4/42 ,  H01M4/64 ,  H01M6/06 ,  H01M6/08 ,  H01M6/10 ,  H01M10/30

摘要： An alkaline dry battery including nickel oxyhydroxide and manganese dioxide as positive electrode active materials. The nickel oxyhydroxide is a solid solution including at least manganese and cobalt. The content of the manganese is 5.2×10−2 to 7.5×10−2 moles per mole of the nickel oxyhydroxide, and the content of the cobalt is 0.5×10−2 to 2.0×10−2 moles. The alkaline dry battery maintains excellent heavy-load discharge characteristics, exhibits suppressed polarization during heavy-load pulse discharge to improve the operational stability of digital devices, and has high reliability with respect to leakage resistance and safety under short-circuit conditions.

摘要翻译： 一种碱性干电池，包括氢氧化正镍和二氧化锰作为正极活性物质。 氢氧化镍是至少含有锰和钴的固溶体。 每摩尔羟基氧化镍，锰的含量为5.2×10 -2〜7.5×10 -2摩尔，钴的含量为0.5×10 -6〜 2至2.0×10 -2摩尔。 碱性干电池保持优异的重负载放电特性，在重负载脉冲放电期间显示抑制极化，提高数字器件的操作稳定性，并且在短路条件下具有高耐漏电性和安全性的可靠性。

公开(公告)号：US20080292960A1

公开(公告)日：2008-11-27

申请号：US11882497

申请日：2007-08-02

申请人： Shigeto Noya ,  Susumu Kato ,  Tadaya Okada ,  Takashi Mushiga

发明人： Shigeto Noya ,  Susumu Kato ,  Tadaya Okada ,  Takashi Mushiga

IPC分类号： H01M10/26

CPC分类号： C01G53/04 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/30 ,  C01P2006/11 ,  C01P2006/40 ,  H01M4/32 ,  H01M6/08 ,  H01M2004/021

摘要： In order to provide an alkaline dry battery having excellent heavy load discharge characteristics, suppressed polarization at the time of heavy load pulse discharge, and excellent heavy load discharge characteristics after high temperature storage, a nickel oxyhydroxide powder having a tap density of 2.1 to 2.7 g/cm3 and including non-spherical and sheet-like nickel oxyhydroxide particles is included in a positive electrode active material.

摘要翻译： 为了提供具有优异的重负荷放电特性的碱性干电池，在重负载脉冲放电时抑制的极化，以及高温保存后的优异的重负荷放电特性，振实密度为2.1〜2.7g的氢氧化镍粉末 / cm 3，并且包括非球形和片状氢氧化正镍颗粒在正极活性材料中。

公开(公告)号：US20070092789A1

公开(公告)日：2007-04-26

申请号：US11582444

申请日：2006-10-18

申请人： Tadaya Okada ,  Yasuhiko Shoji ,  Shigeto Noya

发明人： Tadaya Okada ,  Yasuhiko Shoji ,  Shigeto Noya

IPC分类号： H01M10/50 ,  H01M2/08

CPC分类号： H01M2/34 ,  H01M2/348 ,  H01M4/32 ,  H01M4/366 ,  H01M4/38 ,  H01M4/42 ,  H01M4/44 ,  H01M4/46 ,  H01M4/66 ,  H01M10/443 ,  H01M2004/028

摘要： An alkaline battery according to the present invention includes: a power generation element including a positive electrode, a negative electrode, a separator placed between the positive electrode and the negative electrode, and an electrolyte; a positive terminal portion electrically connected to the positive electrode; and a negative terminal portion electrically connected to the negative electrode. The positive electrode contains at least nickel oxyhydroxide powder as an active material. A PTC element is provided in a current path that does not come into contact with the electrolyte at least one of between the positive electrode and the positive terminal portion and between the negative electrode and the negative terminal portion.

摘要翻译： 根据本发明的碱性电池包括：发电元件，其包括正极，负极，置于正极和负极之间的隔板和电解质; 电连接到所述正极的正极端子部分; 以及与该负极电连接的负极端子部。 正极至少含有氢氧化正镍粉末作为活性物质。 PTC元件设置在电流路径中，其不与正极和正极端子部分之间以及负极和负极端子部分之间的至少一个电解质接触。

公开(公告)号：US20080063933A1

公开(公告)日：2008-03-13

申请号：US11793592

申请日：2006-04-05

申请人： Tadaya Okada ,  Shigeto Noya ,  Yasuo Mukai ,  Michiko Fujiwara ,  Hidekatsu Izumi

发明人： Tadaya Okada ,  Shigeto Noya ,  Yasuo Mukai ,  Michiko Fujiwara ,  Hidekatsu Izumi

IPC分类号： H01M2/16

CPC分类号： H01M6/08 ,  H01M4/02 ,  H01M4/244 ,  H01M4/32 ,  H01M4/364 ,  H01M4/42 ,  H01M4/50 ,  H01M4/625 ,  H01M10/30 ,  H01M2004/021

摘要： To provide an alkaline dry battery that is excellent in discharge characteristics under a heavy load after storage at high temperature and suppresses polarization in pulse discharge under a heavy load, used is a nickel oxyhydroxide which is obtained by oxidizing a nickel hydroxide having a half width of a (101) face of 0.6 to 0.8 deg./2θ and a half width of a (001) face of 0.5 to 0.7 deg./2θ in powder X-ray diffraction, and which has an average nickel valence of 2.95 or more and an average particle diameter of 8 to 18 μm.

摘要翻译： 为了提供在高温下储存后在重负荷下的放电特性优异的碱性干电池，并且在重负荷下抑制脉冲放电中的极化，使用的是氢氧化镍，其通过将具有半值宽度的氢氧化镍氧化 （101）面为0.6〜0.8度/2θ，粉末X射线衍射中（001）面的半宽度为0.5〜0.7度/2θ，平均镍价为2.95以上， 平均粒径为8〜18μm。

公开(公告)号：US20060166095A1

公开(公告)日：2006-07-27

申请号：US10562440

申请日：2005-02-17

申请人： Fumio Kato ,  Katsuya Sawada ,  Tadaya Okada ,  Yasuo Mukai ,  Shigeto Noya

发明人： Fumio Kato ,  Katsuya Sawada ,  Tadaya Okada ,  Yasuo Mukai ,  Shigeto Noya

IPC分类号： H01M4/32 ,  H01M4/50 ,  H01M4/62

CPC分类号： H01M4/08 ,  C01G31/006 ,  C01G53/00 ,  C01G53/04 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/42 ,  H01M4/50 ,  H01M4/52 ,  H01M4/62 ,  H01M4/625 ,  H01M6/04 ,  H01M2004/021

摘要： An alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, the positive electrode including a positive electrode material mixture containing a nickel oxyhydroxide, electrolytic manganese dioxide and a graphite conductive material, wherein the nickel oxyhydroxide includes a crystal having manganese dissolved therein and having a β type structure, and the amount of the manganese contained in the nickel oxyhydroxide is 0.5 to 10 mol % relative to the total amount of nickel and the manganese in the nickel oxyhydroxide.

摘要翻译： 包括正极，负极和碱性电解质的碱性电池，所述正极包括含有氢氧化正镍，电解二氧化锰和石墨导电材料的正极材料混合物，其中所述氢氧化镍包括其中溶解有锰的晶体 并且具有β型结构，并且在氢氧化正镍中所含的锰的量相对于镍的总量和羟基氧化镍中的锰为0.5〜10摩尔％。

公开(公告)号：US07569306B2

公开(公告)日：2009-08-04

申请号：US11587206

申请日：2005-03-24

申请人： Fumio Kato ,  Katsuya Sawada ,  Tadaya Okada ,  Yasuo Mukai ,  Shigeto Noya

发明人： Fumio Kato ,  Katsuya Sawada ,  Tadaya Okada ,  Yasuo Mukai ,  Shigeto Noya

IPC分类号： H01M4/52 ,  H01M4/08

CPC分类号： C01G53/00 ,  C01G53/04 ,  C01P2002/50 ,  C01P2002/74 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/02 ,  H01M4/06 ,  H01M4/52 ,  H01M6/06

摘要： An alkaline battery of the present invention includes a positive electrode material mixture including nickel oxyhydroxide. The nickel oxyhydroxide includes a secondary particle with a crystal structure mainly composed of γ-type at least a portion of the surface layer of the secondary particle, and with a crystal structure mainly composed of β-type in the inner portion of the secondary particle. Based on the present invention, the advantage of the alkaline battery, i.e., excellence in discharge performance under high-load, can be kept and the conventional problem of storage characteristics can be improved.

摘要翻译： 本发明的碱性电池包括含有氢氧化正镍的正极合剂混合物。 羟基氧化镍包括主要由γ型至少部分二次粒子的表面层构成的晶体结构的二次粒子，以及在二次粒子的内部主要由β型构成的晶体结构。 基于本发明，可以保持碱性电池的优点，即在高负载下的放电性能优异，并且可以提高传统的存储特性问题。

公开(公告)号：US20090098462A1

公开(公告)日：2009-04-16

申请号：US11919885

申请日：2006-08-25

申请人： Michiko Fujiwara ,  Tadaya Okada ,  Yasuo Mukai ,  Hidekatsu Izumi ,  Shigeto Noya

发明人： Michiko Fujiwara ,  Tadaya Okada ,  Yasuo Mukai ,  Hidekatsu Izumi ,  Shigeto Noya

IPC分类号： H01M4/32

CPC分类号： H01M4/32 ,  H01M4/24 ,  H01M4/364 ,  H01M4/42 ,  H01M4/62 ,  H01M6/08

摘要： In order to provide an alkaline dry battery which enables to improve the operational stability of digital equipment by suppressing the progress of polarization during heavy load pulse discharge while maintaining the excellent heavy load discharge characteristics, and has an excellent reliability in terms of the leakage resistance and the safety under short-circuit conditions, the alkaline dry battery includes a positive electrode including a nickel oxyhydroxide powder and a manganese dioxide powder as positive electrode active materials, and including graphite as a conductive material; a negative electrode including zinc or a zinc alloy as a negative electrode active material; a separator interposed between the positive electrode and the negative electrode; a negative electrode current collector inserted in the negative electrode; an aqueous alkaline solution included in the separator; a battery case housing the positive electrode, the negative electrode, the separator, the negative electrode current collector and the aqueous alkaline solution; a sealing member for sealing an opening of the battery case, wherein the positive electrode includes a calcium compound in an amount of 0.1 to 10 mol % relative to a total amount of the positive electrode active material, and the content of iron element in the calcium compound is 150 ppm or less.

摘要翻译： 为了提供一种碱性干电池，其能够通过抑制重负载脉冲放电期间的极化进行而提高数字设备的操作稳定性，同时保持优异的重负载放电特性，并且在耐漏电性方面具有优异的可靠性， 在短路条件下的安全性，碱性干电池包括含有氢氧化正镍粉末和二氧化锰粉末的正极作为正极活性物质，并且包括石墨作为导电材料; 包含锌或锌合金的负极作为负极活性物质; 夹在正极和负极之间的隔膜; 负极集电体插入负极中; 包含在隔膜中的碱性水溶液; 容纳正极，负极，隔膜，负极集电体和碱性水溶液的电池壳体; 用于密封电池壳体的开口的密封构件，其中所述正极包含相对于所述正极活性物质的总量为0.1〜10摩尔％的钙化合物，所述钙元素的含量 化合物为150ppm以下。

公开(公告)号：US07476466B2

公开(公告)日：2009-01-13

申请号：US11885663

申请日：2006-09-22

申请人： Hidekatsu Izumi ,  Tadaya Okada ,  Yasuo Mukai ,  Michiko Fujiwara ,  Shigeto Noya

发明人： Hidekatsu Izumi ,  Tadaya Okada ,  Yasuo Mukai ,  Michiko Fujiwara ,  Shigeto Noya

IPC分类号： H01M4/42 ,  H01M4/52 ,  H01M4/50

CPC分类号： H01M6/06 ,  H01M2/0235 ,  H01M4/02 ,  H01M4/244 ,  H01M4/32 ,  H01M4/364 ,  H01M4/381 ,  H01M4/42 ,  H01M4/48 ,  H01M4/50 ,  H01M4/52 ,  H01M4/62 ,  H01M4/625 ,  H01M6/08 ,  H01M10/30 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2004/023 ,  H01M2004/027

摘要： Provided is an alkaline dry battery allowing suppression of polarization in pulse discharge under heavy load to improve discharge characteristics, and having high reliability in safety in case of short circuit. In the positive electrode, a calcium compound having a content of iron element of 150 ppm or less is added in an amount of 0.1 to 10 mol % with respect to a positive electrode active material, a nickel oxyhydroxide powder having 2.95 or more of an average nickel valence and 8 to 18 μm of an average particle diameter is used, the weight ratio of the nickel oxyhydroxide powder and a manganese dioxide powder is in the range of 20:80 to 90:10. A zinc or zinc alloy powder used as negative electrode active material includes a first powder having a particle diameter more than 75 μm and 425 μm or less, and a second powder having a particle diameter more than 5 μm and 75 μm or less, and the weight ratio of the first powder and the second powder is in the range of 65:35 to 75:25, and the concentration of a potassium hydroxide solution is 33 to 35% by weight.

摘要翻译： 本发明提供一种碱性干电池，其能够抑制重负载下的脉冲放电中的极化，以改善放电特性，并且在短路的情况下具有高的安全可靠性。 在正极中，相对于正极活性物质，以铁元素含量为150ppm以下的钙化合物的添加量为0.1〜10摩尔％，羟基氧化镍粉末的平均值为2.95以上 使用镍价和8〜18μm的平均粒径，羟基氧化镍粉末和二氧化锰粉末的重量比在20:80〜90:10的范围内。 用作负极活性物质的锌或锌合金粉末包括粒径大于75μm和425μm或更小的第一粉末和粒径大于5μm和75μm或更小的第二粉末，并且 第一粉末和第二粉末的重量比在65:35〜75:25的范围内，氢氧化钾溶液的浓度为33〜35重量％。

公开(公告)号：US20070166614A1

公开(公告)日：2007-07-19

申请号：US10588036

申请日：2005-06-16

申请人： Fumio Kato ,  Katsuya Sawada ,  Tadaya Okada ,  Yasuo Mukai ,  Shigeto Noya

发明人： Fumio Kato ,  Katsuya Sawada ,  Tadaya Okada ,  Yasuo Mukai ,  Shigeto Noya

IPC分类号： H01M4/52 ,  H01M4/50

CPC分类号： H01M4/32 ,  C01G53/04 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/364 ,  H01M4/50 ,  H01M4/52 ,  H01M2004/021

摘要： Disclosed is an alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, (1) the positive electrode having a positive electrode material mixture containing electrolytic manganese doxide and nickel oxyhydroxide, (2) the nickel oxyhydroxide having a crystal in which at least Mg is dissolved, and (3) the nickel oxyhydroxide having a tap density determined after 500 taps of not less than 2 g/cm3, an average particle size based on volume of 8 to 20 μm, and an average nickel valence of 2.95 to 3.05.

摘要翻译： 公开了一种包括正极，负极和碱性电解质的碱性电池，（1）正极具有含有电解锰氧化锰和氢氧化正镍的正极材料混合物，（2）具有晶体的氢氧化正镍， 溶解最少量的Mg，（3）在500次抽头后测定的振实密度不小于2g / cm 3的氢氧化正镍，基于体积为8〜20μm的平均粒径， 平均镍价为2.95〜3.05。