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公开(公告)号：US4798664A
公开(公告)日：1989-01-17
申请号：US946089
申请日：1986-12-24
IPC分类号： G01N27/26 , G01N27/30 , G01N27/333
CPC分类号： G01N27/3335
摘要： Disclosed is a solid-type ion sensor which does not have an internal liquid chamber. The ion sensor has a laminated structure basically includes an electrically conductive substrate, a redox layer having a redox function covering the surface of the electrically conductive substrate, and an ion-selective layer covering the surface of the redox layer. Also provided is an ion sensor of this type having an insulated thermister imbedded so as to contact the redox layer.
摘要翻译： 公开了一种不具有内部液体室的固体离子传感器。 离子传感器具有层叠结构，主要包括导电性基板，覆盖导电性基板表面的氧化还原功能的氧化还原层和覆盖氧化还原层表面的离子选择层。 还提供了这种类型的离子传感器，其具有嵌入以与氧化还原层接触的绝缘热敏电阻。
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公开(公告)号：US5190636A
公开(公告)日：1993-03-02
申请号：US602230
申请日：1990-10-24
IPC分类号： G01N27/02 , G01N27/333
CPC分类号： G01N27/3335
摘要： The present invention provides an ion sensitive film (6) comprising a mixed layer containing a redox manifesting substance manifesting redox function and a polymeric compound containing an ion carrier substance. The present invention also provides a method of producing the ion sensitive film (6) and an ion sensor which uses the film (6). The ion sensitive film (6) of the present invention enables the provision of an ion sensor having excellent durability, preservative stability and sensor characteristics.
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公开(公告)号：US4507194A
公开(公告)日：1985-03-26
申请号：US518354
申请日：1983-07-29
IPC分类号： A61B5/145 , A61B5/1468 , A61B5/1486 , G01N27/30 , G01N27/40
CPC分类号： G01N27/301
摘要： A reference electrode is prepared by coating the surface of a conductive substrate with a silver complex polymer compound, which is either a compound prepared by the complex formation between a polymer compound containing a coordination nitrogen atom and a silver ion or an aforementioned complex compound containing a silver halide. This reference electrode can be used by a combination with ion sensor, a pH sensor and so on.
摘要翻译： 参考电极是通过用银络合物聚合物化合物涂覆导电性基材的表面来制备的，所述银络合物聚合物化合物是通过在配位氮原子的高分子化合物与银离子之间的络合物形成而制备的化合物或前述的含有 卤化银 该参比电极可以与离子传感器，pH传感器等组合使用。
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公开(公告)号：US5139626A
公开(公告)日：1992-08-18
申请号：US607856
申请日：1990-10-31
IPC分类号： G01N27/403 , G01N27/49
CPC分类号： G01N27/48 , G01N27/4035
摘要： An electrochemical cell is formed by immersing an electrochemical ion sensor and a reference electrode into a solution of interest, the electrochemical ion sensor exhibiting ion selectivity with respect to an ion of interest and having a high electrode resistance. A current which flows through the electrochemical cell is measured while the potential of the electrochemical ion sensor is held to a constant potential with respect to the reference electrode. The current so obtained are proportional to the logarithm value of the concentration of the ion.
摘要翻译： 通过将电化学离子传感器和参考电极浸入感兴趣的溶液中形成电化学电池，所述电化学离子传感器相对于感兴趣的离子表现出离子选择性并具有高电极电阻。 测量流过电化学电池的电流，同时电化学离子传感器的电位相对于参考电极保持恒定电位。 如此获得的电流与离子浓度的对数值成比例。
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公开(公告)号：US5126937A
公开(公告)日：1992-06-30
申请号：US626413
申请日：1990-12-14
IPC分类号： A61B5/145 , A61B5/00 , G01N33/487 , G01N33/49
CPC分类号： A61B5/14539 , A61B5/145 , G01N33/492
摘要： A biological information measurement apparatus is adapted to measure biological information in an extracorporeal circuration or in a living body by various measurement circuits comprising circuit elements which are not affected by electrical disturbances, and to transmit the results of measurement in the form of a non-electrical signal which is not affected by electrical disturbances. Measured values from measurement sections are gathered at a central processing section separated from the measurement sections. The processing section converts the measured values into output values, compensates the values for temperature and outputs the values to a display unit and recorder.
摘要翻译： 生物信息测量装置适于通过包括不受电扰动影响的电路元件的各种测量电路来测量体外循环或生物体内的生物信息，并以非电气形式传输测量结果 信号不受电气干扰影响。 来自测量部分的测量值在与测量部分分离的中央处理部分收集。 处理部分将测量值转换为输出值，补偿温度值并将其输出到显示单元和记录器。
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公开(公告)号：US5071537A
公开(公告)日：1991-12-10
申请号：US298744
申请日：1989-05-08
IPC分类号： G01N27/30
CPC分类号： G01N27/301
摘要： A miniature, solid-state long-life reference electrode in which the amount of outflow of an internal electrolyte containing a halogen ion is reduced includes a conductor on the periphery of which is formed a sintered body consisting of a silver halide and silver oxide, a water-containing gel enveloping the conductor and including a halogen ion electrolyte, and a hollow tubular body closed by a liquid-junction portion comprising a porous ceramic, or by a partitioning wall having an ion permeable portion of a predetermined diffusion coefficient and volume. In another embodiment, the tubular body of the reference electrode is partitioned by a partitioning wall having an ion permeable portion of a predetermined diffusion coefficient and volume.
摘要翻译： PCT No.PCT / JP87 / 00491 Sec。 371日期1989年5月8日 102（e）日期1989年5月8日PCT提交1987年7月9日PCT公布。 出版物WO88 / 00700 日期：1988年1月28日。一种微型固态长寿命参比电极，其中包含卤素离子的内部电解质的流出量减少包括其周边的导体形成为由 卤化银和氧化银，包封导体并含有卤素离子电解质的含水凝胶，以及由包含多孔陶瓷的液体接合部分封闭的中空管状体，或通过具有离子渗透部分的分隔壁 预定的扩散系数和体积。 在另一个实施例中，参考电极的管体由具有预定扩散系数和体积的离子可渗透部分的分隔壁分隔。
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公开(公告)号：US5133856A
公开(公告)日：1992-07-28
申请号：US577050
申请日：1990-09-04
IPC分类号： G01N27/333
CPC分类号： G01N27/3335
摘要： An ion sensor of the type wherein a specific type of ion in an aqueous solution is measured by potential response. The sensor includes a conductor base, and a reversible redox polymer film formed directly on a surface of said conductor base. An ion carrier film is formed directly on a surface of said redox polymer film. The carrier film contains an ion carrier substance for allowing the specific type of ions to permeate from the aqueous solution to said polymer film.
摘要翻译： 其中通过潜在响应测量水溶液中特定类型的离子的离子传感器。 传感器包括导体基底和直接形成在所述导体基底的表面上的可逆的氧化还原聚合物膜。 在所述氧化还原聚合物膜的表面上直接形成离子载体膜。 载体膜含有用于使特定类型的离子从水溶液渗透到所述聚合物膜的离子载体物质。
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公开(公告)号：US4753719A
公开(公告)日：1988-06-28
申请号：US866738
申请日：1986-05-27
IPC分类号： G01N27/30 , G01N27/333
CPC分类号： G01N27/3335
摘要： Disclosed is an ion sensor having an ion-sensitive substrate provided within a tube at a position recessed from an open end of the tube and having an ion carrier membrane, which is selectively permeable to an ion of interest, filling the space between the opening of the tube and the surface of the ion-sensitive substrate on the open-end side of the tube. A method of manufacturing the ion sensor includes steps of inserting and retaining the ion-sensitive substrate in the tube, filling the space between the ion-sensitive substrate and the tube with a sol-like ion carrier membrane composition, and gelling the sol-like ion carrier membrane composition.
摘要翻译： 公开了一种离子传感器，其具有设置在管内的位于从管的开口端凹入的位置处的离子敏感基板，并且具有离子载体膜，该离子载体膜选择性地渗透感兴趣的离子， 管和离子敏感衬底的表面在管的开放端侧。 制造离子传感器的方法包括以下步骤：将离子敏感衬底插入并保持在管中，用溶胶状离子载体膜组合物填充离子敏感衬底和管之间的空间，并将溶胶状 离子载体膜组成。
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公开(公告)号：US4579641A
公开(公告)日：1986-04-01
申请号：US749189
申请日：1985-06-26
IPC分类号： G01N27/30 , G01N27/333 , G01N27/403
CPC分类号： G01N27/4035
摘要： A pH measurement device includes working and reference electrodes. The working electrode has a linear electrically conductive substrate, at least a distal end surface of which consists of platinum, and a selective hydrogen ion permeable layer formed on the distal end face of the substrate. The reference electrode includes an electric conductor formed to be insulated from the working electrode and surrounding the working electrode, a polymer-silver (I) complex layer formed on the outer circumferential surface of the conductor, and an ion-conductive layer containing an anionic compound and formed on the complex layer. The pH of a solution is measured in accordance with a difference between a potential of the working electrode and that of the reference electrode.
摘要翻译： pH测量装置包括工作电极和参比电极。 工作电极具有至少其前端表面由铂构成的线性导电基板和形成在基板的远端面上的选择性氢离子可渗透层。 参考电极包括形成为与工作电极绝缘并围绕工作电极的导电体，形成在导体的外周面上的聚合物 - 银（I）配合层和含有阴离子化合物的离子传导层 并形成在复合层上。 根据工作电极的电位和参考电极的电位之差来测量溶液的pH。
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公开(公告)号：US4563263A
公开(公告)日：1986-01-07
申请号：US339715
申请日：1982-01-15
申请人： Noboru Oyama , Hiroaki Matsuda , Eishun Tsuchida , Yukio Ohnuki , Takeshi Shimomura , Norihiko Ushizawa
发明人： Noboru Oyama , Hiroaki Matsuda , Eishun Tsuchida , Yukio Ohnuki , Takeshi Shimomura , Norihiko Ushizawa
IPC分类号： G01N27/333 , G01N27/26
CPC分类号： G01N27/3335
摘要： A selectively permeable film directly applied to coat the surface of an electroconductive element, said electively permeable film comprising a polymer which is derived from at least one aromatic compound selected from the group of nitrogen-containing aromatic compounds or from the group of hydroxy aromatic compounds. The nitrogen-containing aromatic compounds are aniline, 2-aminobenzotrifluoride, 2-aminopyridine, 2,3-diaminopyridine, 4,4'-diaminodiphenyl ether, 4,4'-methylenedianiline, tyramine, N-(o-hydroxybenzyl)-aniline and pyrrole. The film coated on the electrode surfaces permits selective passage of ions and the electrode can be used as an ions sensor for measuring the concentration of ions in solutions.
摘要翻译： 选择性渗透膜直接施加以涂覆导电元件的表面，所述选择性渗透膜包含衍生自至少一种选自含氮芳族化合物的芳族化合物或羟基芳族化合物的聚合物。 含氮芳族化合物为苯胺，2-氨基三氟甲苯，2-氨基吡啶，2,3-二氨基吡啶，4,4'-二氨基二苯醚，4,4'-亚甲基二苯胺，酪胺，N-（邻羟基苄基） - 苯胺和 吡咯。 涂覆在电极表面上的膜允许离子的选择性通过，并且电极可以用作用于测量溶液中离子浓度的离子传感器。
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