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公开(公告)号：US4996130A
公开(公告)日：1991-02-26
申请号：US492212
申请日：1990-03-13
申请人： Shuzo Suga , Masaki Satake , Senzo Sasaoka
发明人： Shuzo Suga , Masaki Satake , Senzo Sasaoka
摘要： A negative type silver halide photographic material is disclosed, which comprises a support having thereon at least one silver halide emulsion layer and at least one other hydrophilic colloidal layer, wherein at least one said silver halide emulsion layer or at least one said other hydrophilic colloidal layer contains a hydrazine derivative and a polyacrylamide derivative.
摘要翻译： 公开了一种负型卤化银照相材料，其包括其上具有至少一个卤化银乳剂层和至少一种其它亲水胶体层的载体，其中至少一种所述卤化银乳剂层或至少一种所述其它亲水胶体层 含有肼衍生物和聚丙烯酰胺衍生物。
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2.发明授权
公开(公告)号：US4722884A
公开(公告)日：1988-02-02
申请号：US757973
申请日：1985-07-23
CPC分类号： G03C1/035 , G03C1/061 , G03C1/16 , G03C1/18 , G03C2001/03535 , G03C2001/03558 , G03C2200/06 , Y10S430/15
摘要： A negative silver halide photographic light-sensitive material is provided, having a silver halide emulsion layer, which layer comprises silver haloiodide grains prepared in the presence of an iridium salt in an amount of 1.times.10.sup.-8 to 1.times.10.sup.-5 mole per one mole of silver, wherein the silver iodide content in the surface part of said grain is larger than the average silver iodide content in said grain, and additionally containing in said emulsion layer or in some other hydrophilic colloid layer, a compound of formula (I):R.sub.1 --NHNH--CHO (I)wherein R.sub.1 represents an aliphatic group or an aromatic group. Said photographic light-sensitive material is, after being exposed imagewise, developed with a developer containing 0.15 mole/l or more sulfite ion and having a pH value of 9.5-12.3, to form negative images having ultra-high contrast. The present photographic light-sensitive material has good photographic characteristics of sensitivity and gamma value, and the preservation stability thereof is good.
摘要翻译： 提供负卤化银照相感光材料，其具有卤化银乳剂层，该层包含在铱盐存在下制备的碘卤化银颗粒，其量为每摩尔银1×10-8至1×10-5摩尔 其中所述晶粒的表面部分中的碘化银含量大于所述晶粒中的平均碘化银含量，并且还包含在所述乳剂层或一些其它亲水胶体层中的式（I）化合物：R1- NHNH-CHO（I）其中R1表示脂族基团或芳族基团。 所述照相感光材料在成像曝光后，用含有0.15摩尔/升以上亚硫酸根离子并且pH值为9.5-12.3的显影剂显影，形成具有超高对比度的负像。 本照相感光材料具有良好的感光度和γ值的照相特性，其保存稳定性良好。
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公开(公告)号：US5976758A
公开(公告)日：1999-11-02
申请号：US995146
申请日：1997-12-19
申请人： Kouta Fukui , Senzo Sasaoka , Kohzaburoh Yamada
发明人： Kouta Fukui , Senzo Sasaoka , Kohzaburoh Yamada
摘要： A development processing method which comprises the steps of: imagewise exposing a silver halide photographic light-sensitive material; and developing the exposed photographic material with a developing solution, wherein the silver halide photographic material comprises a support having thereon at least one light-sensitive silver halide emulsion layer, at least one of the silver halide emulsion layer and other hydrophilic colloidal layers containing at least one hydrazine derivative; and wherein the developing solution is substantially free from a dihydroxybenzene compound, has a pH of from 9.0 to 10.5 and contains (1) at least one ascorbic acid developing agent, (2) at least one 1-phenyl-3-pyrazolidone auxiliary developing agent and (3) a compound represented by the following formula (I): ##STR1## wherein R.sub.1 to R.sub.4 may be the same or different and each represents a hydrogen atom, a halogen atom or a substituent group bonded to the ring in formula (I) by a carbon atom, a nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom, with the proviso that neither R.sub.1 nor R.sub.3 represents a hydroxyl group and that at least one of R.sub.1 to R.sub.4 is an --SM group, wherein M represents a hydrogen, atom, an alkali metal atom or an ammonium group.
摘要翻译： 一种显影处理方法，包括以下步骤：将卤化银照相感光材料成像曝光; 并用显影液显影所述曝光的照相材料，其中所述卤化银照相材料包括其上具有至少一个感光卤化银乳剂层的载体，所述卤化银乳剂层和至少含有至少一种 一种肼衍生物; 并且其中所述显影液基本上不含二羟基苯化合物，其pH为9.0〜10.5，并含有（1）至少一种抗坏血酸显影剂，（2）至少一种1-苯基-3-吡唑烷酮辅助显影剂 和（3）由下式（I）表示的化合物：其中R 1至R 4可以相同或不同，并且各自表示通过式（I）中与环结合的氢原子，卤素原子或取代基， 碳原子，氮原子，氧原子，硫原子或磷原子，条件是R1和R3都不表示羟基，并且R1至R4中的至少一个为-SM基团，其中M表示 氢原子，碱金属原子或铵基。
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4.发明授权
公开(公告)号：US5051336A
公开(公告)日：1991-09-24
申请号：US522400
申请日：1990-05-11
申请人： Nobuaki Inoue , Senzo Sasaoka , Tetsuo Yoshida
发明人： Nobuaki Inoue , Senzo Sasaoka , Tetsuo Yoshida
摘要： A negative type silver halide photographic material is disclosed. The material comprises a support having provided thereon at least one silver halide emulsion layer containing silver halide grains sensitized with gold and sulfur sensitizers, the emulsion layer or at least one other hydrophilic colloid layer containing at least one high contrast-imparting hydrazine derivative and at least one compound represented by the following general formula (I): ##STR1## wherein Z represents N or C--X wherein X represents a substituted or unsubstituted alkyl or aryl group, Y represents a substituted or unsubstituted alkyl or aryl group, and M represents a hydrogen atom, a metallic atom, or ammonium which may be substituted.
摘要翻译： 公开了负型卤化银照相材料。 该材料包括其上提供有至少一个含有由金和硫敏化剂敏化的卤化银颗粒的卤化银乳剂层的载体，所述乳剂层或至少一种其它亲水胶体层含有至少一种高对比度赋予肼衍生物，并且至少 一种由以下通式（I）表示的化合物：其中Z表示N或CX，其中X表示取代或未取代的烷基或芳基，Y表示取代或未取代的烷基或芳基，M表示 氢原子，金属原子或可被取代的铵。
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5.发明授权
公开(公告)号：US4873173A
公开(公告)日：1989-10-10
申请号：US110981
申请日：1987-10-21
申请人： Senzo Sasaoka , Tetsuo Yoshida , Nobuaki Inoue
发明人： Senzo Sasaoka , Tetsuo Yoshida , Nobuaki Inoue
摘要： A method of forming an image is provided. The method comprises the steps of (a) imagewise exposing a photographic material which comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer and which contains a hydrazine compound represented by the following general formula (I) in the emulsion layer or a hydrophilic colloid layer adjacent thereto, the photographic material being designed so that a difference in sensitivity (sensitivity being defined as log E corresponding to the density of fog+2.0) between (1) the photographic material is development-processed with a developing solution having a sulfite ion concentration of 0.15 mole/l or more, a potassium ion concentration of 0.2 mole/l or more and a pH value ranging from 10.5 to 12.3 and (2) the photographic material is development-processed with the same developing solution as described above, except that the pH value was lowered by 1.0, (.DELTA.log E), is 0.7 or less, and moreover, the gamma value obtained in (1) is 10 or more and the gamma value obtained in (2) is 5 or more: ##STR1## wherein A represents an aliphatic group, or an aromatic group; B represents a formyl group, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxcarbonyl group, a sulfinamoyl group, an alkoxysulfonyl group, a thioacyl group, a thiocarbamoyl group, a sulfamoyl group, or a heterocyclic group; both R.sub.0 and R.sub.1 represent a hydrogen atom, or one of them represents a hydrogen atom and the other represents an alkysulfonyl group, an arylsulfonyl group, or an acyl group; and B, R.sub.1 and the nitrogen atom attached thereto may form a partial structure of hydrazone, and (b) developing the exposed material with a developer. The method realizes superhigh contrast and high resolution images.
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6.发明授权
公开(公告)号：US4849319A
公开(公告)日：1989-07-18
申请号：US124442
申请日：1987-11-20
申请人： Nobuaki Inoue , Senzo Sasaoka , Hiroshi Hayashi
发明人： Nobuaki Inoue , Senzo Sasaoka , Hiroshi Hayashi
CPC分类号： G03C1/061 , G03C1/053 , Y10S430/15
摘要： A negative silver halide photographic material comprising a support and at least one silver halide emulsion layer on the support, the emulsion layer or other hydrophilic colloid layer containing a hydrazine derivative, wherein the photographic material further contains an acid polymer and in which the pH of the surface of the photographic material is not more than 5.8. Also, a method for forming a superhigh contrast negative image using the above photographic material is disclosed.
摘要翻译： 负极卤化银照相材料，其包含载体和载体上的至少一个卤化银乳剂层，所述乳液层或含有肼衍生物的其它亲水胶体层，其中所述照相材料还含有酸聚合物，其中所述 照相材料的表面不超过5.8。 此外，公开了使用上述照相材料形成超高对比度负像的方法。
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公开(公告)号：US4135931A
公开(公告)日：1979-01-23
申请号：US828113
申请日：1977-08-26
IPC分类号： G03C5/29 , C07D213/04 , C07D213/20 , C07D213/68 , C07D213/75 , C07D213/76 , C07D213/79 , C07D213/80 , G03C1/06 , G03C5/305 , G03C5/30
摘要： A method of forming an image which comprises development processing an image-wise exposed silver halide photosensitive element in the presence of at least one compound represented by the following general formula (I): ##STR1## wherein X.crclbar. represents an anion; R.sub.1 represents a --Y--R.sub.3 group, a --Y--COOR.sub.3 group, a --Y--OCOR.sub.3 group, a --Y'--COO--Y--OCO--R.sub.3 group, a --Y'--OCO--Y--COO--R.sub.3 group or a --Y'--COO--Y--COO--R.sub.3 group; Y represents an alkylene group having 1 to 18 carbon atoms, an arylene group or an aralkylene group; R.sub.3 represents an alkyl group having 1 to 18 carbon atoms, an aryl group, an aralkyl group, a ##STR2## group or a ##STR3## group; R.sub.4 represents an alkyl group having 1 to 18 carbon atoms, an aryl group or an aralkyl group; R.sub.2 represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 12 carbon atoms, an aryl group having 6 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, an oxycarbonyl group (--COOR.sub.5 wherein R.sub.5 represents an alkyl group having 1 to 18 carbon atoms or an aryl group), an acyloxy group having 1 to 18 carbon atoms, an alkoxy group having 1 to 18 carbon atoms, an amino group, a substituted amino group, an acylamino group, a sulfonamido group, a carbamoyl group, a ##STR4## group or R.sub.1 ; Y' is an alkylene group having 1 to 12 carbon atoms, an arylene group, an aralkylene group or a single bond; with the proviso that R.sub.1 or R.sub.2 contains at least one ester group.
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8.发明授权
公开(公告)号：US4997743A
公开(公告)日：1991-03-05
申请号：US463825
申请日：1990-01-08
申请人： Senzo Sasaoka , Nobuaki Inoue , Eiichi Okutsu
发明人： Senzo Sasaoka , Nobuaki Inoue , Eiichi Okutsu
摘要： Silver halide photographic material and method of forming an image using the same are disclosed. The material comprises one or more silver halide emulsion layers on a support, with a hydrazine derivative and a developing agent being incorporated in at least one of said emulsion layers. The image forming method comprises performing imagewise exposure of the above-described photographic material and developing said material with a developing solution that contains sulfite ions in a concentration of not less than 0.15 mole per liter and which has a pH within the range of from 9.5 to 12.3, and provides a supercontrasty negative image that has a very contrasty photographic characteristic of a gamma (.gamma.) of 10 or more and which is not highly susceptible to the occurrence of "black spots".
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9.发明授权Silver halide photographic material and method for forming super high contrast negative images therewith 失效卤化银照相材料和用于形成超高对比度负像的方法
公开(公告)号：US4920029A
公开(公告)日：1990-04-24
申请号：US235805
申请日：1988-08-23
申请人： Nobuaki Inoue , Senzo Sasaoka , Yoshio Inagaki , Tetsuro Kojima , Morio Yagihara
发明人： Nobuaki Inoue , Senzo Sasaoka , Yoshio Inagaki , Tetsuro Kojima , Morio Yagihara
CPC分类号： G03C1/061 , Y10S430/15
摘要： A negative type silver halide photographic material and a process for forming a super high contrast negative image using said material are described. This photographic material comprises a support having provided thereon at least one silver halide emulsion layer which has a substantial influence upon image density and at least one light-insensitive hydrophilic colloid layer, wherein a hydrophilic colloid layer other than said silver halide emulsion layer contains a hydrazine derivative in a non-diffusing condition. With this photographic material, a super high contrast negative image can be obtained without decreasing sensitivity and gamma by the use of a developer containing not less than 0.15 mol/liter of sulfite ions and having a pH of from 10.5 to 12.3.
摘要翻译： 描述负型卤化银照相材料和使用所述材料形成超高对比度负像的方法。 该照相材料包括其上设置有至少一个卤化银乳剂层的载体，其对图像密度具有实质影响，并且至少一个不透光的亲水胶体层，其中除了所述卤化银乳剂层之外的亲水胶体层含有肼 衍生物在非扩散条件下。 利用该照相材料，可以通过使用含有不低于0.15mol / l亚硫酸根离子并且pH为10.5〜12.3的显影剂，而不降低灵敏度和γ而获得超高对比度负像。
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10.发明授权
公开(公告)号：US4839259A
公开(公告)日：1989-06-13
申请号：US130482
申请日：1987-12-09
申请人： Senzo Sasaoka , Nobuaki Inoue , Eiichi Okutsu
发明人： Senzo Sasaoka , Nobuaki Inoue , Eiichi Okutsu
摘要： Silver halide photographic material and method of forming an image using the same are disclosed. The material comprises one or more silver halide emulsion layers on a support, with a hydrazine derivative and a developing agent being incorporated in at least one of said emulsion layers. The image forming method comprises performing imagewise exposure of the above-described photographic material and developing said material with a developing solution that contains sulfite ions in a concentration of not less than 0.15 mole per liter and which has a pH within the range of from 9.5 to 12.3, and provides a supercontrasty negative image that has a very contrasty photographic characteristic of a gamma (.gamma.) of 10 or more and which is not highly susceptible to the occurrence of "black spots".
摘要翻译： 公开了卤化银照相材料和使用其形成图像的方法。 该材料在载体上包含一个或多个卤化银乳剂层，其中肼衍生物和显影剂被引入至少一个所述乳剂层中。 图像形成方法包括进行上述照相材料的成像曝光并用含有亚硫酸根离子的显影液显影所述材料，所述显影液的浓度不低于0.15摩尔/升，其pH值在9.5〜 12.3，并且提供了具有10或更大的伽马（伽马）的非常对比度的照相特征并且对“黑点”的发生不高度敏感的超立体负像。
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