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公开(公告)号:US5051434A
公开(公告)日:1991-09-24
申请号:US438543
申请日:1989-11-16
申请人: Shiokawa Kozo , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Shiokawa Kozo , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: C07D239/26 , A01N43/40 , A01N43/828 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/57 , C07D213/61 , C07D213/75 , C07D239/30 , C07D241/12 , C07D261/08 , C07D271/08 , C07D271/10 , C07D277/20 , C07D277/28 , C07D277/32 , C07D333/08 , C07D333/28 , C07D401/12 , C07D413/12 , C07D417/12 , C07D521/00
CPC分类号: C07D277/32 , A01N43/40 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/61 , H01L2924/01006 , H01L2924/01039
摘要: Insecticidal novel nitro compounds of the formula ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or C.sub.1-4 alkyl, R.sup.3 is --S--R.sup.4 or ##STR2## in which R.sup.4 is C.sub.1-4 alkyl, R.sup.5 and R.sup.6 are hydrogen or C.sub.1-4 alkyl,Y is CH or N, andZ is a five- or six-membered heterocyclic group having at least one nitrogen atom which may be substituted by halogen or C.sub.1-4 alkyl, provided that where Y is CH,then R.sup.1 is C.sub.1-4 alkyl.
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公开(公告)号:US5384324A
公开(公告)日:1995-01-24
申请号:US55402
申请日:1993-04-30
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Ikuro Honda , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Ikuro Honda , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: C07D237/08 , A01N47/40 , C07D213/38 , C07D213/40 , C07D213/61 , C07D213/74 , C07D231/12 , C07D239/26 , C07D239/30 , C07D241/12 , C07D261/08 , C07D263/34 , C07D271/10 , C07D277/20 , C07D277/28 , C07D277/32 , C07D333/28 , C07D521/00 , A01N43/78
CPC分类号: C07D213/40 , C07D213/61 , C07D239/26 , C07D241/12 , C07D277/32
摘要: A cyano compound useful as an insecticide, of the formula (I) ##STR1## wherein the radicals are defined in the claims.
摘要翻译: 用作杀虫剂的氰基化合物,式(I)其中基团在权利要求中定义。
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公开(公告)号:US5066808A
公开(公告)日:1991-11-19
申请号:US584398
申请日:1990-09-14
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Ikuro Honda , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Ikuro Honda , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: C07D237/08 , A01N47/40 , C07D213/38 , C07D213/40 , C07D213/61 , C07D213/74 , C07D231/12 , C07D239/26 , C07D239/30 , C07D241/12 , C07D261/08 , C07D263/34 , C07D271/10 , C07D277/20 , C07D277/28 , C07D277/32 , C07D333/28 , C07D521/00
CPC分类号: C07D213/40 , C07D213/61 , C07D239/26 , C07D241/12 , C07D277/32
摘要: A cyano compound useful as an insecticide, of the formula (I) ##STR1## wherein R.sup.1 is hydrogen, cyano or C.sub.1-4 alkyl, m is 0 or 1,R.sup.2 is hydrogen, C.sub.1-6 alkyl, C.sub.3-4 alkenyl optionally substituted by halogen,C.sub.3-4 alkynyl, C.sub.3-8 cycloalkyl optionally substituted by methyl, optionally substituted phenyl, optionally substituted benzyl, hydroxy, C.sub.1-4 alkoxy or --CH.sub.2 --Z, in which Z has the same meanings as stated below,R.sup.3 is ##STR2## in which R.sup.4 is C.sub.1-6 alkyl, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, C.sub.3-8 cycloalkyl, optionally substituted phenyl, optionally substituted benzyl or --(CH.sub.2)n-Z, in which n is 1 or 2 andZ has the same meanings as stated below, andR.sup.5 and R.sup.6 are hydrogen, C.sub.1-9 alkyl optionally substituted by at least one selected from a group consisting of halogen, hydroxy, mercapto, C.sub.1-2 alkoxy, C.sub.1-2 alkylthio, C.sub.3-6 cycloalkyl, amino, C.sub.1-2 monoalkylamino, C.sub.2-4 (in total)di-alkylamino, carboxy, C.sub.1-2 alkoxy-carbonyl and cyano, C.sub.3-4 alkenyl optionally substituted by halogen, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl, C.sub.1-4 alkoxy, hydroxy, formyl, C.sub.1-4 alkoxy-carbonyl, C.sub.1-4 alkylamino, C.sub.2-4 (in total)di-alkylamino, amino, acyl or ##STR3## in which R.sup.1 and m have the same meanings as stated above, and Z has the same meanings as stated below, and in addition,R.sup.5 and R.sup.6 may form, together with the N-atom to which they are bonded, a 3 to 7 membered ring which may be substituted by C.sub.1-2 alkyl and may contain N, O or S as the member of said ring, besides the N-atom to which they are bonded, andZ is a substituted 5 or 6 membered heterocyclic group which contains at least one heteroatom selected from N, O and S as a ring member, provided that where Z is pyridyl substituted by halogen, m is 1, R.sup.2 is C.sub.1-6 alkyl and R.sup.3 is --S--alkyl(C.sub.1-6) or --S--benzyl, then R.sup.1 is cyano or C.sub.1-4 alkyl.
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公开(公告)号:US5719146A
公开(公告)日:1998-02-17
申请号:US597780
申请日:1996-02-07
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: A01N43/64 , A01N43/653 , A01N43/72 , A01N43/80 , A01N43/832 , A01N43/836 , A01N43/84 , A01N43/88 , A01N47/40 , A01N51/00 , C07D401/06 , C07D401/14 , C07D403/06 , C07D405/06 , C07D409/06 , C07D413/06 , C07D417/06 , C07D419/06
CPC分类号: C07D401/06 , A01N47/40 , A01N51/00 , C07D401/14 , C07D403/06 , C07D405/06 , C07D409/06 , C07D413/06 , C07D417/06 , C07D419/06
摘要: Insecticidal heterocyclic compounds of the formula ##STR1## wherein A represents a five-membered or six-membered heteroaryl group containing one to three hetero atoms selected from the group consisting of S, O and N, said heteroaryl group being unsubstituted or substituted by a halogen atom or C.sub.1-4 alkyl group, Z represents a three-membered straight chain, each member being selected from the group consisting of CH.sub.2 --, O, S and N--R.sup.2 with at least one of said three members being O, S or N--R.sup.2, E represents CH.sub.2, O, S or N--R.sup.2, wherein R.sup.2 represents a hydrogen atom, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group or the group ##STR2## wherein R.sup.3 represents a hydrogen atom or halogen atom, X represents CH or N, Y represents a nitro group or cyano group, and R.sup.1 represents a hydrogen atom or methyl group.
摘要翻译: 式(I)的杀虫杂环化合物其中A表示含有1-3个选自S,O和N的杂原子的五元或六元杂芳基,所述杂芳基是未取代或取代的 通过卤原子或C 1-4烷基,Z表示三元直链,每个成员选自CH 2 - ,O,S和N-R 2,所述三个成员中的至少一个为O, S或N-R2,E表示CH 2,O,S或N-R 2,其中R 2表示氢原子,C 1-4烷基,C 1-4烷氧基或基团,其中R 3表示氢原子 或卤原子,X表示CH或N,Y表示硝基或氰基,R 1表示氢原子或甲基。
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公开(公告)号:US5314897A
公开(公告)日:1994-05-24
申请号:US90566
申请日:1993-07-12
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: C07D239/48 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/60 , A01N43/647 , A01N43/78 , A01N43/80 , A01N43/82 , A01N43/824 , A01N47/18 , C07D213/61 , C07D213/74 , C07D213/79 , C07D239/06 , C07D401/04 , C07D401/12 , C07D401/14 , C07D403/12 , C07D407/12 , C07D413/12 , C07D417/12
CPC分类号: C07D401/14 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/60 , A01N43/647 , A01N43/78 , A01N43/80 , A01N43/82 , A01N47/18 , C07D213/74 , C07D239/06 , C07D401/12 , C07D417/12
摘要: Insecticidal nitro-substituted heterocyclic compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen, cyano or C.sub.1-4 alkyl,m represents 0 or 1,n represents 0 or 1,R.sup.2 represents hydrogen or C.sub.1-4 alkyl,R.sup.3 represents hydrogen, C.sub.1-6 alkyl optionally substituted substituted by cyano, halogen or C.sub.1-4 alkoxy, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl or optionally substituted heterocyclic-methyl,T represents an optionally substituted two- or three-membered divalent or trivalent chain comprising hetero atoms and/or carbon atom, andA represents optionally substituted phenyl or an optionally substituted five- or six-membered heterocyclic radical comprising at least one hetero atom selected from the group consisting of N, O and S.
摘要翻译: 式(I)的杀虫硝基取代的杂环化合物,其中R1表示氢,氰基或C1-4烷基,m表示0或1,n表示0或1,R2表示氢或C1-4烷基,R3表示 氢,任选被氰基,卤素或C 1-4烷氧基取代的C 1-6烷基,C 3-4烯基,C 3-4炔基,任选取代的苯基,任选取代的苄基或任选取代的杂环甲基,T代表任选取代的二价基团, 或包含杂原子和/或碳原子的三元二价或三价链,并且A表示任选取代的苯基或任选取代的五元或六元杂环基,其包含至少一个选自N,O 和S.
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公开(公告)号:US5032589A
公开(公告)日:1991-07-16
申请号:US487004
申请日:1990-03-01
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: A01N43/64 , A01N43/653 , A01N43/72 , A01N43/80 , A01N43/832 , A01N43/836 , A01N43/84 , A01N43/88 , A01N47/40 , A01N51/00 , C07D401/06 , C07D401/14 , C07D403/06 , C07D405/06 , C07D409/06 , C07D413/06 , C07D417/06 , C07D419/06
CPC分类号: C07D401/06 , A01N47/40 , A01N51/00 , C07D401/14 , C07D403/06 , C07D405/06 , C07D409/06 , C07D413/06 , C07D417/06 , C07D419/06
摘要: Insecticidal heterocyclic compounds of the formula ##STR1## wherein A represents a five-membered or six-membered heteroaryl group containing one to three hetero atoms selected from the group consisting of S, O and N, said heteroaryl group being unsubstituted or substituted by a halogen atom or C.sub.1-4 alkyl group, Z represents a three-membered straight chain, each member being selected from the group consisting of CH.sub.2 --, O, S and N--R.sup.2 with at least one of said three members being O, S or N--R.sup.2, E represents CH.sub.2, O, S or N--R.sup.2 wherein R.sup.2 represents a hydrogen atom, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group or the group ##STR2## wherein R.sup.3 represents a hydrogen atom or halogen atom, X represents CH or N, Y represents a nitro group or cyano group, and R.sup.1 represents a hydrogen atom or methyl group.
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公开(公告)号:US5238949A
公开(公告)日:1993-08-24
申请号:US527217
申请日:1990-05-22
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: A01N43/40 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/61 , C07D277/32
CPC分类号: C07D277/32 , A01N43/40 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/61 , H01L2924/01006 , H01L2924/01039
摘要: Insecticidal novel nitro compounds of the formula ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or C.sub.1-4 alkyl,R.sup.3 is -S-R.sup.4 or ##STR2## in which R.sup.4 is C.sub.1-4 alkyl, R.sup.5 and R.sup.6 are hydrogen or C.sub.1-4 alkyl,Y is CH or N, andZ is a five- or six-membered heterocyclic group having at least one nitrogen atom which may be substituted by halogen or C.sub.1-4 alkyl, provided that where Y is CH, then R.sup.1 is C.sub.1-4 alkyl.
摘要翻译: 其中R 1和R 2是氢或C 1-4烷基,R 3是-S-R 4或其中R 4是C 1-4烷基,R 5和R 6的R 1是氢或C 1 -C 4烷基的杀虫新型硝基化合物, 4烷基,Y是CH或N,Z是具有至少一个可被卤素或C 1-4烷基取代的氮原子的五元或六元杂环基,条件是其中Y是CH,则R1是C1 -4-烷基。
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公开(公告)号:US5219869A
公开(公告)日:1993-06-15
申请号:US943950
申请日:1992-09-11
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: A01N43/40 , A01N43/54 , A01N43/78 , C07D213/74 , C07D239/06 , C07D401/12 , C07D401/14 , C07D417/12
CPC分类号: C07D213/74 , A01N43/40 , A01N43/54 , A01N43/78 , C07D239/06 , C07D401/12 , C07D401/14 , C07D417/12
摘要: Insecticidal nitro-substituted heterocyclic compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen, cyano or C.sub.1-4 alkyl,m represents 0 or 1,n represents 0 or 1,R.sup.2 represents hydrogen or C.sub.1-4 alkyl,R.sup.3 represents hydrogen, C.sub.1-6 alkyl optionally substituted substituted by cyano, halogen or C.sub.1-4 alkoxy, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl or optionally substituted heterocyclic-methyl,T represents an optionally substituted two- or three-membered divalent or trivalent chain comprising hetero atoms and/or carbon atom, andA represents optionally substituted phenyl or an optionally substituted five- or six-membered heterocyclic radical comprising at least one hetero atom selected from the group consisting of N, O and S.
摘要翻译: 式(I)的杀虫硝基取代的杂环化合物,其中R1表示氢,氰基或C1-4烷基,m表示0或1,n表示0或1,R2表示氢或C1-4烷基,R3表示 氢,任选被氰基,卤素或C 1-4烷氧基取代的C 1-6烷基,C 3-4烯基,C 3-4炔基,任选取代的苯基,任选取代的苄基或任选取代的杂环甲基,T代表任选取代的二价基团, 或包含杂原子和/或碳原子的三元二价或三价链,并且A表示任选取代的苯基或任选取代的五元或六元杂环基,其包含至少一个选自N,O 和S.
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公开(公告)号:US5204359A
公开(公告)日:1993-04-20
申请号:US757864
申请日:1991-09-11
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: A01N43/40 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/61 , C07D277/32
CPC分类号: C07D277/32 , A01N43/40 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/61 , H01L2924/01006 , H01L2924/01039
摘要: Insecticidally active nitro compounds of the formula ##STR1## wherein R.sup.1 is hydrogen, cyano or alkyl,R.sup.2 is hydrogen or an organic radical,R.sup.3 is ##STR2## R.sup.4 is an organic radical, R.sup.5 and R.sup.6 are hydrogen or organic radicals,Y is CH or N, andZ is an optionally substituted 5- or 6-membered heterocyclic group,with certain conditions and exceptions.
摘要翻译: 式(I)的杀虫活性硝基化合物其中R 1是氢,氰基或烷基,R 2是氢或有机基团,R 3是有机基团,R 5和R 6是氢或有机基团, Y是CH或N,Z是任选取代的5或6元杂环基,具有某些条件和例外。
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公开(公告)号:USRE35811E
公开(公告)日:1998-05-26
申请号:US538756
申请日:1995-10-03
申请人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Koichi Moriya , Yumi Hattori , Ikuro Honda , Katsuhiko Shibuya
IPC分类号: C07D239/26 , A01N43/40 , A01N43/828 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/57 , C07D213/61 , C07D213/75 , C07D239/30 , C07D241/12 , C07D261/08 , C07D271/08 , C07D271/10 , C07D277/20 , C07D277/28 , C07D277/32 , C07D333/08 , C07D333/28 , C07D401/12 , C07D413/12 , C07D417/12 , C07D521/00
CPC分类号: C07D277/32 , A01N43/40 , A01N47/42 , A01N47/44 , C07D213/38 , C07D213/61 , H01L2924/01006 , H01L2924/01039
摘要: Insecticidal novel nitro compounds of the formula ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or C.sub.1-4 alkyl, R.sup.3 is --S--R.sup.4 or ##STR2## in which R.sup.4 is C.sub.1-4 alkyl, R.sup.5 and R.sup.6 are hydrogen or C.sub.1-4 alkyl, Y is CH or N, and Z is a five- or six-membered heterocyclic group having at least one nitrogen atom which may be substituted by halogen or C.sub.1-4 alkyl, provided that where Y is CH, then R.sup.1 is C.sub.1-4 alkyl.
摘要翻译: 式4烷基的杀虫新型硝基化合物,R 3为-S-R 4或其中R 4为C 1-4烷基,R 5和R 6为氢或C 1-4烷基,Y为CH或N,且Z为 具有至少一个可被卤素或C 1-4烷基取代的氮原子的五元或六元杂环基,条件是其中Y为CH,则R 1为C 1-4烷基。
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