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1.发明授权Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion 失效在碳 - 金属油转化期间沉积在催化材料上的氧化钒的固定化
公开(公告)号：US4750987A
公开(公告)日：1988-06-14
申请号：US928675
申请日：1986-11-07
申请人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
发明人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
CPC分类号： C10G11/18 , C10G11/04 , C10G11/05 , Y10S502/521
摘要： A process is disclosed for the conversion of a hydrocarbon oil feed having a significant content of vanadium to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a metal additive to immobilize vanadium compounds. Conversion conditions are such that coke and vanadium are deposited on the catalyst in the conversion zone. Coked catalyst is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke and regenerated catalyst is recycled to the conversion zone for contact with fresh feed. The metal additive is present on the catalyst in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the catalyst regeneration temperature. A catalyst composition comprises a crystalline alumino-silicate zeolite dispersed in an amorphous inert solid matrix containing the metal additive, which may be introduced into the catalyst during the conversion process or during catalyst manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble inorganic metal salts and hydrocarbon soluble organometallic compounds of select metals.
摘要翻译： 公开了一种通过使转化区中的转化条件下的进料与含有金属添加剂的催化剂接触来固定钒化合物的方法，用于将具有显着含量的钒的烃油进料转化成较轻油的产物。 转化条件使得焦炭和钒沉积在转化区中的催化剂上。 在含氧气体的存在下，在足以除去焦炭的温度下再生催化剂，再生催化剂再循环到转化区以与新鲜进料接触。 催化剂上存在的金属添加剂的量足以在催化剂再生温度下在含氧气体存在下固定钒化合物。 催化剂组合物包含分散在含有金属添加剂的无定形惰性固体基质中的结晶铝硅酸盐沸石，其可在转化过程期间或在催化剂制备期间引入催化剂。 金属添加剂包括水溶性无机金属盐和烃溶性无机金属盐和选择性金属的烃溶性有机金属化合物。
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2.发明授权Immobilization of vanadia deposited on sorbent materials during treatment of carbo-metallic oils 失效固化在金属油处理过程中沉积在吸附剂材料上的氧化钒
公开(公告)号：US4513093A
公开(公告)日：1985-04-23
申请号：US277752
申请日：1981-03-30
申请人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
发明人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
CPC分类号： C10G25/00 , C10G25/003 , C10G25/09 , Y10S502/521
摘要： A process is disclosed for the treatment of a hydrocarbon oil feed having a significant content of vanadium to provide a higher grade of oil products by contacting the feed under treatment conditions in a treatment zone with sorbent material containing a metal additive to immobilize vanadium compounds. Treatment conditions are such that coke and vanadium are deposited on the sorbent in the treatment zone. Coked sorbent is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke, and regenerated sorbent is recycled to the treatment zone for contact with fresh feed. The metal additive is present on the sorbent in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the sorbent regeneration temperature. A sorbent composition disclosed comprises a kaolin clay containing the metal additive, which may be introduced into the clay during the treatment process or during sorbent manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble organo-metallic compounds of select metals.
摘要翻译： PCT No.PCT / US81 / 00357 Sec。 371日期1981年3月30日 102（e）1981年3月30日PCT提交1981年3月19日PCT公布。 出版物WO82 / 03226 公开了一种用于处理具有显着含量的钒的烃油进料的方法，以通过使处理区中的处理条件下的进料与含有金属的吸附剂材料接触来提供更高等级的油产物 添加剂以固定钒化合物。 处理条件使得焦炭和钒沉积在处理区中的吸附剂上。 在含有氧气的气体存在下，在足以除去焦炭的温度下再生焦化吸附剂，再生的吸附剂被再循环到处理区域以与新鲜进料接触。 在吸附剂再生温度下，金属添加剂以足以在含氧气体存在下固定钒化合物的量存在于吸附剂上。 公开的吸附剂组合物包含含有金属添加剂的高岭土，其可以在处理过程期间或在吸附剂制造期间引入到粘土中。 金属添加剂包括选择性金属的水溶性无机金属盐和可溶于烃的有机金属化合物。
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3.发明授权Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion 失效在碳 - 金属油转化期间沉积在催化材料上的氧化钒的固定化
公开(公告)号：US4432890A
公开(公告)日：1984-02-21
申请号：US277751
申请日：1981-03-30
申请人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
发明人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
CPC分类号： B01J29/061 , C10G11/18 , B01J29/088
摘要： A process is disclosed for the conversion of a hydrocarbon oil feed having a significant content of vanadium to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a metal additive to immobilize vanadium compounds. Conversion conditions are such that coke and vanadium are deposited on the catalyst in the conversion zone. Coked catalyst is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke and regenerated catalyst is recycled to the conversion zone for contact with fresh feed. The metal additive is present on the catalyst in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the catalyst regeneration temperature. A catalyst composition comprises a crystalline alumino-silicate zeolite dispersed in an amorphous inert solid matrix containing the metal additive, which may be introduced into the catalyst during the conversion process or during catalyst manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble inorganic metal salts and hydrocarbon soluble organometallic compounds of select metals.
摘要翻译： PCT No.PCT / US81 / 00356 Sec。 371日期1981年3月30日 102（e）1981年3月30日PCT提交1981年3月19日PCT公布。 出版物WO82 / 03225 公开了一种通过在转化区与转化条件下的进料与含有金属添加剂的催化剂接触来将钒显着含量的烃油进料转化成较轻油产物的方法，以固定钒 化合物。 转化条件使得焦炭和钒沉积在转化区中的催化剂上。 在含氧气体的存在下，在足以除去焦炭的温度下再生催化剂，再生催化剂再循环到转化区以与新鲜进料接触。 在催化剂再生温度下，在含氧气体存在下，金属添加剂以足以固定钒化合物的量存在于催化剂上。 催化剂组合物包含分散在含有金属添加剂的无定形惰性固体基质中的结晶铝硅酸盐沸石，其可在转化过程期间或在催化剂制备期间引入催化剂。 金属添加剂包括水溶性无机金属盐和烃溶性无机金属盐和选择性金属的烃溶性有机金属化合物。
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4.发明授权Immobilization of vanadia deposited on sorbent materials during treatment of carbo-metallic oils 失效固化在金属油处理过程中沉积在吸附剂材料上的氧化钒
公开(公告)号：US4549958A
公开(公告)日：1985-10-29
申请号：US444275
申请日：1982-11-24
申请人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
发明人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , William P. Hettinger, Jr. , Stephen M. Kovach , James L. Palmer , Oliver J. Zandona
CPC分类号： C10G25/09
摘要： A process is disclosed for the treatment of a hydrocarbon oil feed having a significant content of vanadium to provide a higher grade of oil products by contacting the feed under treatment conditions in a treatment zone with sorbent material containing a metal additive to immobilize vanadium compounds. Treatment conditions are such that coke and vanadium are deposited on the sorbent in the treatment zone. Coked sorbent is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke, and regenerated sorbent is recycled to the treatment zone for contact with fresh feed. The metal additive is present on the sorbent in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the sorbent regeneration temperature. A sorbent composition disclosed comprises a kaolin clay containing the metal additive, which may be introduced into the clay during the treatment process or during sorbent manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble organo-metallic compounds of select metals.
摘要翻译： 公开了一种用于处理具有显着含量的钒的烃油进料的方法，以通过使处理区域中的处理条件下的进料与含有金属添加剂的吸附剂材料接触来固定钒化合物来提供更高等级的油产物。 处理条件使得焦炭和钒沉积在处理区中的吸附剂上。 在含有氧气的气体存在下，在足以除去焦炭的温度下再生焦化吸附剂，再生的吸附剂被再循环到处理区域以与新鲜进料接触。 在吸附剂再生温度下，金属添加剂以足以在含氧气体存在下固定钒化合物的量存在于吸附剂上。 公开的吸附剂组合物包含含有金属添加剂的高岭土，其可以在处理过程期间或在吸附剂制造期间引入到粘土中。 金属添加剂包括选择性金属的水溶性无机金属盐和可溶于烃的有机金属化合物。
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5.发明授权Trapping of metals deposited on catalytic materials during carbometallic oil conversion 失效在金属油转化期间捕获沉积在催化材料上的金属
公开(公告)号：US4485184A
公开(公告)日：1984-11-27
申请号：US492153
申请日：1983-05-10
申请人： William P. Hettinger, Jr. , H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Stephen M. Kovach , James L. Palmer
发明人： William P. Hettinger, Jr. , H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Stephen M. Kovach , James L. Palmer
CPC分类号： B01J29/061 , C10G11/05 , C10G11/18
摘要： A process is disclosed for the treatment of a hydrocarbon oil feed having a significant content of metals to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a sacrificial trap material sufficient to immobilize Ni-V-Na compounds. Conversion conditions are such that carbonaceous material and metals are deposited on the catalyst in the conversion zone. The catalyst is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the carbonaceous deposits, and regenerated catalyst is recycled to the conversion zone for a contact with fresh feed. The sacrificial trap material is present on the catalyst in an amount sufficient to substantially immobilize the metal compounds in the presence of oxygen containing gas at the catalyst regeneration temperature. A catalyst composition for the above conversion comprises a catalytically active alumino-silicate zeolite dispersed in an amorphous inert solid matrix material containing the sacrificial trap material with or without one or more selected metal additives. The sacrificial trap material preferable includes inexpensive naturally occurring or synthetic zeolites which can be ion exchanged with water soluble metal additives.
摘要翻译： 公开了一种用于通过在转化区与转化条件下的进料与含有足以固定Ni-V-Na化合物的牺牲阱材料的催化剂接触来处理具有显着含量金属的烃油进料的方法， 。 转化条件使得碳质材料和金属沉积在转化区中的催化剂上。 催化剂在含氧气体的存在下在足以除去含碳沉积物的温度下再生，再生催化剂再循环到转化区以与新鲜进料接触。 牺牲阱材料以足以在催化剂再生温度下在含氧气体存在下基本上固定金属化合物的量存在于催化剂上。 用于上述转化的催化剂组合物包含分散在含有或不具有一种或多种选择的金属添加剂的牺牲捕获材料的无定形惰性固体基质材料中的催化活性铝硅酸盐沸石。 牺牲阱材料优选包括可与水溶性金属添加剂进行离子交换的便宜的天然存在或合成的沸石。
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6.发明授权High performance catalysts for carbometallic oil conversion and their manufacture and use 失效用于金属油转化的高性能催化剂及其制造和使用
公开(公告)号：US4588702A
公开(公告)日：1986-05-13
申请号：US662475
申请日：1984-10-18
申请人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Ronald A. Kmecak , Stephen M. Kovach , William P. Hettinger, Jr.
发明人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Ronald A. Kmecak , Stephen M. Kovach , William P. Hettinger, Jr.
CPC分类号： B01J29/084 , C10G11/05
摘要： A catalyst nominally containing zeolite, clay and silica-alumina gel. The zeolite is preferably partially exchanged with high La/Ce ratio solution in a wetting step. The catayst and processes for its manufacture and use are disclosed. The catalyst is excellent for processing heavy oils, generally produces higher LCO/slurry oil ratio and has high metals tolerance.
摘要翻译： 名义上含有沸石，粘土和二氧化硅 - 氧化铝凝胶的催化剂。 在润湿步骤中，沸石优选与高La / Ce比溶液部分交换。 公开了其制造和使用的催化剂和方法。 该催化剂对于加工重油是非常好的，通常产生较高的LCO /浆料油比例，并且具有高的金属耐受性。
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公开(公告)号：US4561968A
公开(公告)日：1985-12-31
申请号：US568326
申请日：1984-02-27
申请人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Ronald A. Kmecak , Stephen M. Kovach , William P. Hettinger, Jr.
发明人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Ronald A. Kmecak , Stephen M. Kovach , William P. Hettinger, Jr.
CPC分类号： C10G11/05 , B01J29/084
摘要： A catalyst nominally containing zeolite, clay and silica-alumina gel is disclosed. The zeolite is preferably partially exchanged with high La/Ce ratio solution in a wetting step. The catalyst and processes for its manufacture and use are disclosed. The catalyst is excellent for processing heavy oils, generally produces higher LCO/slurry oil ratio and has high metals tolerance.
摘要翻译： 公开了一种名义上含有沸石，粘土和二氧化硅 - 氧化铝凝胶的催化剂。 在润湿步骤中，沸石优选与高La / Ce比溶液部分交换。 公开了其制造和使用的催化剂和方法。 该催化剂对于加工重油是非常好的，通常产生较高的LCO /浆料油比例，并且具有高的金属耐受性。
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8.发明授权High performance catalysts for carbometallic oil conversion and their manufacturing and use 失效用于金属油转化的高性能催化剂及其制造和使用
公开(公告)号：US4480047A
公开(公告)日：1984-10-30
申请号：US483061
申请日：1983-04-07
申请人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Ronald A. Kmecak , Stephen M. Kovach , William P. Hettinger, Jr.
发明人： H. Wayne Beck , James D. Carruthers , Edward B. Cornelius , Ronald A. Kmecak , Stephen M. Kovach , William P. Hettinger, Jr.
CPC分类号： B01J29/084 , C10G11/05
摘要： A catalyst nominally containing zeolite, preferably HY zeolite and/or ultrastable HY zeolite, clay, alumina and an acidic silica-alumina co-gel matrix. The zeolite is preferably partially exchanged with high La/Ce ratio solution in a wetting step, and rare earths are precipitated onto the matrix. The catalyst has high metals tolerance and is capable of cracking heavy reduced crude oils, producing higher LCO/slurry oil ratio.
摘要翻译： 名义上含有沸石，优选HY沸石和/或超稳定HY沸石，粘土，氧化铝和酸性二氧化硅 - 氧化铝共凝胶基质的催化剂。 沸石优选在湿润步骤中与高La / Ce比溶液部分交换，稀土沉淀在基体上。 该催化剂具有高金属耐受性，能够破裂重质原油，产生较高的LCO /浆料油比。
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公开(公告)号：US4508839A
公开(公告)日：1985-04-02
申请号：US296679
申请日：1981-08-27
CPC分类号： B01J29/084 , C10G11/05 , C10G11/18 , Y02P30/446
摘要： An improved process and catalyst for economically converting carbo-metallic oils to lighter products. This process is practiced in accordance with effective metals management, carbon management and catalyst activity management combined with feed atomization-vaporization, efficient stripping of carbonaceous material from the coked catalyst, exothermic and endothermic removal of hydrocarbonaceous material to effectively maintain the RCC unit in heat balance. This reduced crude cracking process is practiced with a new and improved catalyst composition identified as RCCC-1 Special that is characterized by the following composition; at least 30 wt % rare earth exchanged "Y" faujasite crystalline zeolite with a silica to alumina ratio of at least 5 of a high lanthanum to cerium ratio and residual sodium content less than 0.30 wt %, is provided with a pore volume greater than 0.35 cc/gm. and comprises a clay matrix material that may or may not be acidic with pore size openings in the range of 500 to 2,000 angstroms. The RCCC-1 Special can contain metal promoters to catalyze the endothermic removal of coke and the partial removal of hydrogen present in the carbonaceous material with carbon dioxide. In addition, metal additives to passivate and immobilize vanadium are contemplated.
摘要翻译： 一种改进的方法和催化剂，用于将碳金属油经济转化为轻质产品。 该过程根据有效的金属管理，碳管理和催化剂活性管理结合进料雾化蒸发，从焦化催化剂高效汽提碳质材料，含烃材料的放热和吸热除去以有效地保持RCC单元的热平衡 。 这种减少的粗裂化过程是用新的和改进的催化剂组合物来实现的，鉴定为RCCC-1 Special，其特征在于以下组成： 至少30wt％的稀土交换的“Y”八面沸石结晶沸石的二氧化硅与氧化铝的比例至少为5，高镧与铈的比例和残留的钠含量小于0.30wt％，孔体积大于0.35 cc / gm 并且包含粘土基质材料，其可以具有或不具有500至2000埃范围内的孔径开口的酸性。 RCCC-1 Special可以含有金属助催化剂，以催化焦炭的吸热去除和用二氧化碳部分除去存在于碳质材料中的氢。 此外，考虑了钝化和固定钒的金属添加剂。
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公开(公告)号：US4432863A
公开(公告)日：1984-02-21
申请号：US288952
申请日：1981-07-20
CPC分类号： C01B3/44 , C01B3/38 , Y02P20/584
摘要： A process is disclosed for economically converting carbo-metallic oils to liquid fuel products by bringing a converter feed containing 650.degree. F.+ material characterized by a carbon residue on pyrolysis of at least about 1 and by containing at least about 4 ppm of Nickel Equivalents of heavy metals, including nickel, into contact with a particulate cracking catalyst in a progressive flow type reactor having an elongated conversion zone. The suspension of catalyst and feed in the reactor has a vapor residence time in the range of about 0.5 to about 10 seconds, a temperature of about 900.degree. F. to about 1400.degree. F. and a pressure of about 10 to about 50 pounds per square inch absolute for causing a conversion per pass in the range of about 50 to about 90 percent while depositing nickel on the catalyst and coke on the catalyst in amounts in the range of about 0.3 to about 3 percent by weight. The coke-laden catalyst is separated from the resulting stream of hydrocarbons and regenerated by combustion of the coke with oxygen, the regenerated catalyst being characterized by deposited nickel in at least a partially oxidized state and a level of carbon on catalyst of about 0.25 percent by weight or less. The regenerated catalyst is contacted with a reducing gas under reducing conditions sufficient to reduce at least a portion of the oxidized nickel deposits to a reduced state and the regenerated catalyst with reduced nickel deposits is recycled to the conversion zone for contact with fresh feed. Water is also introduced into the reactor conversion zone and the amount of water and the amount of reduced nickel on the recycled catalyst are sufficient to provide a steam reforming reaction so that hydrogen deficient components of the feed are converted to products having higher hydrogen to carbon ratios and the amount of feed converted to coke is reduced. The amount of deposited nickel on catalyst is preferably in the range from about 2,000 to about 20,000 ppm and the mole ratio of water relative to feed in the conversion zone is preferably in the range from about 2 to about 14.
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