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1.发明申请公开(公告)号：US20090290287A1
公开(公告)日：2009-11-26
申请号：US12511568
申请日：2009-07-29
IPC分类号： H01G9/155
摘要： The disclosure relates to asymmetric supercapacitors containing: a positive electrode comprising a current collector and a first active material selected from a layered double hydroxide of formula [M2+1−xMx3+(OH)2]An−x/n·mH2O where M2+ is at least one divalent metal, M3+ is at least one trivalent metal and A is an anion of charge n−, where x is greater than zero and less than 1, n is 1, 2, 3 or 4 and m is 0 to 10; LiCoO2; LiCoxNiyO2 where x and y are greater than zero and less than 1; LiCoxNiyMn(1−x−y)O2 where x and y are greater than zero and less than 1; CoSx where x is from 1 to 1.5; MoS; Zn; activated carbon and graphite; a negative electrode containing a material selected from a carbonaceous active material, MoO3 and Li1xMoO6−x/2; an aqueous electrolyte solution or a non-aqueous ionic conducting electrolyte solution containing a salt and a salt and a non-aqueous solution; and a separator plate. Alternatively, the electrolyte can be a solid electrolyte.
摘要翻译： 本公开涉及不对称超级电容器，其包含：正极，其包含集电器和选自式[M2 + 1-xMx3 +（OH）2] An-x / n.mH2O的层状双氢氧化物的第一活性材料，其中M2 +处于 至少一种二价金属，M3 +为至少一种三价金属，A为电荷n n的阴离子，其中x大于零且小于1，n为1,2,3或4，m为0至10; LiCoO2; LiCoxNiyO2其中x和y大于零且小于1; LiCoxNiyMn（1-x-y）O2，其中x和y大于零且小于1; CoSx，其中x为1至1.5; MoS; 锌; 活性炭和石墨; 含有选自碳质活性物质MoO3和Li1xMoO6-x / 2的材料的负极; 含有盐和盐的非水电解质溶液或非水性离子导电电解质溶液和非水溶液; 和隔板。 或者，电解质可以是固体电解质。
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2.发明授权公开(公告)号：US08107223B2
公开(公告)日：2012-01-31
申请号：US12511568
申请日：2009-07-29
IPC分类号： H01G9/00
摘要： The disclosure relates to asymmetric supercapacitors containing: a positive electrode comprising a current collector and a first active material selected from a layered double hydroxide of formula [M2+1−xMx3+(OH)2]An−x/n·mH2O where M2+ is at least one divalent metal, M3+ is at least one trivalent metal and A is an anion of charge n−, where x is greater than zero and less than 1, n is 1, 2, 3 or 4 and m is 0 to 10; LiCoO2; LiCoxNiyO2 where x and y are greater than zero and less than 1; LiCoxNiyMn(1−x−y)O2 where x and y are greater than zero and less than 1; CoSx where x is from 1 to 1.5; MoS; Zn; activated carbon and graphite; a negative electrode containing a material selected from a carbonaceous active material, MoO3 and Li1xMoO6−x/2; an aqueous electrolyte solution or a non-aqueous ionic conducting electrolyte solution containing a salt and a salt and a non-aqueous solution; and a separator plate. Alternatively, the electrolyte can be a solid electrolyte.
摘要翻译： 本公开涉及不对称超级电容器，其包含：正极，其包含集电器和选自式[M2 + 1-xMx3 +（OH）2] An-x / n·mH2O的层状双氢氧化物的第一活性物质，其中M2 +处于 至少一个二价金属，M3 +是至少一种三价金属，A是电荷n n的阴离子，其中x大于零且小于1，n为1,2,3或4，m为0至10; LiCoO2; LiCoxNiyO2其中x和y大于零且小于1; LiCoxNiyMn（1-x-y）O2，其中x和y大于零且小于1; CoSx，其中x为1至1.5; MoS; 锌; 活性炭和石墨; 含有选自碳质活性物质MoO3和Li1xMoO6-x / 2的材料的负极; 含有盐和盐的非水电解质溶液或非水性离子导电电解质溶液和非水溶液; 和隔板。 或者，电解质可以是固体电解质。
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3.发明授权公开(公告)号：US07576971B2
公开(公告)日：2009-08-18
申请号：US11711376
申请日：2007-02-27
IPC分类号： H01G9/00
摘要： Asymmetric supercapacitors comprise: a positive electrode comprising a current collector and a first active material selected from the group consisting of manganese dioxide, silver oxide, iron sulfide, lithium manganese oxide, lithium cobalt oxide, lithium nickel oxide, lithium iron phosphate, and a combination comprising at least one of the foregoing active materials; a negative electrode comprising a carbonaceous active material; an aqueous electrolyte solution selected from the group consisting of aqueous solutions of hydroxides of alkali metals, aqueous solutions of carbonates of alkali metals, aqueous solutions of chlorides of alkali metals, aqueous solutions of sulfates of alkali metals, aqueous solutions of nitrates of alkali metals, and a combination comprising at least one of the foregoing aqueous solutions; and a separator plate. Alternatively, the electrolyte can be a non-aqueous ionic conducting electrolyte or a solid electrolyte.
摘要翻译： 不对称超级电容器包括：正极，其包含集电体和选自二氧化锰，氧化银，硫化铁，锂锰氧化物，钴酸锂，锂镍氧化物，磷酸铁锂和组合的第一活性物质 包括至少一种前述活性材料; 包含碳质活性物质的负极; 选自碱金属的氢氧化物的水溶液，碱金属的碳酸盐的水溶液，碱金属的氯化物的水溶液，碱金属的硫酸盐的水溶液，碱金属的硝酸盐的水溶液， 和包含至少一种前述水溶液的组合; 和隔板。 或者，电解质可以是非水性离子导电电解质或固体电解质。
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4.发明申请公开(公告)号：US20080158778A1
公开(公告)日：2008-07-03
申请号：US11711376
申请日：2007-02-27
摘要： Asymmetric supercapacitors comprise: a positive electrode comprising a current collector and a first active material selected from the group consisting of manganese dioxide, silver oxide, iron sulfide, lithium manganese oxide, lithium cobalt oxide, lithium nickel oxide, lithium iron phosphate, and a combination comprising at least one of the foregoing active materials; a negative electrode comprising a carbonaceous active material; an aqueous electrolyte solution selected from the group consisting of aqueous solutions of hydroxides of alkali metals, aqueous solutions of carbonates of alkali metals, aqueous solutions of chlorides of alkali metals, aqueous solutions of sulfates of alkali metals, aqueous solutions of nitrates of alkali metals, and a combination comprising at least one of the foregoing aqueous solutions; and a separator plate. Alternatively, the electrolyte can be a non-aqueous ionic conducting electrolyte or a solid electrolyte.
摘要翻译： 不对称超级电容器包括：正极，其包含集电体和选自二氧化锰，氧化银，硫化铁，锂锰氧化物，钴酸锂，锂镍氧化物，磷酸铁锂和组合的第一活性物质 包括至少一种前述活性材料; 包含碳质活性物质的负极; 选自碱金属的氢氧化物的水溶液，碱金属的碳酸盐的水溶液，碱金属的氯化物的水溶液，碱金属的硫酸盐的水溶液，碱金属的硝酸盐的水溶液， 和包含至少一种前述水溶液的组合; 和隔板。 或者，电解质可以是非水性离子导电电解质或固体电解质。
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5.发明授权公开(公告)号：US07199997B1
公开(公告)日：2007-04-03
申请号：US09590496
申请日：2000-06-09
IPC分类号： H01G9/00
CPC分类号： H01G11/28 , H01G11/36 , H01G11/46 , Y02E60/13 , Y02T10/7022
摘要： An asymmetric supercapacitor has a positive electrode having a current collector an active material selected from the group consisting of manganese dioxide, silver oxide, iron sulfide and mixtures thereof, a negative electrode having a carbonaceous active material carbon and optional current collector, an electrolyte, and a separator plate. In a preferred embodiment at least one of the electrodes has nanostructured/nanofibrous material and in a more preferred embodiment, both electrodes have nanostructured/nanfibrous material. The electrolyte can be liquid or solid although liquid electrolytes are preferred.The asymmetric supercapacitor has improved energy density by electrically coupling an electrode of high faradaic capacity such as one having manganese oxide (MnO2) with an electrode such as carbon that stores charge through charge separation at the electric double-layer. The asymmetric supercapacitor also improves power density by using high surface area nanostructured/nanofibrous electrode materials.
摘要翻译： 不对称超级电容器具有具有集电体的正极，选自二氧化锰，氧化银，硫化铁及其混合物的活性物质，具有碳质活性物质碳的负极和任选的集电体，电解质，以及 分隔板。 在优选实施例中，至少一个电极具有纳米结构/纳米纤维材料，并且在更优选的实施方案中，两个电极都具有纳米结构/纳米纤维材料。 电解质可以是液体或固体，尽管液体电解质是优选的。
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公开(公告)号：US20120007027A1
公开(公告)日：2012-01-12
申请号：US12987794
申请日：2011-01-10
CPC分类号： H01G11/46 , B01J21/18 , B01J37/10 , B82Y30/00 , C01B3/0021 , H01G11/34 , H01G11/38 , Y02E60/13 , Y02E60/325
摘要： Activated carbon blacks and the enhanced methods of preparing activated carbon blacks have been discovered. In order to form an activated carbon black, a conductive carbon black is coated with nanoparticles containing metal, and then catalytically activated in steam and an inert gas to form a catalytically activated mesoporous carbon black, where the mass of the catalytically activated carbon black is lower than the mass of the carbon black. The nanoparticles may serve as catalysts for activation rugosity of mesoporous carbon blacks. The catalytically activated carbon black material may be used in all manner of devices that contain carbon materials.
摘要翻译： 已经发现活性炭黑和制备活性炭黑的增强方法。 为了形成活性炭黑，导电炭黑涂覆有含有金属的纳米颗粒，然后在蒸汽和惰性气体中催化活化以形成催化活化的中孔炭黑，其中催化活性炭黑的质量较低 比炭黑的质量。 纳米颗粒可作为介孔炭黑活化粗糙度的催化剂。 催化活性炭黑材料可以以包含碳材料的各种装置使用。
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公开(公告)号：US20230035364A1
公开(公告)日：2023-02-02
申请号：US17745849
申请日：2022-05-16
申请人： Stephen M. Lipka , Uschi M. Graham
发明人： Stephen M. Lipka , Uschi M. Graham
IPC分类号： C01B32/05 , C01B32/336 , C01B32/348 , C01B32/21
摘要： A method of using carbon dioxide and low pH effluent from prior processing batches for synthesizing-carbon particles or hydrochar from carbohydrate/water solution formulations and conversion of aqueous feedstock containing carbohydrate waste. The hydrochar is a precursor material containing biochar solids and an acidic effluent. The hydrochar can be separated into solids (biochar) and liquid where the solids can be used for preparing a variety of carbonaceous products such as activated carbon. The carbohydrate/water formulation is heated in a pressure vessel converting solid waste to hydrochar forming uniform stable carbon nuclei and converting the aqueous carbohydrates in solution to solid spherical carbon particles. Microwave-assisted or inductive heating can be used as a preprocessing step to increase formation of carbon nuclei to accelerate growth of the carbon particles.
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公开(公告)号：US09670066B2
公开(公告)日：2017-06-06
申请号：US14087219
申请日：2013-11-22
CPC分类号： C01B31/08 , C01B31/02 , C01B31/10 , C01B31/12 , C01B32/05 , C01B32/336 , C01B32/342 , H01G11/24 , H01G11/34 , H01G11/42 , Y02E60/13 , Y10T428/2982 , Y10T428/30
摘要： A composition generally includes carbon particles. The particles are prepared by dissolving a carbohydrate-based precursor in water to form a precursor solution and placing the precursor solution in a pressure vessel. The precursor solution is placed in a pressure vessel. The pressure vessel is heated to a reaction temperature to form carbon particles. The carbon particles are subjected to a chemical activation and a physical activation. The composition includes, by weight, about 5% to about 30% oxygen.
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公开(公告)号：US20140104754A1
公开(公告)日：2014-04-17
申请号：US14087219
申请日：2013-11-22
CPC分类号： C01B31/08 , C01B31/02 , C01B31/10 , C01B31/12 , C01B32/05 , C01B32/336 , C01B32/342 , H01G11/24 , H01G11/34 , H01G11/42 , Y02E60/13 , Y10T428/2982 , Y10T428/30
摘要： A composition generally includes carbon particles. The particles are prepared by dissolving a carbohydrate-based precursor in water to form a precursor solution and placing the precursor solution in a pressure vessel. The precursor solution is placed in a pressure vessel. The pressure vessel is heated to a reaction temperature to form carbon particles. The carbon particles are subjected to a chemical activation and a physical activation. The composition includes, by weight, about 5% to about 30% oxygen.
摘要翻译： 组合物通常包括碳颗粒。 通过将基于碳水化合物的前体溶解在水中以形成前体溶液并将前体溶液置于压力容器中来制备颗粒。 将前体溶液置于压力容器中。 将压力容器加热至反应温度以形成碳颗粒。 碳颗粒经受化学活化和物理活化。 该组合物包含按重量计约5％至约30％的氧气。
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公开(公告)号：US09440858B2
公开(公告)日：2016-09-13
申请号：US14003978
申请日：2012-03-15
CPC分类号： C01B31/125 , C01B32/05 , C01B32/348 , C01P2004/32 , C01P2004/60 , C01P2006/12 , C01P2006/14 , H01B1/24 , H01G9/0029 , H01G11/06 , H01G11/34 , H01M4/587 , Y02E60/13 , Y02T10/7022
摘要： A composition generally includes carbon particles. The particles are prepared by dissolving a carbohydrate-based precursor in water to form a precursor solution and placing the precursor solution in a pressure vessel. The precursor solution is placed in a pressure vessel. The pressure vessel is heated to a reaction temperature to form carbon particles. The carbon particles are subjected to a chemical activation and a physical activation. The composition includes, by weight, about 5% to about 30% oxygen.
摘要翻译： 组合物通常包括碳颗粒。 通过将基于碳水化合物的前体溶解在水中以形成前体溶液并将前体溶液置于压力容器中来制备颗粒。 将前体溶液置于压力容器中。 将压力容器加热至反应温度以形成碳颗粒。 碳颗粒经受化学活化和物理活化。 该组合物包含按重量计约5％至约30％的氧气。
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