公开(公告)号：US20130281688A1

公开(公告)日：2013-10-24

申请号：US13867542

申请日：2013-04-22

申请人： Stephen A. Di Biase ,  Keith M. Wampler ,  David R. Allen ,  Randal J. Bernhardt ,  Ryan Littich

发明人： Stephen A. Di Biase ,  Keith M. Wampler ,  David R. Allen ,  Randal J. Bernhardt ,  Ryan Littich

IPC分类号： C07H1/00 ,  C07C41/06 ,  C07F9/09 ,  C07C41/03 ,  C07C67/08 ,  C07C43/178 ,  C07C69/007

CPC分类号： C07C29/147 ,  C07C29/095 ,  C07C29/74 ,  C07C41/03 ,  C07C41/06 ,  C07C43/178 ,  C07C67/08 ,  C07C69/007 ,  C07F9/09 ,  C07H1/00 ,  C08F210/00 ,  C08F216/04 ,  C07C33/025

摘要： Unsaturated alcohol compositions are obtained by reducing a metathesis-derived hydrocarbyl unsaturated ester. Also disclosed is a process for preparing an unsaturated alcohol composition, where a metathesis derived hydrocarbyl carbonyl compound is reacted in the presence of a silane compound, an organic solvent, and a catalyst system prepared from a metallic complex and a reducing agent. This mixture is then hydrolyzed with a metallic base, and then mixed with organic solvent. The resultant mixture is then separated, washed, dried, and/or purified to produce the unsaturated alcohol composition. The unsaturated alcohol derivatives are useful in many end-use applications, including, for example, lubricants, functional fluids, fuels, functional additives for such lubricants, functional fluids and fuels, plasticizers, asphalt additives, friction reducing agents, plastics, and adhesives.