公开(公告)号：US4549958A

公开(公告)日：1985-10-29

申请号：US444275

申请日：1982-11-24

申请人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

发明人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

IPC分类号： C10G25/09 ,  C10G25/00 ,  C10G29/04 ,  C10G29/16 ,  C10G29/20

CPC分类号： C10G25/09

摘要： A process is disclosed for the treatment of a hydrocarbon oil feed having a significant content of vanadium to provide a higher grade of oil products by contacting the feed under treatment conditions in a treatment zone with sorbent material containing a metal additive to immobilize vanadium compounds. Treatment conditions are such that coke and vanadium are deposited on the sorbent in the treatment zone. Coked sorbent is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke, and regenerated sorbent is recycled to the treatment zone for contact with fresh feed. The metal additive is present on the sorbent in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the sorbent regeneration temperature. A sorbent composition disclosed comprises a kaolin clay containing the metal additive, which may be introduced into the clay during the treatment process or during sorbent manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble organo-metallic compounds of select metals.

摘要翻译： 公开了一种用于处理具有显着含量的钒的烃油进料的方法，以通过使处理区域中的处理条件下的进料与含有金属添加剂的吸附剂材料接触来固定钒化合物来提供更高等级的油产物。 处理条件使得焦炭和钒沉积在处理区中的吸附剂上。 在含有氧气的气体存在下，在足以除去焦炭的温度下再生焦化吸附剂，再生的吸附剂被再循环到处理区域以与新鲜进料接触。 在吸附剂再生温度下，金属添加剂以足以在含氧气体存在下固定钒化合物的量存在于吸附剂上。 公开的吸附剂组合物包含含有金属添加剂的高岭土，其可以在处理过程期间或在吸附剂制造期间引入到粘土中。 金属添加剂包括选择性金属的水溶性无机金属盐和可溶于烃的有机金属化合物。

公开(公告)号：US4551231A

公开(公告)日：1985-11-05

申请号：US521503

申请日：1983-08-08

申请人： Stephen M. Kovach ,  James L. Palmer

发明人： Stephen M. Kovach ,  James L. Palmer

IPC分类号： B01J29/90 ,  C10G11/05 ,  C10G11/18 ,  B01J29/38

CPC分类号： C10G11/18 ,  B01J29/90 ,  C10G11/05 ,  C10G2300/705 ,  Y02P30/446 ,  Y10S502/521

摘要： Contaminating metals including nickel, vanadium, iron and copper are deposited on a fluid cracking catalyst during the processing of carbo-metallic containing oils such as residual oils, reduced crudes or topped crudes. These contaminating metals lead to undesirous side reactions such as dehydrogenation, coking and methyl group removal which adversely affect conversion and gasoline selectively. Furthermore vanadia deactivates the crystalline zeolite component of the catalyst in addition to causing catalyst agglomeration because of its pentoxide melting point by treatment with a reducing gas such as ammonia. The ammonia is added as ammonia or in the presence of diluents such as nitrogen, carbon dioxide, flue gas, fuel gas and steam. The reaction of ammonia with vanadium produces vanadium nitride which is water insoluble and facilitates the disposal of high vanadium containing spent of deactivated catalyst by landfill techniques.

摘要翻译： 在含金属的含油油（例如残油，还原原油或顶部原油）的加工过程中，将含镍，钒，铁和铜的污染物沉积在流体裂解催化剂上。 这些污染的金属导致不希望的副反应，例如脱氢，焦化和甲基去除，其选择性地不利地影响转化和汽油。 此外，除了由于通过用还原性气体如氨处理其五氧化物熔点引起催化剂附聚之外，还可以使催化剂的结晶沸石组分失活。 氨如氨或在稀释剂如氮气，二氧化碳，烟道气，燃料气体和蒸汽的存在下加入。 氨与钒的反应产生水不溶性的氮化钒，并有利于通过填埋技术处理含有失活催化剂的高钒。

公开(公告)号：US4485184A

公开(公告)日：1984-11-27

申请号：US492153

申请日：1983-05-10

申请人： William P. Hettinger, Jr. ,  H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  Stephen M. Kovach ,  James L. Palmer

发明人： William P. Hettinger, Jr. ,  H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  Stephen M. Kovach ,  James L. Palmer

IPC分类号： B01J29/06 ,  C10G11/05 ,  C10G11/18 ,  B01J29/08 ,  B01J29/18

CPC分类号： B01J29/061 ,  C10G11/05 ,  C10G11/18

摘要： A process is disclosed for the treatment of a hydrocarbon oil feed having a significant content of metals to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a sacrificial trap material sufficient to immobilize Ni-V-Na compounds. Conversion conditions are such that carbonaceous material and metals are deposited on the catalyst in the conversion zone. The catalyst is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the carbonaceous deposits, and regenerated catalyst is recycled to the conversion zone for a contact with fresh feed. The sacrificial trap material is present on the catalyst in an amount sufficient to substantially immobilize the metal compounds in the presence of oxygen containing gas at the catalyst regeneration temperature. A catalyst composition for the above conversion comprises a catalytically active alumino-silicate zeolite dispersed in an amorphous inert solid matrix material containing the sacrificial trap material with or without one or more selected metal additives. The sacrificial trap material preferable includes inexpensive naturally occurring or synthetic zeolites which can be ion exchanged with water soluble metal additives.

摘要翻译： 公开了一种用于通过在转化区与转化条件下的进料与含有足以固定Ni-V-Na化合物的牺牲阱材料的催化剂接触来处理具有显着含量金属的烃油进料的方法， 。 转化条件使得碳质材料和金属沉积在转化区中的催化剂上。 催化剂在含氧气体的存在下在足以除去含碳沉积物的温度下再生，再生催化剂再循环到转化区以与新鲜进料接触。 牺牲阱材料以足以在催化剂再生温度下在含氧气体存在下基本上固定金属化合物的量存在于催化剂上。 用于上述转化的催化剂组合物包含分散在含有或不具有一种或多种选择的金属添加剂的牺牲捕获材料的无定形惰性固体基质材料中的催化活性铝硅酸盐沸石。 牺牲阱材料优选包括可与水溶性金属添加剂进行离子交换的便宜的天然存在或合成的沸石。

公开(公告)号：US4750987A

公开(公告)日：1988-06-14

申请号：US928675

申请日：1986-11-07

申请人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

发明人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

IPC分类号： C10G11/04 ,  C10G11/05 ,  C10G11/18

CPC分类号： C10G11/18 ,  C10G11/04 ,  C10G11/05 ,  Y10S502/521

摘要： A process is disclosed for the conversion of a hydrocarbon oil feed having a significant content of vanadium to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a metal additive to immobilize vanadium compounds. Conversion conditions are such that coke and vanadium are deposited on the catalyst in the conversion zone. Coked catalyst is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke and regenerated catalyst is recycled to the conversion zone for contact with fresh feed. The metal additive is present on the catalyst in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the catalyst regeneration temperature. A catalyst composition comprises a crystalline alumino-silicate zeolite dispersed in an amorphous inert solid matrix containing the metal additive, which may be introduced into the catalyst during the conversion process or during catalyst manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble inorganic metal salts and hydrocarbon soluble organometallic compounds of select metals.

摘要翻译： 公开了一种通过使转化区中的转化条件下的进料与含有金属添加剂的催化剂接触来固定钒化合物的方法，用于将具有显着含量的钒的烃油进料转化成较轻油的产物。 转化条件使得焦炭和钒沉积在转化区中的催化剂上。 在含氧气体的存在下，在足以除去焦炭的温度下再生催化剂，再生催化剂再循环到转化区以与新鲜进料接触。 催化剂上存在的金属添加剂的量足以在催化剂再生温度下在含氧气体存在下固定钒化合物。 催化剂组合物包含分散在含有金属添加剂的无定形惰性固体基质中的结晶铝硅酸盐沸石，其可在转化过程期间或在催化剂制备期间引入催化剂。 金属添加剂包括水溶性无机金属盐和烃溶性无机金属盐和选择性金属的烃溶性有机金属化合物。

公开(公告)号：US4513093A

公开(公告)日：1985-04-23

申请号：US277752

申请日：1981-03-30

申请人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

发明人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

IPC分类号： C10G25/00 ,  C10G25/09 ,  B01J21/16

CPC分类号： C10G25/00 ,  C10G25/003 ,  C10G25/09 ,  Y10S502/521

摘要： A process is disclosed for the treatment of a hydrocarbon oil feed having a significant content of vanadium to provide a higher grade of oil products by contacting the feed under treatment conditions in a treatment zone with sorbent material containing a metal additive to immobilize vanadium compounds. Treatment conditions are such that coke and vanadium are deposited on the sorbent in the treatment zone. Coked sorbent is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke, and regenerated sorbent is recycled to the treatment zone for contact with fresh feed. The metal additive is present on the sorbent in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the sorbent regeneration temperature. A sorbent composition disclosed comprises a kaolin clay containing the metal additive, which may be introduced into the clay during the treatment process or during sorbent manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble organo-metallic compounds of select metals.

摘要翻译： PCT No.PCT / US81 / 00357 Sec。 371日期1981年3月30日 102（e）1981年3月30日PCT提交1981年3月19日PCT公布。 出版物WO82 / 03226 公开了一种用于处理具有显着含量的钒的烃油进料的方法，以通过使处理区中的处理条件下的进料与含有金属的吸附剂材料接触来提供更高等级的油产物 添加剂以固定钒化合物。 处理条件使得焦炭和钒沉积在处理区中的吸附剂上。 在含有氧气的气体存在下，在足以除去焦炭的温度下再生焦化吸附剂，再生的吸附剂被再循环到处理区域以与新鲜进料接触。 在吸附剂再生温度下，金属添加剂以足以在含氧气体存在下固定钒化合物的量存在于吸附剂上。 公开的吸附剂组合物包含含有金属添加剂的高岭土，其可以在处理过程期间或在吸附剂制造期间引入到粘土中。 金属添加剂包括选择性金属的水溶性无机金属盐和可溶于烃的有机金属化合物。

公开(公告)号：US4432890A

公开(公告)日：1984-02-21

申请号：US277751

申请日：1981-03-30

申请人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

发明人： H. Wayne Beck ,  James D. Carruthers ,  Edward B. Cornelius ,  William P. Hettinger, Jr. ,  Stephen M. Kovach ,  James L. Palmer ,  Oliver J. Zandona

IPC分类号： B01J29/06 ,  B01J29/08 ,  C10G11/18 ,  B01J29/18

CPC分类号： B01J29/061 ,  C10G11/18 ,  B01J29/088

摘要： A process is disclosed for the conversion of a hydrocarbon oil feed having a significant content of vanadium to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a metal additive to immobilize vanadium compounds. Conversion conditions are such that coke and vanadium are deposited on the catalyst in the conversion zone. Coked catalyst is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke and regenerated catalyst is recycled to the conversion zone for contact with fresh feed. The metal additive is present on the catalyst in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the catalyst regeneration temperature. A catalyst composition comprises a crystalline alumino-silicate zeolite dispersed in an amorphous inert solid matrix containing the metal additive, which may be introduced into the catalyst during the conversion process or during catalyst manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble inorganic metal salts and hydrocarbon soluble organometallic compounds of select metals.

摘要翻译： PCT No.PCT / US81 / 00356 Sec。 371日期1981年3月30日 102（e）1981年3月30日PCT提交1981年3月19日PCT公布。 出版物WO82 / 03225 公开了一种通过在转化区与转化条件下的进料与含有金属添加剂的催化剂接触来将钒显着含量的烃油进料转化成较轻油产物的方法，以固定钒 化合物。 转化条件使得焦炭和钒沉积在转化区中的催化剂上。 在含氧气体的存在下，在足以除去焦炭的温度下再生催化剂，再生催化剂再循环到转化区以与新鲜进料接触。 在催化剂再生温度下，在含氧气体存在下，金属添加剂以足以固定钒化合物的量存在于催化剂上。 催化剂组合物包含分散在含有金属添加剂的无定形惰性固体基质中的结晶铝硅酸盐沸石，其可在转化过程期间或在催化剂制备期间引入催化剂。 金属添加剂包括水溶性无机金属盐和烃溶性无机金属盐和选择性金属的烃溶性有机金属化合物。