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公开(公告)号：US09290422B2
公开(公告)日：2016-03-22
申请号：US13686328
申请日：2012-11-27
IPC分类号： C07C27/00 , C07C1/12 , C07C29/151 , C10K3/06 , C10G2/00 , C10K1/00 , C01B3/38 , C10J3/72 , C10K3/04
CPC分类号： C07C1/12 , C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/043 , C01B2203/0475 , C01B2203/062 , C01B2203/0811 , C01B2203/1241 , C01B2203/1258 , C01B2203/142 , C01B2203/148 , C07C29/1518 , C10G2/30 , C10J3/721 , C10J2300/1659 , C10J2300/1665 , C10J2300/1678 , C10J2300/1815 , C10J2300/1838 , C10K1/003 , C10K1/005 , C10K3/04 , C10K3/06 , C07C31/04
摘要： A hybrid plant and method for producing liquid fuel product from hydrogen and carbon monoxide containing streams produced by gasifying solid carbonaceous feedstock and steam reforming of light fossil fuels. When a gasification unit in the hybrid plant is operating at reduced capacity or is not operational, oxygen that would have been used in the gasification unit is diverted to a light fossil fuel conversion unit containing an autothermal reformer to increase H2-rich syngas flow to a liquid fuel production unit and maintain liquid fuel production at near nameplate capacity.
摘要翻译： 一种用于通过气化固体碳质原料和轻化石燃料的蒸汽重整产生的氢气和一氧化碳的液体产生液体燃料产物的混合设备和方法。 当混合设备中的气化单元以降低的能力运行或不可操作时，将在气化单元中使用的氧转移到含有自热重整器的轻化石燃料转化单元，以将富H2合成气流增加到 液体燃料生产单元，并保持液体燃料生产接近铭牌能力。
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公开(公告)号：US20150005398A1
公开(公告)日：2015-01-01
申请号：US13927880
申请日：2013-06-26
CPC分类号： C10K1/004 , C01B3/24 , C01B3/38 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C01B2203/0816 , C01B2203/1241 , C01B2203/141 , C01B2203/142 , C10G2/30 , C10J3/00 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/0959 , C10J2300/0969 , C10J2300/0976 , C10J2300/1659 , C10J2300/1678 , C10K1/005 , C10K3/06 , Y02E20/18 , Y02P20/145
摘要： A process and method for producing liquid fuel product from hydrogen and carbon monoxide containing streams produced by gasifying solid carbonaceous feedstock and steam reforming of light fossil fuels. The gasifier syngas is treated to preferentially remove at least 99% of sulfur containing impurities and less than 50% of the CO2 to produce a treated gasifier syngas and a CO2 enriched gas. The treated gasifier syngas and the light fossil fuel conversion unit product gas are combined to form a mixed syngas that is converted into a liquid fuel product. The CO2 enriched gas is used in the gasification unit.
摘要翻译： 一种用于通过气化固体碳质原料和轻化石燃料的蒸汽重整产生的含氢气和一氧化碳的液体生产液体燃料产品的方法和方法。 处理气化器合成气以优先除去至少99％的含硫杂质和少于50％的CO 2，以产生经处理的气化器合成气和富含CO 2的气体。 经处理的气化器合成气和轻化石燃料转化装置产物气体合并形成混合合成气，其被转化为液体燃料产物。 在气化单元中使用富含CO 2的气体。
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3.发明申请METHOD AND SYSTEM FOR PRODUCING A SYNTHESIS GAS USING AN OXYGEN TRANSPORT MEMBRANE BASED REFORMING SYSTEM WITH SECONDARY REFORMING AND AUXILIARY HEAT SOURCE 有权使用具有二次改造和辅助热源的基于氧气运输膜的改造系统生产合成气的方法和系统公开(公告)号：US20140323598A1
公开(公告)日：2014-10-30
申请号：US14261781
申请日：2014-04-25
IPC分类号： C07C29/151 , C07C29/152 , C01B3/02
CPC分类号： C01B3/384 , B01J19/245 , B01J19/2475 , B01J2219/00121 , B01J2219/00157 , B01J2219/24 , C01B3/02 , C01B3/382 , C01B3/386 , C01B13/0251 , C01B2203/0227 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/0822 , C01B2203/0827 , C01B2203/0838 , C01B2203/1235 , C01B2203/142 , C07C29/1518 , Y02P20/128 , C07C31/04
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out a primary reforming process within a reforming reactor, and a secondary reforming process within an oxygen transport membrane reactor and in the presence of heat generated from a oxygen transport membrane reactor and an auxiliary source of heat. The auxiliary source of heat is disposed within the reactor housing proximate the reforming reactors and may include an auxiliary reactively driven oxygen transport membrane reactor or a ceramic burner.
摘要翻译： 公开了一种在基于氧传输膜的重整系统中生产合成气的方法和系统，其在重整反应器内进行初级重整过程，并在氧传输膜反应器内进行二次重整过程，并在存在由 氧传输膜反应器和辅助热源。 辅助热源在反应器壳体内靠近重整反应器设置，并且可以包括辅助的反应式驱动氧传输膜反应器或陶瓷燃烧器。
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公开(公告)号：US09145525B2
公开(公告)日：2015-09-29
申请号：US13927880
申请日：2013-06-26
CPC分类号： C10K1/004 , C01B3/24 , C01B3/38 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C01B2203/0816 , C01B2203/1241 , C01B2203/141 , C01B2203/142 , C10G2/30 , C10J3/00 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/0959 , C10J2300/0969 , C10J2300/0976 , C10J2300/1659 , C10J2300/1678 , C10K1/005 , C10K3/06 , Y02E20/18 , Y02P20/145
摘要： A process and method for producing liquid fuel product from hydrogen and carbon monoxide containing streams produced by gasifying solid carbonaceous feedstock and steam reforming of light fossil fuels. The gasifier syngas is treated to preferentially remove at least 99% of sulfur containing impurities and less than 50% of the CO2 to produce a treated gasifier syngas and a CO2 enriched gas. The treated gasifier syngas and the light fossil fuel conversion unit product gas are combined to form a mixed syngas that is converted into a liquid fuel product. The CO2 enriched gas is used in the gasification unit.
摘要翻译： 一种用于通过气化固体碳质原料和轻化石燃料的蒸汽重整产生的含氢气和一氧化碳的液体生产液体燃料产品的方法和方法。 处理气化器合成气以优先除去至少99％的含硫杂质和少于50％的CO 2，以产生经处理的气化器合成气和富含CO 2的气体。 经处理的气化器合成气和轻化石燃料转化装置产物气体合并形成混合合成气，其被转化为液体燃料产物。 在气化单元中使用富含CO 2的气体。
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公开(公告)号：US10005664B2
公开(公告)日：2018-06-26
申请号：US14936194
申请日：2015-11-09
IPC分类号： C01B3/38 , B01J19/24 , C07C29/151 , C01B3/02 , C01B13/02
CPC分类号： C01B3/384 , B01J19/245 , B01J19/2475 , B01J2219/00121 , B01J2219/00157 , B01J2219/24 , C01B3/02 , C01B3/382 , C01B3/386 , C01B13/0251 , C01B2203/0227 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/0822 , C01B2203/0827 , C01B2203/0838 , C01B2203/1235 , C01B2203/142 , C07C29/1518 , Y02P20/128 , C07C31/04
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out a primary reforming process within a reforming reactor, and a secondary reforming process within an oxygen transport membrane reactor and in the presence of heat generated from a oxygen transport membrane reactor and an auxiliary source of heat. The auxiliary source of heat is disposed within the reactor housing proximate the reforming reactors and may include an auxiliary reactively driven oxygen transport membrane reactor or a ceramic burner.
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6.发明授权Method and system for producing hydrogen using an oxygen transport membrane based reforming system with secondary reforming 有权使用具有二次重整的基于氧传输膜的重整系统来生产氢的方法和系统公开(公告)号：US09556027B2
公开(公告)日：2017-01-31
申请号：US14556833
申请日：2014-12-01
CPC分类号： C01B3/48 , B01J8/067 , B01J19/245 , B01J19/2475 , B01J2219/00051 , B01J2219/00157 , B01J2219/24 , C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/042 , C01B2203/0811 , C01B2203/0838 , C01B2203/0844 , C01B2203/1235 , C01B2203/142 , C01B2203/143 , C01B2203/1623
摘要： A method and system for producing hydrogen using an oxygen transport membrane based reforming system is disclosed that carries out a primary reforming process within a reforming reactor, and a secondary reforming process within a reactively driven and catalyst containing oxygen transport membrane reactor with or without an auxiliary source of heat to support primary reforming process within the reforming reactor to first form a synthesis gas product. The auxiliary source of heat is disposed within the oxygen transport membrane based reforming system proximate to the reforming reactors and comprises an auxiliary oxygen transport membrane reactor or a ceramic burner. The synthesis gas product is further treated in a separate high temperature water gas shift reactor and optionally in a separate low temperature water gas shift reactor. Hydrogen is produced from the resulting hydrogen-enriched gas using hydrogen PSA.
摘要翻译： 公开了一种使用基于氧传输膜的重整系统来生产氢的方法和系统，其在重整反应器内进行一次重整过程，以及在具有或不具有辅助的反应驱动和含催化剂的氧输送膜反应器内进行二次重整过程 热源以支持重整反应器内的初级重整工艺，以首先形成合成气产物。 辅助热源设置在靠近重整反应器的氧传输膜基重整系统内，并且包括辅助氧传输膜反应器或陶瓷燃烧器。 合成气产物在单独的高温水煤气变换反应器中进一步处理，并且任选地在单独的低温水煤气变换反应器中进行处理。 使用氢PSA从产生的富氢气体中产生氢。
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7.发明申请METHOD AND SYSTEM FOR PRODUCING A SYNTHESIS GAS USING AN OXYGEN TRANSPORT MEMBRANE BASED REFORMING SYSTEM WITH SECONDARY REFORMING AND AUXILIARY HEAT SOURCE 有权使用具有二次改造和辅助热源的基于氧气运输膜的改造系统生产合成气的方法和系统公开(公告)号：US20160060109A1
公开(公告)日：2016-03-03
申请号：US14936194
申请日：2015-11-09
CPC分类号： C01B3/384 , B01J19/245 , B01J19/2475 , B01J2219/00121 , B01J2219/00157 , B01J2219/24 , C01B3/02 , C01B3/382 , C01B3/386 , C01B13/0251 , C01B2203/0227 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/0822 , C01B2203/0827 , C01B2203/0838 , C01B2203/1235 , C01B2203/142 , C07C29/1518 , Y02P20/128 , C07C31/04
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out a primary reforming process within a reforming reactor, and a secondary reforming process within an oxygen transport membrane reactor and in the presence of heat generated from a oxygen transport membrane reactor and an auxiliary source of heat. The auxiliary source of heat is disposed within the reactor housing proximate the reforming reactors and may include an auxiliary reactively driven oxygen transport membrane reactor or a ceramic burner.
摘要翻译： 公开了一种在基于氧传输膜的重整系统中生产合成气的方法和系统，其在重整反应器内进行初级重整过程，并在氧传输膜反应器内进行二次重整过程，并在存在由 氧传输膜反应器和辅助热源。 辅助热源在反应器壳体内靠近重整反应器设置，并且可以包括辅助的反应式驱动氧传输膜反应器或陶瓷燃烧器。
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8.发明授权Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source 有权使用具有二次重整和辅助热源的基于氧传输膜的重整系统来生产合成气的方法和系统公开(公告)号：US09212113B2
公开(公告)日：2015-12-15
申请号：US14261781
申请日：2014-04-25
IPC分类号： C07C29/151 , C07C29/152 , C01B3/02 , C01B3/38 , C01B13/02
CPC分类号： C01B3/384 , B01J19/245 , B01J19/2475 , B01J2219/00121 , B01J2219/00157 , B01J2219/24 , C01B3/02 , C01B3/382 , C01B3/386 , C01B13/0251 , C01B2203/0227 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/0822 , C01B2203/0827 , C01B2203/0838 , C01B2203/1235 , C01B2203/142 , C07C29/1518 , Y02P20/128 , C07C31/04
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out a primary reforming process within a reforming reactor, and a secondary reforming process within an oxygen transport membrane reactor and in the presence of heat generated from a oxygen transport membrane reactor and an auxiliary source of heat. The auxiliary source of heat is disposed within the reactor housing proximate the reforming reactors and may include an auxiliary reactively driven oxygen transport membrane reactor or a ceramic burner.
摘要翻译： 公开了一种在基于氧传输膜的重整系统中生产合成气的方法和系统，其在重整反应器内进行初级重整过程，并在氧传输膜反应器内进行二次重整过程，并在存在由 氧传输膜反应器和辅助热源。 辅助热源在反应器壳体内靠近重整反应器设置，并且可以包括辅助的反应式驱动氧传输膜反应器或陶瓷燃烧器。
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9.发明申请METHOD AND SYSTEM FOR PRODUCING A LIQUID HYDROCARBON PRODUCT FROM A FISCHER-TROPSCH PROCESS USING A SYNTHESIS GAS PRODUCED FROM AN OXYGEN TRANSPORT MEMBRANE BASED REFORMING REACTOR 有权使用由氧气输送膜生产的合成气基于改性反应器的FISCHER-TROPSCH工艺生产液体烃产品的方法和系统公开(公告)号：US20150251967A1
公开(公告)日：2015-09-10
申请号：US14638344
申请日：2015-03-04
CPC分类号： C07C1/04 , C01B3/382 , C01B3/384 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/0255 , C01B2203/062 , C01B2203/0811 , C01B2203/0838 , C01B2203/0844 , C01B2203/1241 , C01B2203/142
摘要： A system and method for producing a liquid hydrocarbon product from a Fischer-Tropsch process using a synthesis gas feed produced in an oxygen transport membrane based reforming reactor. The system and method involve reforming a mixed feed stream comprising natural gas, hydrogen and the Fischer-Tropsch tail gas, in a reforming reactor in the presence of steam, radiant heat from oxygen transport membrane elements and a reforming catalyst to produce a reformed synthesis gas stream comprising hydrogen, carbon monoxide, and unreformed hydrocarbon gas. The reformed synthesis gas stream is further reformed in an oxygen transport membrane based reforming reactor and conditioned to produce a synthesis gas product stream preferably having a H2/CO ratio of from about 1.7 to about 2.2. The synthesis gas product stream is then synthesized using a Fischer Tropsch process to produce the liquid hydrocarbon product and a Fischer-Tropsch tail gas.
摘要翻译： 一种使用在基于氧传输膜的重整反应器中生产的合成气进料从费 - 托方法生产液体烃产物的系统和方法。 该系统和方法包括在重整反应器中，在蒸汽存在的情况下重整包含天然气，氢气和费 - 托尾气的混合进料流，以及来自氧传输膜元件的辐射热和重整催化剂，以产生重整合成气 包含氢气，一氧化碳和未重整的烃气体。 将改性的合成气流在氧传输膜基重整反应器中进一步重整，并调节以产生优选具有约1.7至约2.2的H 2 / CO比的合成气产物流。 然后使用费托法合成合成气产物流，以产生液体烃产物和费 - 托尾气。
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公开(公告)号：US10787615B2
公开(公告)日：2020-09-29
申请号：US14166304
申请日：2014-01-28
摘要： The present invention relates to a method and system for treating a flow back fluid exiting a well site following stimulation of a subterranean formation. More specifically, the invention relates to processing the flow back fluid, and separating into a carbon dioxide rich stream and a carbon dioxide depleted stream, and continuing the separation until the carbon dioxide concentration in the flow back stream until the carbon dioxide concentration in the flow back gas diminishes to a point selected in a range of about 50-80 mol % in carbon dioxide concentration, after which the lower concentration carbon dioxide flow back stream continues to be separated into a carbon dioxide rich stream which is routed to waste or flare, and a hydrocarbon rich stream is formed.
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