摘要:
An object of the present invention is to provide a nonaqueous electrolytic solution capable of improving low-temperature load characteristics after high temperature charging storage, an electrochemical element using it, and a 1,2-dioxypropane compound used for it.The nonaqueous electrolytic solution of the present invention comprises an electrolyte salt dissolved in a nonaqueous solvent, and contains a 1,2-dioxypropane compound represented by the above-mentioned general formula (I). (wherein R1 and R2 each represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; X1 represents a group selected from —S(═O)—, —S(═O)2—, —C(═O)—, —CR3R4—, —P(═O)(OR5)— and —SiR6R7—; R3 and R4 each represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; R5 to R7 each represent an alkyl group having from 1 to 6 carbon atoms. Y1 represents an alkylsulfinyl group, an alkenylsulfinyl group, an alkynylsulfinyl group, an arylsulfinyl group, an alkylsulfonyl group, an alkenylsulfonyl group, an alkynylsulfonyl group, or an arylsulfonyl group; Z1 represents a hydrogen atom, an alkyl group, an alkylsulfinylmethyl group, an alkenylsulfinylmethyl group, an alkynylsulfinylmethyl group, an arylsulfinylmethyl group, an alkylsulfonylmethyl group, an alkenylsulfonylmethyl group, an alkynylsulfonylmethyl group, or an arylsulfonylmethyl group; provided that at least one hydrogen atom on the carbon atom of X1, Y1 and Z1 may be substituted with a halogen atom).
摘要:
An electric double layer capacitor that contains at least one electrochemical cell is provided. The cell contains electrodes (e.g., two electrodes) that each contain a porous matrix of electrochemically-active particles (e.g., carbon). An aqueous-based electrolyte is disposed in contact with the porous matrix. In accordance with the present invention, the electrolyte is provided with an anionic polymer that serves as binding agent for the electrochemically active particles and thus reduces electrolyte loss, especially at higher temperatures. Because the polymer is anionic in nature, it is generally hydrophilic and thus can retain its binding properties in the presence of water. The anionic nature of the polymer also allows it to remain stable in the presence of a corrosive polyprotic acid, which is employed in the electrolyte to enhance charge density. Thus, as a result of the present invention, a capacitor may be formed that is capable of exhibiting good electrical performance (e.g., high capacitance and low ESR), even at high temperatures (e.g., 70° C. and above).
摘要:
The present invention provides an electrical double layer capacity comprising a non-aqueous electrolytic solution comprising (A) a solvent comprising a specific fluorine-containing cyclic carbonate and (B) an electrolyte salt comprising a cyclic quaternary onium salt comprising cyclic quaternary onium cation and PF6−, (CF3SO2)2N− or (C2F5SO2)2N−, and (C) a polarizable electrode, and having high withstanding voltage and assuring excellent solubility in a wide range of solvents for dissolving an electrolyte salt.
摘要翻译:本发明提供一种电双层容量,其包含非水电解液,其包含(A)包含特定含氟环状碳酸酯的溶剂和(B)包含环状季铵阳离子和PF 6的环状季鎓盐的电解质盐 - ,(CF 3 SO 2)2 N - 或(C 2 F 5 SO 2)2 N - 和(C)可极化电极,并且具有高耐压并且确保在宽范围的溶剂中溶解电解质盐的优异溶解性。
摘要:
There are provided an electrolyte for a lithium ion capacitor, and a lithium ion capacitor including the same. The electrolyte includes a lithium salt having divalent anions. The lithium ion capacitor including the electrolyte may have high capacitance and stability, even at high temperatures.
摘要:
A device having a first electrode, a second electrode, a separator positioned between the first electrode and the second electrode, and an electrolyte incorporated throughout the first electrode, the second electrode, and the separator. The electrolyte includes one or more lithium salts and one or more solvents. The first electrode and second electrodes comprise a majority of activated carbon having a microporous pore size distribution.
摘要:
An electric double layer capacitor includes a container including electric insulating material for housing the capacitor. At least two electrodes including granular particulate store a charge. An aqueous electrolyte, having a generally neutral pH, floods the at least two electrodes. A separator material including a porous electrical insulating and ionic conducting material separates the at least two electrodes. At least two collectors including graphite each in contact with an electrode conduct current. An elastic compression material compressing the at least two electrodes flooded by the aqueous electrolyte maintains a firm contact of the at least two collectors with material in flooded electrodes. End caps including a high conductivity material joined to the at least two collectors make external electrical connections.
摘要:
Disclosed herein is a water-based electrolyte for an electric double layer capacitor. The water-based electrolyte includes a solution having a first salt and a second salt. The cation of the first salt may be Li+, Na+ or K+, whereas the cation of the second salt may be Cl−, SO42−, PO43− or NO3−, whereas the anion of the second salt is OH−.
摘要:
An electrolyte solution for electric double layer capacitors, which comprises the following (a) and (b): (a) a compound represented by the formula (1), (b) a mixed solvent comprising ethylmethyl carbonate, at least one kind selected from chain carbonates other than ethylmethyl carbonate, and at least one kind selected from cyclic carbonates, (wherein R1 and R2 may be the same or different and independently denote methyl, ethyl, methoxymethyl or ethoxymethyl, or may form a ring structure).
摘要:
A quaternary ammonium salt of the formula (1), electrolytic solution and electrochemical device using the salt wherein R1 is straight-chain or branched alkyl having 1 to 4 carbon atoms, R2 is straight-chain or branched alkyl having 1 to 3 carbon atoms, and X− is N(CN)2−, SCN−, NO3−, NCO− or NO2−.
摘要:
A conductive electrolyte comprises an indicator dye for facilitating detection of electrolyte leakage in a high voltage electrolytic capacitor as well as for facilitating the determination as to when an electrolyte has reached a desired pH range. In a method for detecting electrolyte leakage, a capacitor comprising a flat stack of anodes enclosed in a housing with a lid and an electrolyte comprising an indicator dye is inspected for the presence of electrolyte leaking out of the capacitor. The indicator dye facilitates viewing leaking electrolyte. The indicator dye can be a coloring agent that changes the color of the electrolyte or can be a fluorescent that fluoresces when exposed to ultraviolet light. The indicator dye is also utilized as a pH indicator during the manufacture of electrolytic capacitors, wherein a base is introduced into an electrolyte having an indicator dye that changes pH when the electrolyte turns basic. The base is introduced into the electrolyte until the indicator dye causes the electrolyte to change color indicating the desired pH has been reached.